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Polymer Bulletin
Published in: Polymer Bulletin 10/2017

07-02-2017 | Original Paper

Synthesis and thermal properties of difunctional polysulfone telechelics

Author: Lokman Torun

Published in: Polymer Bulletin | Issue 10/2017

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Abstract

Three series of dichloride and dihydroxyl-terminated polysulfone telechelics (Cl-PES-Cl and HO-PES-OH, M n = 2580–12,750 daltons) were prepared from bis(4-chlorophenyl) sulfone with bisphenol A, 4,4′-dihydroxydiphenyl ether and 4,4′-dihydroxybiphenyl. The glass transition temperatures and thermal stabilities of the 30 telechelics synthesized were evaluated as a function of molecular weights and the nature of the end groups. It was observed that the glass transition temperatures of lower molecular weighted dihydroxyl telechelics are higher, due to the capabilities of forming hydrogen bonds, than the corresponding dichloride telechelics. On the other hand, the increase in the glass transition temperatures was steeper with dichloride-terminated oligomers as compared to the corresponding dihydroxyl-terminated ones. In addition, dichloride telechelics manifest higher thermal stabilities than dihydroxyl-terminated oligomers.
next article Combining control of branching and sulfonation in one-pot synthesis of random sulfonated polyarylethersulfones: effects on thermal stability and water retention

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Metadata
Title
Synthesis and thermal properties of difunctional polysulfone telechelics
Author
Lokman Torun
Publication date
07-02-2017
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 10/2017
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-017-1932-3

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