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Journal of Polymer Research
Published in: Journal of Polymer Research 6/2020

01-06-2020 | ORIGINAL PAPER

Synthesis of optothermal responsive polymers by thiol-ene click reaction and their aggregation behavior

Authors: Yaxia Li, Qihao Xue, Hongyan Zhang, Zhaoyang Ji, Dongxiang Li, Chunfang Li

Published in: Journal of Polymer Research | Issue 6/2020

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Abstract

Thermosensitive and photosensitive polymers (PNIPAM-Azo) were synthesized by thiol-ene click reaction with PNIPAM with terminal thiol groups (PNIPAM-SH) and azobenzene compounds containing a double bond. Different catalysts were used in the reaction to investigate their catalytic effect and a photocatalyst was found to have the best effect. The aggregation behavior of PNIPAM-Azo in aqueous solution was studied, which showed that PNIPAM-Azo had good surface activity in aqueous solution, and could form different aggregates at different concentration. Meanwhile PNIPAM-Azo exhibited good light response and thermal response, only the LCST of PNIPAM-Azo increased a little after long time ultraviolet irradiation.
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Metadata
Title
Synthesis of optothermal responsive polymers by thiol-ene click reaction and their aggregation behavior
Authors
Yaxia Li
Qihao Xue
Hongyan Zhang
Zhaoyang Ji
Dongxiang Li
Chunfang Li
Publication date
01-06-2020
Publisher
Springer Netherlands
Published in
Journal of Polymer Research / Issue 6/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-020-02162-w

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