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01-03-2014 | Research Paper

Synthesis, spectroscopic and luminescent properties of nanosized powders of yttrium phosphates doped with Er³⁺ ions

Authors: Polina A. Ryabochkina, Svetlana A. Antoshkina, Alexander S. Vanetsev, Ilmo Sildos, Olga M. Gaitko, Vladimir M. Kyashkin, Sergey N. Ushakov, Andrey A. Panov, Natalie Yu. Tabachkova, Konstantin N. Nishchev

Published in: Journal of Nanoparticle Research | Issue 3/2014

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Abstract

Here, we report synthesis of pure crystalline nanopowders of yttrium orthophosphate Y_0.95Er_0.05PO₄ with xenotime-type structure and hydrate of yttrium orthophosphate Y_0.95Er_0.05PO₄⋅0.8H₂O with rhabdophane-type structure using microwave-hydrothermal treatment of freshly precipitated gels. To establish phase composition of the synthesized nanopowders, we have carried out XRD analysis. Also, we have investigated their morphology by means of TEM and SAXS. We have registered scattered reflection spectra for synthesized Y_0.95Er_0.05PO₄ and Y_0.95Er_0.05PO₄⋅0.8H₂O powders. Also, we have obtained luminescent spectra of these nanocrystalline samples for ⁴I_13/2 → ⁴I_15/2 transition of Er³⁺ ion with excitation of ⁴I_11/2 level. We have proposed the mode of application of nanocrystalline powders Y_0.95Er_0.05PO₄ and Y_0.95Er_0.05PO₄⋅0.8H₂O for the development of composite materials based on polymer capsules that are being used in targeted drug delivery.

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Title: Synthesis, spectroscopic and luminescent properties of nanosized powders of yttrium phosphates doped with Er3+ ions
Authors: Polina A. Ryabochkina
Svetlana A. Antoshkina
Alexander S. Vanetsev
Ilmo Sildos
Olga M. Gaitko
Vladimir M. Kyashkin
Sergey N. Ushakov
Andrey A. Panov
Natalie Yu. Tabachkova
Konstantin N. Nishchev
Publication date: 01-03-2014
Publisher: Springer Netherlands
Published in: Journal of Nanoparticle Research / Issue 3/2014
Print ISSN: 1388-0764
Electronic ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-014-2326-1

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