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Published in: Polymer Science, Series D 1/2023

01-03-2023

Synthesis and Properties of Phenol–Formaldehyde Resins from Thermal-Processing Products of Wood

Authors: A. I. Valiullina, A. N. Grachev, A. R. Valeeva, S. A. Zabelkin, G. M. Bikbulatova, R. M. Khaziakhmedova, V. N. Bashkirov

Published in: Polymer Science, Series D | Issue 1/2023

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Abstract

We present a laboratory study confirming that phenol in phenol–formaldehyde resins can be replaced with deep thermal-processing products of raw wood. Operating conditions of synthesis are described, and a synthetic recipe is given. The synthesized resins were analyzed by physicochemical methods (IR spectroscopy, TGA, and the tensile strength test). The study revealed that such a replacement requires no considerable changes to be made in operating parameters of the current synthetic process for phenol–formaldehyde resins and allows one to obtain a glue based on this resin with a shear strength equal to 1.58 MPa, which meets specifications of the state standard.

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Literature
1.
go back to reference A. Volkov, Plywood Handbook (Politekh. Univ., St. Petersburg, 2010) [in Russian]. A. Volkov, Plywood Handbook (Politekh. Univ., St. Petersburg, 2010) [in Russian].
2.
go back to reference G. Doronin, Synthetic Resins in Woodworking, 2nd ed. (Lesnaya Prom-st’, Moscow, 1987) [in Russian]. G. Doronin, Synthetic Resins in Woodworking, 2nd ed. (Lesnaya Prom-st’, Moscow, 1987) [in Russian].
3.
go back to reference E. N. Medvedeva, “Synthesis of lignin-containing phenol-formaldehyde resins,” Khim. Rastitelnogo Syrya, No. 1, 51–54 (2000). E. N. Medvedeva, “Synthesis of lignin-containing phenol-formaldehyde resins,” Khim. Rastitelnogo Syrya, No. 1, 51–54 (2000).
4.
go back to reference R. M. Khaziakhmedova, A. N. Grachev, S. A. Pushkin, and V. N. Bashkirov, “Physical and mechanical properties of sawdust concrete with torrefied wood filler,” Derevoobrabat. Prom-st’, No. 3, 54–60 (2019). R. M. Khaziakhmedova, A. N. Grachev, S. A. Pushkin, and V. N. Bashkirov, “Physical and mechanical properties of sawdust concrete with torrefied wood filler,” Derevoobrabat. Prom-st’, No. 3, 54–60 (2019).
5.
go back to reference A. Knop and L. A. Pilato, Phenolic Resins: Chemistry, Applications and Performance (Springer, Berlin, 1985).CrossRef A. Knop and L. A. Pilato, Phenolic Resins: Chemistry, Applications and Performance (Springer, Berlin, 1985).CrossRef
6.
go back to reference A. I. Valiullina, A. N. Grachev, A. R. Valeeva, G. M. Bikbulatova, S. A. Zabelkin, and V. N. Bashkirov, “The use of biopolyols obtained from liquid birch sawdust pyrolysis products as a renewable component in the production of rigid polyurethane foam,” Polym. Sci., Ser. D 15, 300—305 (2022). A. I. Valiullina, A. N. Grachev, A. R. Valeeva, G. M. Bikbulatova, S. A. Zabelkin, and V. N. Bashkirov, “The use of biopolyols obtained from liquid birch sawdust pyrolysis products as a renewable component in the production of rigid polyurethane foam,” Polym. Sci., Ser. D 15, 300—305 (2022).
7.
go back to reference G. M. Faizrakhmanova, S. A. Zabelkin, A. N. Grachev, V. N. Bashkirov, and A. A. Makarov, “The use of wood pyrolysis liquid to obtain a binder component for road construction,” Vestn. Kazan. Tekhnol. Univ. 16, 312–314 (2013). G. M. Faizrakhmanova, S. A. Zabelkin, A. N. Grachev, V. N. Bashkirov, and A. A. Makarov, “The use of wood pyrolysis liquid to obtain a binder component for road construction,” Vestn. Kazan. Tekhnol. Univ. 16, 312–314 (2013).
8.
go back to reference S. A. Zabelkin, A. N. Grachev, G. M. Bikbulatova, A. E. Yakovleva, A. A. Makarov, and V. N. Bashkirov, “Resole-type phenol–formaldehyde resin with neutralized liquid products of fast pyrolysis of birch wood,” Polym. Sci., Ser. D 11, 131–134 (2018). S. A. Zabelkin, A. N. Grachev, G. M. Bikbulatova, A. E. Yakovleva, A. A. Makarov, and V. N. Bashkirov, “Resole-type phenol–formaldehyde resin with neutralized liquid products of fast pyrolysis of birch wood,” Polym. Sci., Ser. D 11, 131–134 (2018).
9.
go back to reference V. A. Belyi, “Study of the acid-base properties of lignin using pK spectroscopy,” in Proceedings of the 20th All-Russian Conference “Structure and Dynamics of Molecular Systems”, Yal’chik, 2013. V. A. Belyi, “Study of the acid-base properties of lignin using pK spectroscopy,” in Proceedings of the 20th All-Russian Conference “Structure and Dynamics of Molecular Systems”, Yal’chik, 2013.
10.
go back to reference A. R. Valeeva, A. I. Sabirzyanova, G. M. Bikbulatova, and S. A. Zabelkin, “The strength of phenol-formaldehyde resin modified with liquid products of wood pyrolysis depending on the use of its various fractions,” in Proceedings of 22nd International Scientific and Practical Conference of Students and Young Scientists “Chemistry and Chemical Technology in the 21st century” (Nats. Issled. Tomsk. Politekh. Univ., 2021), pp. 240–241. A. R. Valeeva, A. I. Sabirzyanova, G. M. Bikbulatova, and S. A. Zabelkin, “The strength of phenol-formaldehyde resin modified with liquid products of wood pyrolysis depending on the use of its various fractions,” in Proceedings of 22nd International Scientific and Practical Conference of Students and Young Scientists “Chemistry and Chemical Technology in the 21st century” (Nats. Issled. Tomsk. Politekh. Univ., 2021), pp. 240–241.
11.
go back to reference A. Stucker, F. Schutt, B. Saake, and R. Lehnen, “Lignins from enzymatic hydrolysis and alkaline extraction of steam refined poplar wood. Utilization in lignin-phenol-formaldehyde resins,” Ind. Crops Prod. 85, 300–308 (2016).CrossRef A. Stucker, F. Schutt, B. Saake, and R. Lehnen, “Lignins from enzymatic hydrolysis and alkaline extraction of steam refined poplar wood. Utilization in lignin-phenol-formaldehyde resins,” Ind. Crops Prod. 85, 300–308 (2016).CrossRef
12.
13.
go back to reference D. S. Fardhyanti, “Novia Noor Cahyani improving the quality of bio-oil produced from rice husk pyrolysis by extraction of its phenolic compounds,” Jurnal Bahan Alam Terbarukan JBA 8, 90–100 (2020).CrossRef D. S. Fardhyanti, “Novia Noor Cahyani improving the quality of bio-oil produced from rice husk pyrolysis by extraction of its phenolic compounds,” Jurnal Bahan Alam Terbarukan JBA 8, 90–100 (2020).CrossRef
14.
go back to reference M. A. Varfolomeev, V. N. Emelyanenko, T. R. Musin, A. V. Gerasimov, D. K. Nurgaliev, A. N. Grachev, A. A. Makarov, and S. A. Zabelkin, “Thermal analysis and calorimetric study of the combustion of hydrolytic wood lignin and products of its pyrolysis,” Chem. Technol. Fuels and Oils 51, 140–145 (2015).CrossRef M. A. Varfolomeev, V. N. Emelyanenko, T. R. Musin, A. V. Gerasimov, D. K. Nurgaliev, A. N. Grachev, A. A. Makarov, and S. A. Zabelkin, “Thermal analysis and calorimetric study of the combustion of hydrolytic wood lignin and products of its pyrolysis,” Chem. Technol. Fuels and Oils 51, 140–145 (2015).CrossRef
15.
go back to reference K. N. Sitdykova, R. M. Khaziakhmedova, and R. M. Grachev, “Fast ablative pyrolysis,” in Proceedings of the All-Russian Scientific Conference “Actual Problems of Polymer Science–2018”, Kazan, 2018 (Kazan Nats. Issled. Politekh. Univ., 2018), p. 25. K. N. Sitdykova, R. M. Khaziakhmedova, and R. M. Grachev, “Fast ablative pyrolysis,” in Proceedings of the All-Russian Scientific Conference “Actual Problems of Polymer Science–2018”, Kazan, 2018 (Kazan Nats. Issled. Politekh. Univ., 2018), p. 25.
17.
go back to reference S. Zabelkin, A. Valeva, A. Sabirzyanova, A. Grachev, and V. Bashkirov, “Neutrals influence on the water resistance coefficient of phenol-formaldehyde resin modified by wood pyrolysis liquid products,” Biomass Conversion and Biorefinery, 12, 5563–5570 (2022).CrossRef S. Zabelkin, A. Valeva, A. Sabirzyanova, A. Grachev, and V. Bashkirov, “Neutrals influence on the water resistance coefficient of phenol-formaldehyde resin modified by wood pyrolysis liquid products,” Biomass Conversion and Biorefinery, 12, 5563–5570 (2022).CrossRef
18.
go back to reference GOST 9624–2009. Laminated Glued Wood (Izd. Standartov, Moscow, 2009) [in Russian]. GOST 9624–2009. Laminated Glued Wood (Izd. Standartov, Moscow, 2009) [in Russian].
Metadata
Title
Synthesis and Properties of Phenol–Formaldehyde Resins from Thermal-Processing Products of Wood
Authors
A. I. Valiullina
A. N. Grachev
A. R. Valeeva
S. A. Zabelkin
G. M. Bikbulatova
R. M. Khaziakhmedova
V. N. Bashkirov
Publication date
01-03-2023
Publisher
Pleiades Publishing
Published in
Polymer Science, Series D / Issue 1/2023
Print ISSN: 1995-4212
Electronic ISSN: 1995-4220
DOI
https://doi.org/10.1134/S1995421223010343

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