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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 16/2017

24-04-2017

The comparison: photoluminescence and afterglow behavior in CaSnO3:Dy3+ and Ca2SnO4:Dy3+ phosphors

Authors: Bowen Zhang, Mingming Shi, Dongyun Zhang, Yunyun Guo, Chengkang Chang, WeiJie Song

Published in: Journal of Materials Science: Materials in Electronics | Issue 16/2017

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Abstract

This paper reports the comparison of photoluminescence and afterglow behavior of Dy3+ in CaSnO3 and Ca2SnO4 phosphors. The samples containing CaSnO3 and Ca2SnO4 were prepared via solid-state reaction. The properties have been characterized and analyzed by utilizing X-ray diffraction (XRD), photoluminescence spectroscope (PLS), X-ray photoelectron spectroscopy (XPS), afterglow spectroscopy (AS) and thermal luminescence spectroscope (TLS). The emission spectra revealed that CaSnO3:Dy3+ and Ca2SnO4:Dy3+ phosphors showed different photoluminescence. The Ca2SnO4:Dy3+ phosphor showed a typical 4F9/2 to 6Hj energy transition of Dy3+ ions, with three significant emissions centering around 482, 572 and 670 nm. However, the CaSnO3:Dy3+ phosphor revealed a broad T1 → S0 transitions of Sn2+ ions. The XPS demonstrate the existence of Sn2+ ions in CaSnO3 phosphor caused by the doping of Dy3+ ions. Both the CaSnO3:Dy3+ and Ca2SnO4:Dy3+ phosphors showed a typical triple-exponential afterglow when the UV source switched off. Thermal simulated luminescence study indicated that the persistent afterglow of CaSnO3:Dy3+ and Ca2SnO4:Dy3+ phosphors was generated by the suitable electron or hole traps which were resulted from the doping the calcium stannate host with rare-earth ions (Dy3+).
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Metadata
Title
The comparison: photoluminescence and afterglow behavior in CaSnO3:Dy3+ and Ca2SnO4:Dy3+ phosphors
Authors
Bowen Zhang
Mingming Shi
Dongyun Zhang
Yunyun Guo
Chengkang Chang
WeiJie Song
Publication date
24-04-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 16/2017
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-6964-9

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