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Cellulose

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01-12-2012 | Original Paper

Synthesis of (zinc(II) phthalocyanine)-containing cellulose derivative using phthalocyanine-ring formation reaction

Authors: Yasuko Saito, Toshiyuki Takano, Keita Sakakibara, Hiroshi Kamitakahara, Fumiaki Nakatsubo

Published in: Cellulose | Issue 6/2012

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Abstract

2,3-Di-O-myristyl-6-O-(zinc(II) phthalocyaninyl) cellulose (5) was synthesized from cellulose (1) by five reaction steps via 6-O-(3′,4′-dicyanophenyl)-2,3-di-O-myristyl cellulose (4). The key reaction was phthalocyanine-ring formation on a cellulose backbone, that is, the reaction of compound 4 with o-phthalodinitrile in the presence of hexamethyldisilazane and zinc acetate in DMF afforded to compound 5 in 35.4 % yield. Consequently, the degree of substitution with phthalocyanine moieties of compound 5 was 0.38. The LB monolayer film of compound 5 on an indium tin oxide (ITO) electrode was found to show photocurrent generation performance at 680 nm.

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Title: Synthesis of (zinc(II) phthalocyanine)-containing cellulose derivative using phthalocyanine-ring formation reaction
Authors: Yasuko Saito
Toshiyuki Takano
Keita Sakakibara
Hiroshi Kamitakahara
Fumiaki Nakatsubo
Publication date: 01-12-2012
Publisher: Springer Netherlands
Published in: Cellulose / Issue 6/2012
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-012-9772-7

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