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Colloid and Polymer Science
Published in: Colloid and Polymer Science 6/2004

01-04-2004 | Original Contribution

The aqueous cationic system sodium undecenoate-dodecyltrimethylammonium bromide at low concentration

Authors: Maria Belén Sierra, Marcela A. Morini, Pablo C. Schulz

Published in: Colloid and Polymer Science | Issue 6/2004

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Abstract

The aqueous sodium undecenoate (SUD) –dodecyltrimethylammonium bromide (DTAB) catanionic system was studied at low concentration. The system did not precipitate, even at a 1:1 SUD:DTAB proportion, but showed the formation of a coacervate in a range of surfactant mixture compositions. Micelles have a preferential composition of 0.37 mole fraction of SUD. This behavior is attributed to the presence of the double bond at the distal extreme of the SUD molecule, which can form hydrogen bonds with water. Consequently, the –CH=CH2 group is situated at the interface between the hydrocarbon micelle core and water, reducing the interfacial free energy. Structural computations demonstrate that the mentioned SUD proportion produces complete coverage of the micelle surface by the double bonds.
previous article Analytic calculation of phase diagrams for solutions containing colloids or globular proteins
next article Effect of the content of urea groups on the particle size in water-borne polyurethane or polyurethane/polyacrylate dispersions

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Metadata
Title
The aqueous cationic system sodium undecenoate-dodecyltrimethylammonium bromide at low concentration
Authors
Maria Belén Sierra
Marcela A. Morini
Pablo C. Schulz
Publication date
01-04-2004
Publisher
Springer-Verlag
Published in
Colloid and Polymer Science / Issue 6/2004
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-003-0988-9

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