Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Cellulose
Published in: Cellulose 3/2018

12-02-2018 | Original Paper

The effect of difference in chemical composition between cellulose and lignin on carbon based solid acids applied for cellulose hydrolysis

Authors: Yehui Li, Shuguang Shen, Chunyan Wang, Xin Peng, Shujuan Yuan

Published in: Cellulose | Issue 3/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Carbon based solid acids (CSAs) were prepared from cellulose and lignin at different carbonization temperatures and applied to hydrolysis of cellulose, which is of great significance for the multiple utilization of biomass. The structure and performance of cellulose based solid acids (CCSAs) and lignin based solid acids (LCSAs) were investigated by TG-DTG, XRD, FT-IR, XPS, elemental analysis, titration methods, etc. And immersion enthalpy was introduced into estimating the hydrophilicity of CSAs. The results show that the optimum carbonization temperature varies for raw material, and the optimum carbonization temperatures of cellulose and lignin are 683 and 653 K respectively. The adsorption capacities of CCSAs and LCSAs may not only be related to phenolic OH density, but may also relate to alkyl side chains and aromatic frameworks. Compared with LCSAs, the CCSAs possess higher immersion enthalpy, indicating that the CCSAs are more easily accessible to substrate, which contributes to hydrolysis. The hydrolysis activities of CCSAs are always higher than those of LCSAs, which may be due to a higher –SO3H groups densities and better accessibility between substrate and acid sites for CCSAs. These are determined by a big difference in the chemical composition between cellulose and lignin.
previous article Effect of the nano-fibrillation of bamboo pulp on the thermal, structural, mechanical and physical properties of nanocomposites based on starch/poly(vinyl alcohol) blend
next article Cellulose fiber size defines efficiency of enzymatic hydrolysis and impacts degree of synergy between endo- and exoglucanases

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now
Literature
Davoodnia A, Mahjoobin R, Tavakoli-Hoseini N (2014) A facile, green, one-pot synthesis of amidoalkyl naphthols under solvent-free conditions catalyzed by a carbon-based solid acid. Chin J Catal 35:490–495CrossRef
Dhepe PL, Fukuoka A (2008) Cellulose conversion under heterogeneous catalysis. Chemsuschem 1:969–975CrossRef
Fu Z-W, Wan H, Hu X-S, Cui Q, Guan G-F (2012) Preparation and catalytic performance of a carbon-based solid acid catalyst with high specific surface area. React Kinet Mech Cat 107:203–213CrossRef
Fukuhara K, Nakajima K, Kitano M, Kato H, Hayashi S, Hara M (2011) Structure and catalysis of cellulose-derived amorphous carbon bearing SO3H groups. Chemsuschem 4:778–784CrossRef
Gan L, Zhu J, Lv L (2017) Cellulose hydrolysis catalyzed by highly acidic lignin-derived carbonaceous catalyst synthesized via hydrothermal carbonization. Cellulose 24:5327–5339CrossRef
Gani A, Naruse I (2007) Effect of cellulose and lignin content on pyrolysis and combustion characteristics for several types of biomass. Renew Energ 32:649–661CrossRef
Guo Q (2011) Preparation, structural characterization and catalytic performance of solid acid catalyst from bagasse. Beijing: South China University of Technology, pp 21–58
Guo F, Fang Z, Zhou T-J (2012) Conversion of fructose and glucose into 5-hydroxymethylfurfural with lignin-derived carbonaceous catalyst under microwave irradiation in dimethyl sulfoxide-ionic liquid mixtures. Bioresour Technol 112:313–318CrossRef
Hu S, Jiang F, Hsieh Y-L (2015) 1D lignin-based solid acid catalysts for cellulose hydrolysis to glucose and nanocellulose. ACS Sustain Chem Eng 3:2566–2574CrossRef
Ishimaru K, Hata T, Bronsveld P, Meier D, Imamura Y (2007) Spectroscopic analysis of carbonization behavior of wood, cellulose and lignin. J Mater Sci 42:122–129CrossRef
Kitano M, Arai K, Kodama A, Kousaka T, Nakajima K, Hayashi S, Hara M (2009a) Preparation of a sulfonated porous carbon catalyst with high specific surface area. Catal Lett 131:242–249CrossRef
Kitano M, Yamaguchi D, Suganuma S, Nakajima K, Kato H, Hayashi S, Hara M (2009b) Adsorption-enhanced hydrolysis of beta-1,4-glucan on graphene-based amorphous carbon bearing SO3H, COOH, and OH groups. Langmuir 25:5068–5075CrossRef
Li L, Chen Z, Zhong H, Wang R (2014) Urea-based porous organic frameworks: effective supports for catalysis in neat water. Chemistry 20:3050–3060CrossRef
Liang F, Song Y, Huang C, Zhang J, Chen B (2013) Preparation and performance evaluation of a lignin-based solid acid from acid hydrolysis lignin. Catal Commun 40:93–97CrossRef
Lin Y-C, Huber GW (2009) The critical role of heterogeneous catalysis in lignocellulosic biomass conversion. Energ Environ Sci 2:68–80CrossRef
Liu T, Li Z, Li W, Shi C, Wang Y (2013) Preparation and characterization of biomass carbon-based solid acid catalyst for the esterification of oleic acid with methanol. Bioresour Technol 133:618–621CrossRef
Liu X-Y, Liu S-Y, Fan M-Q, Zhang L (2017) Decrease of hydrophilicity of lignite using CTAB: effects of adsorption differences of surfactant onto mineral composition and functional groups. Fuel 197:474–481CrossRef
Lou WY, Zong MH, Duan ZQ (2008) Efficient production of biodiesel from high free fatty acid-containing waste oils using various carbohydrate-derived solid acid catalysts. Bioresour Technol 99:8752–8758CrossRef
Lu L, Sahajwalla V, Kong C, Harris D (2001) Quantitative X-ray diffraction analysis and its application to various coals. Carbon 39:1821–1833CrossRef
Miller GL (1959) Use of dinitrosalicylic acid reagent for determination of reducing sugar. Anal Chem 31:426–428CrossRef
Nakhate AV, Yadav GD (2016) Synthesis and characterization of sulfonated carbon-based graphene oxide monolith by solvothermal carbonization for esterification and unsymmetrical ether formation. ACS Sustain Chem Eng 4:1963–1973CrossRef
Nata IF, Irawan C, Mardina P, Lee C-K (2015) Carbon-based strong solid acid for cornstarch hydrolysis. J Solid State Chem 230:163–168CrossRef
Ngaosuwan K, Goodwin JG, Prasertdham P (2016) A green sulfonated carbon-based catalyst derived from coffee residue for esterification. Renew Energ 86:262–269CrossRef
Onda A, Ochi T, Yanagisawa K (2008) Selective hydrolysis of cellulose into glucose over solid acid catalysts. Green Chem 10:1033CrossRef
Ordomsky VV, Sushkevich VL, Schouten JC, van der Schaaf J, Nijhuis TA (2013) Glucose dehydration to 5-hydroxymethylfurfural over phosphate catalysts. J Catal 300:37–46CrossRef
Peng X, Shen S, Wang C, Li T, Li Y, Yuan S, Wen X (2017) Influence of relative proportions of cellulose and lignin on carbon-based solid acid for cellulose hydrolysis. Mol Catal 442:133–139CrossRef
Sakamoto T, Hasunuma T, Hori Y, Yamada R, Kondo A (2012) Direct ethanol production from hemicellulosic materials of rice straw by use of an engineered yeast strain codisplaying three types of hemicellulolytic enzymes on the surface of xylose-utilizing Saccharomyces cerevisiae cells. J Biotechnol 158:203–210CrossRef
Salame II, Bandosz TJ (2001) Surface chemistry of activated carbons: combining the results of temperature-programmed desorption, boehm, and potentiometric titrations. J Colloid Interface Sci 240:252–258CrossRef
Shen S-G, Wang C-Y, Cai B, Li H-M, Han Y, Wang T, Qin H-F (2013) Heterogeneous hydrolysis of cellulose into glucose over phenolic residue-derived solid acid. Fuel 113:644–649CrossRef
Shen S-G, Cai B, Wang C-Y, Li H-M, Dai G, Qin H-F (2014) Preparation of a novel carbon-based solid acid from cocarbonized starch and polyvinyl chloride for cellulose hydrolysis. Appl Catal A Gen 473:70–74CrossRef
Sonibare OO, Haeger T, Foley SF (2010) Structural characterization of Nigerian coals by X-ray diffraction, Raman and FTIR spectroscopy. Energy 35:5347–5353CrossRef
Suganuma S, Nakajima K, Kitano M, Yamaguchi D, Kato H, Hayashi S (2008) Hydrolysis of cellulose by amorphous carbon bearing SO3H, COOH, and OH groups. J Am Chem Soc 130:12787–12793CrossRef
Suganuma S, Nakajima K, Kitano M, Hayashi S, Hara M (2012) sp3-Linked amorphous carbon with sulfonic acid groups as a heterogeneous acid catalyst. Chemsuschem 5:1841–1846CrossRef
Sun Z, Tao M, Zhao Q, Guang H, Shi T, Wang X (2015) A highly active willow-derived sulfonated carbon material with macroporous structure for production of glucose. Cellulose 22:675–682CrossRef
Tian D, Hu J, Bao J, Chandra RP, Saddler JN, Lu C (2017) Lignin valorization: lignin nanoparticles as high-value bio-additive for multifunctional nanocomposites. Biotechnol Biofuels 10:192CrossRef
Truss RW, Wood B, Rasch R (2016) Quantitative surface analysis of hemp fibers using XPS, conventional and low voltage in-lens SEM. J Appl Polym Sci 133:9CrossRef
Tyczkowski J, Krawczyk I, Woźniak B, Martin-Martinez JM (2009) Low-pressure plasma chlorination of styrene-butadiene block copolymer for improved adhesion to polyurethane adhesives. Eur Polym J 45:1826–1835CrossRef
Wei S, Kumar V, Banker GS (1996) Phosphoric acid mediated depolymerization and decrystallization of cellulose-preparation of low crystallinity cellulose-a new pharmaceutical excipient. Int J Pharmaceut 142:175–181CrossRef
Wu R-N (2009) Preparation and catalytic performance of carbon-based solid acid catalyst from biomass materials. Beijing: Dalian University of Technology pp 32–58
Yamaguchi D, Kitano M, Suganuma S, Nakajima K, Kato H, Hara M (2009) Hydrolysis of cellulose by a solid acid catalyst under optimal reaction conditions. J Phys Chem C 113:3181–3188CrossRef
Yang H-Q, Yan R, Chen H-P, Lee DH, Zheng C-G (2007) Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86:1781–1788CrossRef
Yang Z-G et al (2013) Dilute-acid conversion of cotton straw to sugars and levulinic acid via 2-stage hydrolysis. Ind Crop Prod 46:205–209CrossRef
Zhang X-C, Zhang Z, Wang F, Wang Y-H, Song Q, Xu J (2013) Lignosulfonate-based heterogeneous sulfonic acid catalyst for hydrolyzing glycosidic bonds of polysaccharides. J Mol Catal A-Chem 377:102–107CrossRef
Zhang C et al (2014) Biochar sulfonic acid immobilized chlorozincate ionic liquid: an efficiently biomimetic and reusable catalyst for hydrolysis of cellulose and bamboo under microwave irradiation. Cellulose 21:1227–1237CrossRef
Zhu J, Gan L, Li B, Yang X (2016) Synthesis and characteristics of lignin-derived solid acid catalysts for microcrystalline cellulose hydrolysis. Korean J Chem Eng 34:110–117CrossRef
Metadata
Title
The effect of difference in chemical composition between cellulose and lignin on carbon based solid acids applied for cellulose hydrolysis
Authors
Yehui Li
Shuguang Shen
Chunyan Wang
Xin Peng
Shujuan Yuan
Publication date
12-02-2018
Publisher
Springer Netherlands
Published in
Cellulose / Issue 3/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-018-1693-7

Other articles of this Issue 3/2018

Cellulose 3/2018 Go to the issue

Original Paper

Fabrication of carboxymethyl-functionalized porous ramie microspheres as effective adsorbents for the removal of cadmium ions

Original Paper

Superhydrophobic modification of cellulose film through light curing polyfluoro resin in situ

Original Paper

Structure development in the condensed state of cellulose fiber regenerated from alkali complex solution

Original Paper

Synthesis of nanoencapsulated Glauber’s salt using PMMA shell and its application on cotton for thermoregulating effect

Original Paper

Calcium alginate beads reinforced with synthetic oligomers, linear polyethylenimine and Cu(II): structural stability and potential applications

Original Paper

Improved properties and drug delivery behaviors of electrospun cellulose acetate nanofibrous membranes by introducing carboxylated cellulose nanocrystals