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Published in: Journal of Materials Science: Materials in Electronics 18/2021

23-08-2021

Synthesis of BiOCl/ZnMoO4 heterojunction with oxygen vacancy for enhanced photocatalytic activity

Authors: Piao Chen, Zhi Zhang, Shuijin Yang, Yun Yang, Yong Sun

Published in: Journal of Materials Science: Materials in Electronics | Issue 18/2021

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Abstract

In this study, a novel oxygen vacancy-rich BiOCl/ZnMoO4 composites were successfully prepared by a simple two-step method. Experimental results indicated that the content of BiOCl with oxygen vacancies played an important role in photocatalytic performance of OBZM heterostructures. OBZM-5 exhibited a highly enhanced photocatalytic activity under visible light irradiation compared to pure BiOCl, Ov-BiOCl, ZnMoO4 and other OBZM composites, which can be attributed to the efficient separation and transfer of photogenerated charge carrier. The photocatalytic degradation efficiency of rhodamine B (RhB) can reach 99% within 40 min and almost all of norfloxacin (NOR) can be degradated after 100 min by OBZM-5. In addition, OBZM-5 displayed a good stability during the photocatalytic process, which favored a long-term use. Moreover, a possible photocatalytic mechanism was proposed based on the active species trapping experiments and electron spin resonance (ESR) tests, verifying that the photogenerated holes (h+) and ·O2 radicals were the dominating active species.

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Metadata
Title
Synthesis of BiOCl/ZnMoO4 heterojunction with oxygen vacancy for enhanced photocatalytic activity
Authors
Piao Chen
Zhi Zhang
Shuijin Yang
Yun Yang
Yong Sun
Publication date
23-08-2021
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 18/2021
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-021-06805-6

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