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Journal of Polymer Research

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01-09-2015 | Original Paper

Thermally mendable material based on a furyl-telechelic semicrystalline polymer and a maleimide crosslinker

Authors: Le-Thu T. Nguyen, Ha Tran Nguyen, Thuy Thu Truong

Published in: Journal of Polymer Research | Issue 9/2015

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Abstract

Based on Diels-Alder reaction, a furyl-telechelic semicrystalline polycaprolactone was crosslinked by a tris-maleimide crosslinker. The synthesized precursors and network were fully characterized via proton nuclear magnetic resonance (¹H NMR) and Fourier transform infrared (FT-IR) spectroscopies, gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and wide-angle powder X-ray diffraction (XRD) measurements. The obtained material showed mendability of scratches under thermal treatment, as evidenced by optical microscopy and tensile analysis. The mending process was a combination of the shape recovery effect favoring scratch closure and the re-crosslinking of the cleaved Diels-Alder bonds at temperatures slightly above the melting transition of polycaprolactone chains. A scratch healing efficiency determined by tensile tests of about 70 % was achieved.

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Title: Thermally mendable material based on a furyl-telechelic semicrystalline polymer and a maleimide crosslinker
Authors: Le-Thu T. Nguyen
Ha Tran Nguyen
Thuy Thu Truong
Publication date: 01-09-2015
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 9/2015
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-015-0827-y

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