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2017 | OriginalPaper | Chapter

Thermal Conversion of Biomass

Authors : Zhongyang Luo, Jingsong Zhou

Published in: Handbook of Climate Change Mitigation and Adaptation

Publisher: Springer International Publishing

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Abstract

Bioenergy is presently the largest global contributor of renewable energy. Biomass thermal conversion has significant potential to expand in the production of heat, electricity, and fuels for transport. In addition, energy from biomass can contribute significantly toward the objectives of reducing greenhouse gas emissions and alleviating problems related to climate change. There are three main thermal processes – combustion, gasification, and pyrolysis – to convert the biomass into various energy products.

Combustion is well established and widely practiced with many examples of dedicated plant and co-firing applications. At present, biomass co-firing in modern coal power plants is the most cost-effective biomass use for power generation. Due to feedstock availability issues, dedicated biomass plants for combined heat and power (CHP) are typically of smaller size.

Gasification provides a competitive way to convert diverse, highly distributed, and low-value lignocellulosic biomass to syngas for combined heat and power generation, synthesis of liquid fuels, and production of hydrogen (H₂). A number of gasifier configurations have been developed. Biomass integrated gasification combined cycles (BIGCC) using black liquor are already in use. Gasification can also coproduce liquid fuels, and such advanced technologies are currently being investigated in research and pilot plants.

Pyrolysis is thermal destruction of biomass in the absence of air/oxygen to produce liquid bio-oil, syngas, and charcoal. Fast pyrolysis for liquid fuel production is currently of particular interest because liquid fuel can be stored and transported more easily and at lower cost than solid biomass. Pyrolysis technology is currently at the demonstration stage, and technologies for upgrading the bio-oil to transport fuels are applied at the R&D and pilot stage.

This chapter provides an overview of the state-of-the-art knowledge on biomass thermal conversion: the recent breakthrough in the technology, the current research and development activities, and the challenges associated with its increased deployment.

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Arvelakis S, Koukios EG (2002) Physicochemical upgrading of agroresidues as feedstocks for energy production via thermochemical conversion methods. Biomass Bioenergy 22:331–348CrossRef

Arvelakis S, Gehrmann H, Beckman M et al (2002) Effect of leaching on the ash behaviour of olive residue during fluidized bed gasification. Biomass Bioenergy 22:55–69CrossRef

Arvelakis S, Gehrmann H, Beckmann M et al (2005) Preliminary results on the ash behavior of peach stones during fluidized bed gasification: evaluation of fractionation and leaching as pre-treatments. Biomass Bioenergy 28:331–338CrossRef

Balat M, Balat H (2009) Recent trends in global production and utilization of bio-ethanol fuel. Appl Energy 86(11):2273–2282CrossRef

Bartels M, Lin WG, Nijenhuis J et al (2008) Agglomeration in fluidized beds at high temperatures – mechanisms, detection and prevention. Prog Energy Combust Sci 34(5):633–666CrossRef

Baxter LL (1993) Ash deposition during biomass and coal combustion-a mechanistic approach. Biomass Bioenergy 4(2):85–102CrossRef

Baxter L (2005) Biomass-coal co-combustion: opportunity for affordable renewable energy. Fuel 84:1295–1302CrossRef

Boerrigter H (2005) “OLGA” tar removal technology. The Energy research Centre of the Netherlands, ECN-C-05-009

Brammer J, Lauer M, Bridgwater A (2006) Opportunities for biomass-derived “bio-oil” in European heat and power markets. Energy Policy 34(17):2871–2880CrossRef

Branca C, Giudicianni P, Blasi C (2003) GC/MS characterization of liquids generated from low-temperature pyrolysis of wood. Ind Eng Chem Res 42:3190–3202CrossRef

Branca C, Blasi C, Elefante R (2005) Devolatilization and heterogeneous combustion of wood fast pyrolysis oils. Ind Eng Chem Res 44(4):799–810CrossRef

Branca C, DiBlasi C, Elefante R (2006) Devolatilization of conventional pyrolysis oils generated from biomass and cellulose. Energy Fuels 20(5):2253–2261CrossRef

Bridgwater A (1999) Principles and practice of biomass fast pyrolysis processes for liquids. J Anal Appl Pyrol 51:3–22CrossRef

Bridgwater A (2003) Renewable fuels and chemicals by thermal processing of biomass. Chem Eng J 91:87–102CrossRef

Bridgwater A (2004) Biomass fast pyrolysis. Therm Sci 8:21–49CrossRef

Bridgwater A, Peacocke G (2000) Fast pyrolysis processes for biomass. Renew Sust Energy Rev 4:1–73CrossRef

Bridgwater AV, Beenackers AACM, Spila K et al (1999a) An assessment of the possibilities for transfer of European biomass gasification technology to China. European Community, Belgium

Bridgwater A, Meier D, Radlein D (1999b) An overview of fast pyrolysis of biomass. Org Geochem 30:1479–1493CrossRef

Brown JN (2009) Development of a lab-scale auger reactor for biomass fast pyrolysis and process optimization using response surface methodology. MS thesis, Iowa State University, Ames

Brown RC, Liu Q, Norton G (2000) Catalytic effects observed during the co-gasification of coal and switchgrass. Biomass Bioenergy 18:499–506CrossRef

Bruun EW, Hauqqaard-Nielsen H, Ibrahim N et al (2010) Influence of fast pyrolysis temperature on biochar labile fraction and short-term carbon loss in a loamy soil. Biomass Bioenergy 35(3):1182–1189CrossRef

Chen WY, Gathitu BB (2006) Design of mixed fuel for heterogeneous reburning. Fuel 85:1781–1793CrossRef

Chen G, Andries J, Spliethoff H (2003) Catalytic pyrolysis of biomass for hydrogen rich fuel gas production. Energy Convers Manag 44:2289–2296CrossRef

Chiaramonti D, Bonini M, Fratini E et al (2003a) Development of emulsions from biomass pyrolysis liquid and diesel and their use in engines-Part 1: emulsion production. Biomass Bioenergy 25(1):85–99CrossRef

Chiaramonti D, Bonini M, Fratini E et al (2003b) Development of emulsions from biomass pyrolysis liquid and diesel and their use in engines-Part 2: tests in diesel engines. Biomass Bioenergy 25(1):101–111CrossRef

Chirone R, Miccio F, Scala F (2006) Mechanism and prediction of bed agglomeration during fluidized bed combustion of a biomass fuel: effect of the reactor scale. J Chem Eng 123(3):71–80CrossRef

Czernik S, Bridgwater A (2004) Overview of applications of biomass fast pyrolysis Oil. Energy Fuels 18(2):590–598CrossRef

Davis H, Figueroa C, Schaleger L (1982) Hydrogen or carbon monoxide in the liquefaction of biomass. In: World hydrogen energy conference IV, Pasadena

Dayton D (2002) A review of the literature on catalytic biomass tar destruction. Report No. NREL/TP-510-32815. National Renewable Energy Laboratory, Golden. http://www.osti.gov/bridge

Demirbas A (2003) Sustainable cofiring of biomass with coal. Energy Convers Manag 44:1465–1479CrossRef

Demirbas A (2004) Combustion characteristics of different biomass fuels. Prog Energy Combust Sci 30:219–230CrossRef

Demirbas A (2005) Potential applications of renewable energy sources, biomass combustion problems in boiler power systems and combustion related environmental issues. Prog Energy Combust Sci 31:171–192CrossRef

Diana N, Marco R, Kam-Rigne L et al (2010) Contrasted effect of biochar and earthworms on rice growth and resource allocation in different soils. Soil Biol Biochem 42:1017–1027CrossRef

Dobele G, Rossinskaja G, Dizhbite T et al (2005) Application of catalysts for obtaining 1, 6-anhydrosaccharides from cellulose and wood by fast pyrolysis. J Anal Appl Pyrol 74(1–2):401–405CrossRef

Drift A van der, Boerrigter H, Coda B et al. (2004) Entrained flow gasification of biomass: ash behaviour, feeding issues, and system analyses. ECN-C-04-039. ECN, Petten

Elisabet B, Marcus Ö, Anders N (2005) Mechanisms of bed agglomeration during fluidized-bed combustion of biomass fuels. Energy Fuel 19(3):825–832CrossRef

Elliott DC (2007) Historical developments in hydroprocessing bio-oils. Energy Fuels 21(3):1792–1815CrossRef

Elliott DC, Baker EG (1986) The effect of catalysis on wood gasification tar composition. Biomass 9:195–203CrossRef

Fabbri D, Torri C, Baravelli V (2007) Effect of zeolites and nanopowder metal oxides on the distribution of chiral anhydrosugars evolved from pyrolysis of cellulose: an analytical study. J Anal Appl Pyrol 80(1):24–29CrossRef

French R, Czernik S (2009) Catalytic pyrolysis of biomass for biofuels production. Fuel Process Technol 91(1):25–32CrossRef

Furimsky E (2000) Catalytic hydrodeoxygenation. Appl Catal A 199(2):147–190CrossRef

Gabra M, Pettersson E, Backman R et al (2001) Evaluation of cyclone gasifier performance for gasification of sugar cane residue-Part 1: gasification of bagasse. Biomass Bioenergy 21:351–369CrossRef

Garcia-Perez M, Chaala A, Pakdel H et al (2007) Characterization of bio-oils in chemical families. Biomass Bioenergy 31(4):222–242CrossRef

Garcìa-Pérez M, Chaala A, Pakdel H et al (2007) Vacuum pyrolysis of softwood and hardwood biomass: comparison between product yields and bio-oil properties. J Anal Appl Pyrol 78(1):104–116CrossRef

Gil J, Corella J, Aznar MP et al (1999) Biomass gasification in atmospheric and bubbling fluidized bed: effect of the type of gasifying agent on the product distribution. Biomass Bioenergy 17:389–403CrossRef

Graham R, Bergougnou M, Overend R (1984) Fast pyrolysis of biomass. J Anal Appl Pyrol 6(2):95–135CrossRef

Hasler XX (1997) Evaluation of gas cleaning technologies for small scale biomass gasifiers. Swiss Federal Office of Energy and Swiss Federal Office for Education and Science, Zurich

Hasler P, Nussbaumer T (1999) Gas cleaning for IC engine applications from fixed bed biomass gasification. Biomass Bioenergy 16:385–395CrossRef

Heesch BEJM, Paasen SV (2000) Pulsed corona tar cracker. IEEE Trans Plasma Sci 28:1571–1575CrossRef

Hristov JY, Stamatov V, Honnery DR et al. (2004) Radiant heating of a bio-oil droplet: a quest for a suitable most and scaling of pre-explosion conditions. In: 15th Australasian fluid mechanics conference, Sydney

Huber GW, Iborra S, Corma A (2006) Synthesis of transportation fuels from biomass: chemistry, catalysts, and engineering. Chem Rev 106(9):4044–4098CrossRef

Ikura M, Stanciulescu M, Hogan E (2003) Emulsification of pyrolysis derived bio-oil in diesel fuel. Biomass Bioenergy 24(3):221–232CrossRef

Iojoiu E, Domine M, Davidian T et al (2007) Hydrogen production by sequential cracking of biomass-derived pyrolysis oil over noble metal catalysts supported on ceria-zirconia. Appl Catal A 323:147–161CrossRef

Jana S (2004) Biomass technologies & experiences with biomass utilization. Final[R]

Jenkins BM, Baxter LL, Miles TR Jr et al (1998) Combustion properties of biomass. Fuel Process Technol 54:17–46CrossRef

Karhu K et al (2011) Biochar addition to agricultural soil increased CH₄ uptake and water holding capacity – results from a short-term pilot field study. Agric Ecosyst Environ 140:309–313CrossRef

Karlsson G, Ekström C (1994) The development of a biomass IGCC process for power and heat production. In: Proceedings of the eighth European conference on biomass for energy, environment, agriculture and industry, Vienna

Khan AA, de Jong W, Jansens PJ et al (2009) Biomass combustion in fluidized bed boilers: potential problems and remedies. Fuel Process Technol 90:21–50CrossRef

Knoef HAM (2000) Inventory of biomass gasifier manufacturers and installations. Final Report to European Commission, Contract DIS/1734/98-NL. Biomass Technology Group B.V., University of Twente, Enschede. http://www.gasifiers.org/

Knoef H (2001–2003) Technology brief: fixed-bed gasification. Task 33: thermal gasification of biomass. IEA Bioenergy Agreement. http://media.godashboard.com/gti/IEA/FixedBedGasificationr.pdf

Kumar VA, Anil KV, Pant KK (1997) Potassium-containing calcium aluminate catalysts for pyrolysis of n-heptane. Appl Catal A Gen 162:193–200CrossRef

Kurkela E (2000) PROGAS – gasification and pyrolysis R&D programme 1997–1999. In: Proceedings conference on power production from biomass III, gasification & pyrolysis R&D&D. VTT, Espoo

Lédé J (2003) Comparison of contact and radiant ablative pyrolysis of biomass. J Anal Appl Pyrol 70(2):601–618CrossRef

Li J, Xiao B, Liang DT et al (2008) Development of Nano-NiO/Al₂O₃ catalyst to be used for tar removal in biomass gasification. Environ Sci Technol 42:6224–6229CrossRef

Lu Q, Li W, Zhu X (2009a) Overview of fuel properties of biomass fast pyrolysis oils. Energy Convers Manag 50(5):1376–1383CrossRef

Lu Q, Xiong W, Li W et al (2009b) Catalytic pyrolysis of cellulose with sulfated metal oxides: a promising method for obtaining high yield of light furan compounds. Bioresour Technol 100(20):4871–4876CrossRef

Luke B, Marta M (2011) The immobilisation and retention of soluble arsenic, cadmium and zinc by biochar. Environ Pollut 159:474–480CrossRef

Luke B, Eduardo MJ, Jose LGE (2010) Effects of biochar and greenwaste compost amendments on mobility, bioavailability and toxicity of inorganic and organic contaminants in a multi-element polluted soil. Environ Pollut 158:2282–2287CrossRef

Luo Z, Wang S, Liao Y et al (2004) Research on biomass fast pyrolysis for liquid fuel. Biomass Bioenergy 26(5):455–462CrossRef

Ma L, Verelst H, Baron GV (2005) Integrated high temperature gas cleaning: tar removal in biomass gasification with a catalytic filter. Catal Today 105:729–734CrossRef

Miao X, Wu Q, Yang C (2004) Fast pyrolysis of microalgae to produce renewable fuels. J Anal Appl Pyrol 71(2):855–863CrossRef

Miccio F (1999) Gasification of two biomass fuels in bubbling fluidized bed. In: Proceedings of the 15th international conference on fluidized bed combustion, Savannah, pp 16–19

Milne T, Elam C, Evans R (2001) Hydrogen from biomass: state of the art and research challenges. NREL IEA/H2/TR-02/001

Mohan D, Pittman C, Steele P (2006) Pyrolysis of wood/biomass for bio-oil: a critical review. Energy Fuels 20(3):848–889CrossRef

Nielsen HP, Frandsen FJ, Dam-Johansen K et al (2000) The implications of chlorine-associated corrosion on the operation of biomass-fired boilers. Prog Energy Combust Sci 26:283–293CrossRef

Nishimura M, Iwasaki S, Horio M (2009) The role of potassium carbonate on cellulose pyrolysis. J Taiwan Inst Chem Eng 40(6):630–637CrossRef

Nowakowski D, Jones J, Brydson R et al (2007) Potassium catalysis in the pyrolysis behaviour of short rotation willow coppice. Fuel 86:2389–2402CrossRef

Ong Y, Bhatia S (2010) The current status and perspectives of biofuel production via catalytic cracking of edible and non-edible oils. Energy 35(1):111–119CrossRef

Paasen SVB, Rabou L (2004) Tar removal with wet ESP: parametric study. In: The second world conference and technology exhibition on biomass for energy, industry and climate Protection, Rome, pp 205–210

Park H, Park Y, Kim J (2008) Influence of reaction conditions and the char separation system on the production of bio-oil from radiate pine sawdust by fast pyrolysis. Fuel Process Technol 89:797–802CrossRef

Peláez-Samaniego M, Garcia-Perez M, Cortez L et al (2008) Improvements of Brazilian carbonization industry as part of the creation of a global biomass economy. Renew Sust Energy Rev 12(4):1063–1086CrossRef

Peterson A, Vogel F, Lachance R et al (2008) Thermochemical biofuel production in hydrothermal media: a review of sub- and supercritical water technologies. Energy Environ Sci 1:32–65CrossRef

Rapagna S, Jand N, Kiennemann A et al (2000) Steam-gasification of biomass in a fluidised-bed of olivine particles. Biomass Bioenergy 19:187–197CrossRef

Reinhard R (2002) Biomass gasification to produce synthesis gas for fuel cells, liquid fuels and chemicals. Task 33: thermal gasification of biomass (2001–2003). IEA Bioenergy Agreement. http://media.godashboard.com/gti/IEA/TechnologybriefSynthesisGas.pdf

Sami M, Annamalai K, Wooldridge M (2001) Co-firing of coal and biomass fuel blends. Prog Energy Combust Sci 27:171–214CrossRef

Shimada N, Kawamoto H, Saka S (2008) Different action of alkali/alkaline earth metal chlorides on cellulose pyrolysis. J Anal Appl Pyrol 81(1):80–87CrossRef

Song YJ, Gong J (2010) Effects of biochar application on soil ecosystem functions. Ludong Univ J Nat Sci Ed 26(4):361–365

Stahl K, Neergaard M, Nieminen J (2001) Final report: Varnamo demonstration programme. In: Bridgwater AV (ed) Progress in thermochemical biomass conversion. Blackwell Science, London, pp 549–563CrossRef

Tamunaidu P, Bhatia S (2007) Catalytic cracking of palm oil for the production of biofuels: optimization studies. Bioresour Technol 98(18):3593–3601CrossRef

Tillman DA (2000) Biomass cofiring: the technology, the experience, the combustion consequences. Biomass Bioenergy 19:365–384CrossRef

Tomishige K, Asadullah M, Kunimori K (2005) Novel catalyst with high resistance to sulfur for hot gas cleaning at low temperature by partial oxidation of tar derived from biomass. Catal Commun 6:37–40CrossRef

Uzun B, Pütün A, Pütün E (2007) Composition of products obtained via fast pyrolysis of olive-oil residue: effect of pyrolysis temperature. J Anal Appl Pyrol 79:147–153CrossRef

van den Broek R, Faaij A, van Wijk A (1995) Biomass combustion power generation technologies [R]. Energy from biomass: an assessment of two promising systems for energy production. http://www.projects.science.uu.nl/nws/publica/95029.htm

van Loo S (2004) Biomass combustion and cofiring [R]. Task 32, IEA Bioenergy

van Loo S, Koppejan J (2008) Handbook of biomass combustion and co-firing [M]. Earthscan, London

Van RR, Oudhuis ABJ, Faaij A (1995) Modelling of a biomass-integrated-gasifier/combined-cycle (BIG-CC) system with the flowsheet simulation program Aspen-plus. Netherlands Energy Research Foundation ECN, Petten

Venderbosch RH, Prins W (1998) Entrained flow gasification of bio-oil for synthesis gas. BTG Biomass Technology Group b.v. University of Twente

Wagenaar BM, Prins W, van Swaaij WPM (1994) Pyrolysis of biomass in the rotating cone reactor: modeling and experimental justification. Chem Eng Sci 49(24):5109–5126CrossRef

Waldheim L, Morris M, Leal M et al (2001) Biomass power generation: sugar cane bagasse and trash. In: Bridgwater AV (ed) Progress in thermochemical biomass conversion. Blackwell Science, London, pp 509–523CrossRef

Wang J, Zhang M, Chen M et al (2006) Catalytic effects of six inorganic compounds on pyrolysis of three kinds of biomass. Thermochim Acta 444:110–114CrossRef

Wang LJ, Weller CL, Jones DD et al (2008) Contemporary issues in thermal gasification of biomass and its application to electricity and fuel production. Biomass Bioenergy 32:573–581CrossRef

Wang M, Leitch M, Xu C (2009a) Synthesis of phenolic resol resins using cornstalk-derived bio-oil produced by direct liquefaction in hot-compressed phenol-water. J Ind Eng Chem 15(6):870–875CrossRef

Wang M, Leitch M, Xu C (2009b) Synthesis of phenol-formaldehyde resol resins using organosolv pine lignins. Eur Polym J 45(12):3380–3388CrossRef

Werther J, Saenger M, Hartge EU et al (2000) Combustion of agricultural residues. Prog Energy Combust Sci 26:1–27CrossRef

Xu J, Jiang J, Sun Y et al (2008) Bio-oil upgrading by means of ethyl ester production in reactive distillation to remove water and to improve storage and fuel characteristics. Biomass Bioenergy 32(11):1056–1061CrossRef

Yin CG, Lasse AR, Søren KK (2008) Grate-firing of biomass for heat and power production. Prog Energy Combust Sci 34:725–754CrossRef

Yu CJ, Qin JG, Xu J et al (2010) Straw combustion in circulating fluidized bed at low temperature: transformation and distribution of potassium. Can J Chem Eng 88:875–880CrossRef

Yuan JH, Xu RK (2010) Effects of rice-hull-based biochar regulating acidity of red sail and yellow brown soil. J Ecol Rural Environ 26(5):472–476

Zainal ZA, Rifau A, Quadir GA et al (2002) Experimental investigation of a downdraft biomass gasifier. Biomass Bioenergy 23:283–289CrossRef

Zhang XD (2003) The mechanism of tar cracking by catalyst and the gasification of biomass. The dissertation of Zhejiang University

Zhang Q, Chang J, Wang T et al (2007) Review of biomass pyrolysis oil properties and upgrading research. Energy Convers Manag 48(1):87–92CrossRef

Zhang WL, Li GH, Gao WD (2009) Effect of biomass charcoal on soil character and crop yield. Chin Agric Sci Bull 25(17):153–157

Zhao H (2007) PHD thesis in experimental and theoretical research on entrained flow gasification of biomass for syn-gas, Zhejiang University

Zhao M, Florin N, Harris A (2009) The influence of supported Ni catalysts on the product gas distribution and H2 yield during cellulose pyrolysis. Appl Catal B 92:185–193CrossRef

Zheng J (2007) Bio-oil from fast pyrolysis of rice husk: yields and related properties and improvement of the pyrolysis system. J Anal Appl Pyrol 80(1):30–35CrossRef

Zheng J, Yi W, Wang N (2008) Bio-oil production from cotton stalk. Energy Convers Manag 49(6):1724–1730CrossRef

Zhu XF, Lu Q (2010) In: Maggy Ndombo Benteke Momba (ed) Production of chemicals from selective fast pyrolysis of biomass, biomass. Sciyo. ISBN: 978-953-307-113-8

Title: Thermal Conversion of Biomass
Authors: Zhongyang Luo
Jingsong Zhou
Publisher: Springer International Publishing
Book: Handbook of Climate Change Mitigation and Adaptation
Print ISBN: 978-3-319-14408-5

Electronic ISBN: 978-3-319-14409-2

Copyright Year: 2017
DOI: https://doi.org/10.1007/978-3-319-14409-2_27