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Polymer Bulletin

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30-01-2022 | Original Paper

Synthesis, curing and thermal properties of the low melting point phthalonitrile resins containing glycidyl groups

Authors: Huadong Zhang, Zhongyi Yan, Zhizhou Yang, Qiuhong Mu, Dan Peng, Hui Zhao

Published in: Polymer Bulletin | Issue 1/2023

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Abstract

Two low melting point phthalonitrile monomers (EPN and EEPN) containing flexible glycidyl groups were synthesized using hydroxyl-containing phthalonitrile and epichlorohydrin as raw materials. The structures of the synthesized monomers were characterized by Fourier transform infrared (FT-IR), nuclear magnetic resonance (¹H-NMR and ¹³C-NMR) spectra and elemental analysis. Then each of them was blended with 4-(4-aminophenoxy)-phthalonitrile (APPN) and cured to obtain two kinds of amine-catalytic phthalonitrile-based crosslinked polymers. DSC results showed that two blending systems underwent a two-stage polymerization process with the increase of curing temperature. Rheological measurements exhibited that the introduction of glycidyl groups to phthalonitrile resin could greatly improve its processability. Moreover, after thermal cured at 300 ℃, the resulting phthalonitrile resins exhibited excellent mechanical performance, thermal and thermo-oxidative stability.

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Title: Synthesis, curing and thermal properties of the low melting point phthalonitrile resins containing glycidyl groups
Authors: Huadong Zhang
Zhongyi Yan
Zhizhou Yang
Qiuhong Mu
Dan Peng
Hui Zhao
Publication date: 30-01-2022
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 1/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-021-04037-6

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