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Journal of Polymer Research

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01-03-2020 | ORIGINAL PAPER

The surface tunability and dye separation property of PVDF porous membranes modified by P(MMA-b-MEBIm-Br): effect of poly(ionic liquid) brush lengths

Authors: Chunhui Du, Xinyi Zhang, Xumin Ma

Published in: Journal of Polymer Research | Issue 3/2020

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Abstract

In order to obtain the tunable and charged surface of the membranes, polymerized ionic liquid(PIL) block copolymers poly (methyl methacrylate) (PMMA)-b-poly(1-[(2-methacryloyloxy)ethyl]-3-butylimidazoliumbromide) (PMEBIm-Br) with different poly(ionic liquid) brush lengths were synthesized by RAFT polymerization method and used in the fabrication of poly(vinylidene fluoride) blend membranes. Chemistry analysis confirmed the successful copolymerization of P(MMA-b-MEBIm-Br) with different chain lengths of PMEBIm-Br blocks, and the PIL groups was also detected on the surface of the blend membranes, which contributes to the hydrophilic and positively charged surface of the membrane. These properties were further enhanced by the chain length of PMEBIm-Br blocks in the copolymer. The surface wettability of the membranes can be regulated from hydrophilicity to hydrophobicity by anion exchange, and the water flux changes also confirmed these phenomena. In addition, the effects of PMEBIm-Br blocks on the separation properties of the membranes were investigated using two dyes, namely, orange G and rhodamine 6G. Results indicated that the blend membranes with long length of PMEBIm-Br blocks had high rejection and good antifouling property to rhodamine 6G. Furthermore, the adsorption experiment of the blend membranes to the two dyes also indicated that blend membranes with long length of PMEBIm-Br blocks would have good dye adsorption-separation property.

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Yuan JY, David M, Markus A (2013) Poly(ionic liquid)s: an update. Prog Polym Sci 38:1009–1036CrossRef

Tseng LC, Kuo M, Lee RH (2016) An imidazolium iodide–containing hyperbranched polymer ionic liquid that improves the performance of dye-sensitized solar cells. J Polym Res 23:157CrossRef

Zhu JM, Zhou JH, Zhang H, Chu RZ (2011) CO₂ sorption capacity of porous poly(ionic liquid)s. J Polym Res 18:2011–2015CrossRef

Cheng YY, Du CH, Wu CJ, Sun KX, Chi NP (2018) Improving the hydrophilic and antifouling properties of poly(vinyl chloride) membranes by atom transfer radical polymerization grafting of poly(ionic liquid) brushes. Polym Adv Technol 29:623–631CrossRef

Wang LM, Peng B, Su ZH (2010) Tunable wettability and rewritable wettability gradient from superhydrophilicity to superhydrophobicity. Langmuir 26(14):12203–12208CrossRef

Chi YS, Lee JK, Lee S, Choi IS (2004) Control of wettability by anion exchange on Si/SiO₂ surfaces. Langmuir 20:3024–3027CrossRef

Tang Y, Tang BB, Wu PY (2015) A polymeric ionic liquid functionalized temperature-responsive composite membrane with tunable responsive behavior. J Mater Chem A 3:7919–7928CrossRef

Njoroge I, Bout BW, Matson MW, Laibinis PE, Jennings GK (2018) Co-Poly(ionic liquid) Films via Anion Exchange for the Continuous Tunability of Ion Transport and Wettability. ACS Omega 3:16158–16164CrossRef

Mogurampelly S, Keith JR, Ganesan V (2017) Mechanisms underlying ion transport in polymerized ionic liquids. J Am Chem Soc 139(28):9511–9514CrossRef

10.

Vijayakrishna K, Jewrajka SK, Ruiz A, Marcilla R, Pomposo JA, Mecerreyes D, Taton D, Gnanou Y (2008) Synthesis by RAFT and ionic responsiveness of double hydrophilic block copolymer based on ionic liquid monomer units. Macromolecules 41:6299–6308CrossRef

11.

Lee BS, Chi YS, Lee JK, Choi IS, Song CE, Namgoong SK, Lee S (2004) Imidazolium ion-terminated self-assembled monolayers on au: effects ofcounteranions on surface wettability. J Am Chem Soc 126:480–481CrossRef

12.

Azzaroni O, Brown AA, Huck WTS (2007) Tunable wettability by clicking counterions into polyelectrolyte brushes. Adv Mater 19:151–154CrossRef

13.

Adzima BJ, Venna SR, Klara SS, He HK, Zhong MJ, Luebke DR, Mauter MS, Matyjaszewski K, Nulwala HB (2014) Modular polymerized ionic liquid block copolymer membranes for CO₂/N₂ separation. J Mater Chem A 2:7967–7972CrossRef

14.

Ye YS, Choi JH, Winey KI, Elabd YA (2012) Polymerized ionic liquid block and random copolymers: effect of weak microphase separation on ion transport. Macromolecules 45:7027–7035CrossRef

15.

Nykaza JR, Ye YS, Elabd YA (2014) Polymerized ionic liquid diblock copolymers with long alkyl side-chain length. Polymer 55:3360–3369CrossRef

16.

Du CH, Ma XM, Wu CJ, Cai MQ, Hu MX, Wang T (2015) Polymerizable ionic liquidcopolymer P(MMA-co-BVIm-Br) and its effect on the surface wettability of PVDF blend membranes. Chin J Polym Sci 33:1–12CrossRef

17.

Du CH, Ma XM, Li J, Wu CJ (2017) Improving the charged and antifouling properties of PVDF ultrafiltration membranes by blending with polymerized ionic liquid copolymer P(MMA-b-MEBIm-Br). J Appl Polym Sci 134(17):44751. https://doi.org/10.1002/app.44751 CrossRef

18.

Sengupta A, Ethirajan SK, Kamaz M, Jebur M, Wickramasinghe R (2019) Synthesis and characterization of antibacterial poly ionic liquid membranes with tunable performance. Sep Purif Technol 212:307–315CrossRef

19.

Ye YS, Elabd YA (2011) Anion exchanged polymerized ionic liquids: high free volume single ion conductors. Polymer 52:1309–1317CrossRef

20.

Kumar M, Ulbricht M (2014) Novel ultrafiltration membranes with adjustable charge density based on sulfonated poly(arylene ether sulfone) block copolymers and their tunable protein separation performance. Polymer 55:354–365CrossRef

21.

Zhu C, Kang ET, Neoh KG (2005) Brush-type amphiphilicdiblock copolymers from living/controlled radical polymerizations and their aggregation behavior. Langmuir 21(16):7180–7185CrossRef

22.

Wang R, Tang P, Qiu F, Yang Y (2005) Aggregate morphologies of amphiphilic ABC triblock copolymer in dilute solution using self-consistent field theory. J Phys Chem B 109(36):17120–17127CrossRef

23.

Uchida E, Uyama Y, Ikada Y (1994) Zeta potential of polycation layers grafted onto a film surface. Langmuir 10:1193–1198CrossRef

24.

Choi JH, Ye YS, Elabd YA, Winey KI (2013) Network structure and strong microphase separation for high ion conductivity in polymerized ionic liquid block copolymers. Macromolecules 46:5290–5300CrossRef

Title: The surface tunability and dye separation property of PVDF porous membranes modified by P(MMA-b-MEBIm-Br): effect of poly(ionic liquid) brush lengths
Authors: Chunhui Du
Xinyi Zhang
Xumin Ma
Publication date: 01-03-2020
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 3/2020
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-019-1956-5

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