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Published in: Journal of Coatings Technology and Research 4/2022

10-03-2022

The nano building blocks approach for modification of surface properties of nanocomposite inorganic–organic films

Authors: Jana Pagáčová, Iveta Papučová, Alfonz Plško, Katarína Faturíková

Published in: Journal of Coatings Technology and Research | Issue 4/2022

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Abstract

This work deals with utilization of nano building blocks (NBBs) approach for modification of properties of nanocomposite inorganic–organic films. Using the NBBs approach and acid-catalyzed reactions of tetraethoxysilane and triethoxy(octyl)silane, different procedures were used for preparation of six sols. Besides three different ways of mixing of initial precursors, two temperatures with different reaction time were used. The films were prepared by dip-coating technique and treated at temperature of 170°C. The sols were characterized by method of dynamic light scattering. The surface of films was characterized by atomic force microscopy and sessile drop technique. The influence of sol preparation procedure and reaction conditions on particles size in sols as well as the properties of films surface, such as hydrophobicity, morphology and rms-roughness, was observed. The procedure of sol preparation markedly influences the surface morphology of prepared nanocomposite inorganic–organic films. The changes in the studied properties were mainly observed for films, which were deposited from sols prepared at boiling temperature of isopropyl alcohol.

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Literature
1.
go back to reference Ozin, GA, Arsenault, AC, Cademartiri, L, Nanochemistry: A Chemical Approach to Nanomaterials. RSC Publishing, Cambridge (2009) Ozin, GA, Arsenault, AC, Cademartiri, L, Nanochemistry: A Chemical Approach to Nanomaterials. RSC Publishing, Cambridge (2009)
2.
go back to reference Haas, KH, Rose, K, “Hybrid Inorganic/Organic Polymers with Nanoscale Building Blocks: Precursors, Processing, Properties and Applications.” Rev. Adv. Mater. Sci., 5 47–52 (2003) Haas, KH, Rose, K, “Hybrid Inorganic/Organic Polymers with Nanoscale Building Blocks: Precursors, Processing, Properties and Applications.” Rev. Adv. Mater. Sci., 5 47–52 (2003)
3.
go back to reference Sanchez, C, Julián, B, Belleville, P, Popall, M, “Applications of Hybrid Organic–Inorganic Nanocomposites.” J. Mater. Chem., 15 3559–3592 (2005)CrossRef Sanchez, C, Julián, B, Belleville, P, Popall, M, “Applications of Hybrid Organic–Inorganic Nanocomposites.” J. Mater. Chem., 15 3559–3592 (2005)CrossRef
5.
go back to reference Sanchez, C, Soler-Illia, GJ, de Ribot, FAA, Grosso, D, “Design of Functional Nano-Structured Materials Through the Use of Controlled Hybrid Organic–Inorganic Interfaces.” C R Chimie, 6 1131–1151 (2003)CrossRef Sanchez, C, Soler-Illia, GJ, de Ribot, FAA, Grosso, D, “Design of Functional Nano-Structured Materials Through the Use of Controlled Hybrid Organic–Inorganic Interfaces.” C R Chimie, 6 1131–1151 (2003)CrossRef
6.
go back to reference Brinker, CJ, Scherer, GW, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing. Academic Press, Boston (1990) Brinker, CJ, Scherer, GW, Sol-Gel Science: The Physics and Chemistry of Sol-Gel Processing. Academic Press, Boston (1990)
7.
go back to reference Plško, A, Exnar, P, “The Application of Sol-Gel Methods for the Preparation of Advanced Materials, Namely Glasses.” Silikáty, 33 69–84 ((in Slovak)) (1989) Plško, A, Exnar, P, “The Application of Sol-Gel Methods for the Preparation of Advanced Materials, Namely Glasses.” Silikáty, 33 69–84 ((in Slovak)) (1989)
8.
go back to reference Heikkinen, JJ, Kivimäki, L, Hytönen, VP, Kulomaa, MS, Hormi, OEO, “Printable and Flexible Macroporous Organosilica Film with High Protein Adsorption Capacity.” Thin Solid Films, 520 1934–1937 (2012)CrossRef Heikkinen, JJ, Kivimäki, L, Hytönen, VP, Kulomaa, MS, Hormi, OEO, “Printable and Flexible Macroporous Organosilica Film with High Protein Adsorption Capacity.” Thin Solid Films, 520 1934–1937 (2012)CrossRef
9.
go back to reference Dirè, S, Tagliazucca, V, Callone, E, Quaranta, A, “Effect of Functional Groups on Condensation and Properties of Sol–Gel Silica Nanoparticles Prepared by Direct Synthesis from Organoalkoxysilanes.” Mater. Chem. Phys., 126 909–917 (2011)CrossRef Dirè, S, Tagliazucca, V, Callone, E, Quaranta, A, “Effect of Functional Groups on Condensation and Properties of Sol–Gel Silica Nanoparticles Prepared by Direct Synthesis from Organoalkoxysilanes.” Mater. Chem. Phys., 126 909–917 (2011)CrossRef
10.
go back to reference Mori, H, “Design and Synthesis of Functional Silsesquioxane-Based Hybrids by Hydrolytic Condensation of Bulky Triethoxysilanes.” Int. J. Polym. Sci., 2012 173624 (2012)CrossRef Mori, H, “Design and Synthesis of Functional Silsesquioxane-Based Hybrids by Hydrolytic Condensation of Bulky Triethoxysilanes.” Int. J. Polym. Sci., 2012 173624 (2012)CrossRef
11.
go back to reference Boury, B, Corriu, RJP, “Nanostructured Hybrid Organic–Inorganic Solids from Molecules to Materials.” In: Rappoport, Z, Apeloig, Y (eds.) The Chemistry of Organic Silicon Compounds, pp. 565–640. vol 3, Wiley, Chichester (2001)CrossRef Boury, B, Corriu, RJP, “Nanostructured Hybrid Organic–Inorganic Solids from Molecules to Materials.” In: Rappoport, Z, Apeloig, Y (eds.) The Chemistry of Organic Silicon Compounds, pp. 565–640. vol 3, Wiley, Chichester (2001)CrossRef
12.
go back to reference Issa, AA, Luyt, AS, “Kinetics of Alkoxysilanes and Organoalkoxysilanes Polymerization: A Review.” Polymers, 11 537 (2019)CrossRef Issa, AA, Luyt, AS, “Kinetics of Alkoxysilanes and Organoalkoxysilanes Polymerization: A Review.” Polymers, 11 537 (2019)CrossRef
13.
go back to reference Parale, VG, Mahadik, DB, Mahadik, SA, Kavale, MS, Wagh, PB, Gupta, SC, Venkateswara Rao, A, “OTES Modified Transparent Dip Coated Silica Coatings.” Ceram. Int., 39 835–840 (2013)CrossRef Parale, VG, Mahadik, DB, Mahadik, SA, Kavale, MS, Wagh, PB, Gupta, SC, Venkateswara Rao, A, “OTES Modified Transparent Dip Coated Silica Coatings.” Ceram. Int., 39 835–840 (2013)CrossRef
14.
go back to reference Anastasova, S, Milanova, M, Kashchieva, E, Funakubo, H, Kamo, T, Grozev, N, Stefanov, P, Todorovsky, D, “Morphology of Sol–Gel Produced Composite Films for Optical Oxygen Sensors.” Appl. Surf. Sci., 254 1545–1558 (2008)CrossRef Anastasova, S, Milanova, M, Kashchieva, E, Funakubo, H, Kamo, T, Grozev, N, Stefanov, P, Todorovsky, D, “Morphology of Sol–Gel Produced Composite Films for Optical Oxygen Sensors.” Appl. Surf. Sci., 254 1545–1558 (2008)CrossRef
15.
go back to reference Holubová, B, Zlámalová Cílová, Z, Kučerová, I, Zlámal, M, “Weatherability of Hybrid Organic–Inorganic Silica Protective Coatings on Glass.” Prog. Org. Coat., 88 172–180 (2015)CrossRef Holubová, B, Zlámalová Cílová, Z, Kučerová, I, Zlámal, M, “Weatherability of Hybrid Organic–Inorganic Silica Protective Coatings on Glass.” Prog. Org. Coat., 88 172–180 (2015)CrossRef
16.
go back to reference Wu, L-K, Zhang, X-F, Hu, J-M, “Corrosion Protection of Mild Steel by One-Step Electrodeposition of Superhydrophobic Silica Film.” Corros. Sci., 85 482–487 (2014)CrossRef Wu, L-K, Zhang, X-F, Hu, J-M, “Corrosion Protection of Mild Steel by One-Step Electrodeposition of Superhydrophobic Silica Film.” Corros. Sci., 85 482–487 (2014)CrossRef
17.
go back to reference Chou, TP, Chandrasekaran, C, Limmer, SJ, Seraji, S, Wu, Y, Forbess, MJ, Nguyen, C, Cao, GZ, “Organic-Inorganic Hybrid Coating for Corrosion Protection.” J. Non-Cryst. Solids., 290 153–162 (2001)CrossRef Chou, TP, Chandrasekaran, C, Limmer, SJ, Seraji, S, Wu, Y, Forbess, MJ, Nguyen, C, Cao, GZ, “Organic-Inorganic Hybrid Coating for Corrosion Protection.” J. Non-Cryst. Solids., 290 153–162 (2001)CrossRef
18.
go back to reference Jeeva Jothi, K, Palanivelu, K, “Synergistic Effect of Silane Modified Nanocomposites for Active Corrosion Protection.” Ceram. Int., 39 7619–7625 (2013)CrossRef Jeeva Jothi, K, Palanivelu, K, “Synergistic Effect of Silane Modified Nanocomposites for Active Corrosion Protection.” Ceram. Int., 39 7619–7625 (2013)CrossRef
19.
go back to reference Petcu, C, Alexandrescu, E, Bălan, A, Tănase, MA, Cinteză, LO, “Synthesis and Characterisation of Organo-Modified Silica Nanostructured Films for the Water-Repellent Treatment of Historic Stone Buildings.” Coatings, 10 1010 (2020)CrossRef Petcu, C, Alexandrescu, E, Bălan, A, Tănase, MA, Cinteză, LO, “Synthesis and Characterisation of Organo-Modified Silica Nanostructured Films for the Water-Repellent Treatment of Historic Stone Buildings.” Coatings, 10 1010 (2020)CrossRef
20.
go back to reference Ramezani, M, Vaezi, MR, Kazemzadeh, A, “The Influence of the Hydrophobic Agent, Catalyst, Solvent and Water Content on the Wetting Properties of the Silica Films Prepared by One-Step Sol–Gel Method.” Appl. Surf. Sci., 326 99–106 (2015)CrossRef Ramezani, M, Vaezi, MR, Kazemzadeh, A, “The Influence of the Hydrophobic Agent, Catalyst, Solvent and Water Content on the Wetting Properties of the Silica Films Prepared by One-Step Sol–Gel Method.” Appl. Surf. Sci., 326 99–106 (2015)CrossRef
21.
go back to reference Anastasova, S, Milanova, M, Manolov, I, Czeppe, T, Todorovsky, D, “Thermochemical Behaviour of Ru(II) Complex–SiO2 Microcomposites.” Bull. Mater. Sci., 30 511–520 (2007)CrossRef Anastasova, S, Milanova, M, Manolov, I, Czeppe, T, Todorovsky, D, “Thermochemical Behaviour of Ru(II) Complex–SiO2 Microcomposites.” Bull. Mater. Sci., 30 511–520 (2007)CrossRef
22.
go back to reference Penna, A, Elviri, L, Careri, M, Mangia, A, Predieri, G, “Investigation of Novel Sol–Gel Hydrophobic Surfaces for Desorption Electrospray Ionization-Mass Spectrometry Analysis.” Anal. Bioanal. Chem., 400 1515–1523 (2011)CrossRef Penna, A, Elviri, L, Careri, M, Mangia, A, Predieri, G, “Investigation of Novel Sol–Gel Hydrophobic Surfaces for Desorption Electrospray Ionization-Mass Spectrometry Analysis.” Anal. Bioanal. Chem., 400 1515–1523 (2011)CrossRef
23.
go back to reference Pantulap, U, Petchareanmongkol, B, Kaewdang, W, Tapasa, K, “Optical Transparent and Hydrophobic Properties of TEOS/OTES Hybrid Materials by Sol-Gel Processing.” Key Eng. Mater., 798 134–139 (2019)CrossRef Pantulap, U, Petchareanmongkol, B, Kaewdang, W, Tapasa, K, “Optical Transparent and Hydrophobic Properties of TEOS/OTES Hybrid Materials by Sol-Gel Processing.” Key Eng. Mater., 798 134–139 (2019)CrossRef
24.
go back to reference Purcar, V, Stamatin, I, Cinteza, O, Petcu, C, Raditoiu, V, Ghiurea, M, Miclaus, T, Andronie, A, “Fabrication of Hydrophobic and Antireflective Coatings Based on Hybrid Silica Films by Sol–Gel Process.” Surf. Coat. Technol., 206 4449–4454 (2012)CrossRef Purcar, V, Stamatin, I, Cinteza, O, Petcu, C, Raditoiu, V, Ghiurea, M, Miclaus, T, Andronie, A, “Fabrication of Hydrophobic and Antireflective Coatings Based on Hybrid Silica Films by Sol–Gel Process.” Surf. Coat. Technol., 206 4449–4454 (2012)CrossRef
25.
go back to reference Zheng, SX, Li, JH, “Inorganic-Organic Sol Gel Hybrid Coatings for Corrosion Protection of Metals.” J. Sol-Gel Sci. Technol., 54 174–187 (2010)CrossRef Zheng, SX, Li, JH, “Inorganic-Organic Sol Gel Hybrid Coatings for Corrosion Protection of Metals.” J. Sol-Gel Sci. Technol., 54 174–187 (2010)CrossRef
26.
go back to reference Figueira, RB, Silva, CJR, Pereira, EV, “Organic–Inorganic Hybrid Sol–Gel Coatings for Metal Corrosion Protection: A Review of Recent Progress.” J. Coat. Technol. Res., 12 1–35 (2015)CrossRef Figueira, RB, Silva, CJR, Pereira, EV, “Organic–Inorganic Hybrid Sol–Gel Coatings for Metal Corrosion Protection: A Review of Recent Progress.” J. Coat. Technol. Res., 12 1–35 (2015)CrossRef
27.
go back to reference Bláhová, O, Špírková, M, “Local Mechanical Properties of Organic-Inorganic Nanocomposite Coatings.” Chem. Listy, 105 140–142 ((in Czech)) (2011) Bláhová, O, Špírková, M, “Local Mechanical Properties of Organic-Inorganic Nanocomposite Coatings.” Chem. Listy, 105 140–142 ((in Czech)) (2011)
28.
go back to reference de Ferri, L, Lottici, PP, Lorenzi, A, Montenero, A, Vezzalini, G, “Hybrid Sol–Gel Based Coatings for the Protection of Historical Window Glass.” J. Sol-Gel Sci. Technol., 66 253–263 (2013)CrossRef de Ferri, L, Lottici, PP, Lorenzi, A, Montenero, A, Vezzalini, G, “Hybrid Sol–Gel Based Coatings for the Protection of Historical Window Glass.” J. Sol-Gel Sci. Technol., 66 253–263 (2013)CrossRef
29.
go back to reference Pan, X, Wu, J, Ge, Y, Xiao, K, Luo, H, Gao, S, Li, X, “Preparation and Characterization of Anticorrosion Ormosil Sol–Gel Coatings for Aluminum Alloy.” J. Sol-Gel Sci. Technol., 72 8–20 (2014)CrossRef Pan, X, Wu, J, Ge, Y, Xiao, K, Luo, H, Gao, S, Li, X, “Preparation and Characterization of Anticorrosion Ormosil Sol–Gel Coatings for Aluminum Alloy.” J. Sol-Gel Sci. Technol., 72 8–20 (2014)CrossRef
30.
go back to reference Vejar, ND, Azocar, MI, Tamayo, LA, Gonzalez, E, Pavez, J, Gulppi, M, Zagal, JH, Zhou, X, Santibañez, F, Thompson, GE, Paez, MA, “Antibiofouling Properties of Sol-Gel Type Polymers for Aluminium Alloys: Biocorrosion Protection Against Pseudomonas Aeruginosa.” Int. J. Electrochem. Sci., 8 12062–12077 (2013) Vejar, ND, Azocar, MI, Tamayo, LA, Gonzalez, E, Pavez, J, Gulppi, M, Zagal, JH, Zhou, X, Santibañez, F, Thompson, GE, Paez, MA, “Antibiofouling Properties of Sol-Gel Type Polymers for Aluminium Alloys: Biocorrosion Protection Against Pseudomonas Aeruginosa.” Int. J. Electrochem. Sci., 8 12062–12077 (2013)
31.
go back to reference Schuster, JM, Schvezov, CE, Rosenberger, MR, “Influence of Experimental Variables on the Measure of Contact Angle in Metals Using the Sessile Drop Method.” Procedia Mater. Sci., 8 742–751 (2015)CrossRef Schuster, JM, Schvezov, CE, Rosenberger, MR, “Influence of Experimental Variables on the Measure of Contact Angle in Metals Using the Sessile Drop Method.” Procedia Mater. Sci., 8 742–751 (2015)CrossRef
32.
go back to reference Latthe, SS, Hirashima, H, Rao, AV, “TEOS Based Water Repellent Silica Films Obtained by a Co-precursor Sol–Gel Method.” Smart Mater. Struct., 18 095017 (2009)CrossRef Latthe, SS, Hirashima, H, Rao, AV, “TEOS Based Water Repellent Silica Films Obtained by a Co-precursor Sol–Gel Method.” Smart Mater. Struct., 18 095017 (2009)CrossRef
33.
go back to reference Tavana, H, Neumann, AW, “Recent Progress in the Determination of Solid Surface Tensions from Contact Angles.” Adv. Colloid Interface Sci., 132 1–32 (2007)CrossRef Tavana, H, Neumann, AW, “Recent Progress in the Determination of Solid Surface Tensions from Contact Angles.” Adv. Colloid Interface Sci., 132 1–32 (2007)CrossRef
Metadata
Title
The nano building blocks approach for modification of surface properties of nanocomposite inorganic–organic films
Authors
Jana Pagáčová
Iveta Papučová
Alfonz Plško
Katarína Faturíková
Publication date
10-03-2022
Publisher
Springer US
Published in
Journal of Coatings Technology and Research / Issue 4/2022
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-021-00592-9

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