Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2015

01.09.2015 | Original Paper

Thermally mendable material based on a furyl-telechelic semicrystalline polymer and a maleimide crosslinker

verfasst von: Le-Thu T. Nguyen, Ha Tran Nguyen, Thuy Thu Truong

Erschienen in: Journal of Polymer Research | Ausgabe 9/2015

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Based on Diels-Alder reaction, a furyl-telechelic semicrystalline polycaprolactone was crosslinked by a tris-maleimide crosslinker. The synthesized precursors and network were fully characterized via proton nuclear magnetic resonance (1H NMR) and Fourier transform infrared (FT-IR) spectroscopies, gel permeation chromatography (GPC), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and wide-angle powder X-ray diffraction (XRD) measurements. The obtained material showed mendability of scratches under thermal treatment, as evidenced by optical microscopy and tensile analysis. The mending process was a combination of the shape recovery effect favoring scratch closure and the re-crosslinking of the cleaved Diels-Alder bonds at temperatures slightly above the melting transition of polycaprolactone chains. A scratch healing efficiency determined by tensile tests of about 70 % was achieved.
Vorheriger Artikel Preparation and characterization of mechanically and thermally enhanced polyimide/reactive halloysite nanotubes nanocomposites
Nächster Artikel Erratum to: Fabrication of graphite-graphene-ionic liquid modified carbon nanotubes filled natural rubber thin films for microwave and energy storage applications

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Blaiszik BJ, Kramer SLB, Olugebefola SC, Moore JS, Sottos NR, White SR (2010) Self-healing polymers and composites. Annu Rev Mater Res 40:179–211CrossRef
2.
Hillewaere XKD, Teixeira RFA, Nguyen L-TT, Ramos JA, Rahier H, Du Prez FE (2014) Autonomous self-healing of epoxy thermosets with thiol-isocyanate chemistry. Adv Funct Mater 24:5575–5583CrossRef
3.
Fereidoon A, Ghorbanzadeh Ahangari M, Jahanshahi M (2013) Effect of nanoparticles on the morphology and thermal properties of self-healing poly(urea-formaldehyde) microcapsules. J Polym Res 20:1–8CrossRef
4.
Rahimi A, Amiri S (2014) Self-healing hybrid nanocomposite coatings with encapsulated organic corrosion inhibitors. J Polym Res 22:1–8
5.
6.
Zhang Y, v Y-h, Zhang Z-p (2015) The influence of 2,4-toluene diisocyanate content on the intrinsic self-healing performance of polyurethane at room-temperature. J Polym Res 22:1–6CrossRef
7.
Cheng C, Bai X, Zhang X, Li H, Huang Q, Tu Y (2015) Self-healing polymers based on a photo-active reversible addition-fragmentation chain transfer (RAFT) agent. J Polym Res 22:1–8CrossRef
8.
Zhang MQ, Rong MZ (2013) Intrinsic self-healing of covalent polymers through bond reconnection towards strength restoration. Polym Chem 4:4878–4884CrossRef
9.
Liu Y-L, Chuo T-W (2013) Self-healing polymers based on thermally reversible Diels-Alder chemistry. Polym Chem 4:2194–2205CrossRef
10.
Mignard N, Okhay N, Jegat C, Taha M (2013) Facile elaboration of polymethylmethacrylate / polyurethane interpenetrating networks using Diels-Alder reactions. J Polym Res 20:1–13CrossRef
11.
Chen X, Dam MA, Ono K, Mal A, Shen H, Nutt SR, Sheran K, Wudl F (2002) A thermally re-mendable cross-linked polymeric material. Science 295:1698–1702CrossRef
12.
Tasdelen MA (2011) Diels-Alder “click” reactions: recent applications in polymer and material science. Polym Chem 2:2133–2145CrossRef
13.
Tian Q, Yuan YC, Rong MZ, Zhang MQ (2009) A thermally remendable epoxy resin. J Mater Chem 19:1289–1296CrossRef
14.
Zhang Y, Broekhuis AA, Picchioni F (2009) Thermally self-healing polymeric materials: the next step to recycling thermoset polymers? Macromolecules 42:1906–1912CrossRef
15.
Kavitha AA, Singha NK (2009) “Click chemistry” in tailor-made polymethacrylates bearing reactive furfuryl functionality: a new class of self-healing polymeric material. ACS Appl Mater Interfaces 1:1427–1436CrossRef
16.
Scheltjens G, Diaz MM, Brancart J, Assche GV, Mele BV (2013) A self-healing polymer network based on reversible covalent bonding. React Funct Polym 73:413–420CrossRef
17.
Bose RK, Kötteritzsch J, Garcia SJ, Hager MD, Schubert US, van der Zwaag S (2014) A rheological and spectroscopic study on the kinetics of self-healing in a single-component diels–alder copolymer and its underlying chemical reaction. J Polym Sci Part A Polym Chem 52:1669–1675CrossRef
18.
Lendlein A, Sauter T (2013) Shape-memory effect in polymers. Macromol Chem Phys 214:1175–1177CrossRef
19.
Lendlein A, Kelch S (2002) Shape-memory polymers. Angew Chem Int Ed 41:2034–2057CrossRef
20.
Lendlein A, Behl M, Hiebl B, Wischke C (2010) Shape-memory polymers as a technology platform for biomedical applications. Expert Rev Med Devices 7:357–379CrossRef
21.
Leng J, Lan X, Liu Y, Du S (2011) Shape-memory polymers and their composites: stimulus methods and applications. Prog Mater Sci 56:1077–1135CrossRef
22.
Xu H, Yu C, Wang S, Malyarchuk V, Xie T, Rogers JA (2013) Deformable, programmable, and shape-memorizing micro-optics. Adv Funct Mater 23:3299–3306CrossRef
23.
Behl M, Razzaq MY, Lendlein A (2010) Multifunctional shape-memory polymers. Adv Mater 22:3388–3410CrossRef
24.
Kirkby EL, Rule JD, Michaud VJ, Sottos NR, White SR, Månson J-AE (2008) Embedded shape-memory alloy wires for improved performance of self-healing polymers. Adv Funct Mater 18:2253–2260CrossRef
25.
Kirkby EL, Michaud VJ, Månson JAE, Sottos NR, White SR (2009) Performance of self-healing epoxy with microencapsulated healing agent and shape memory alloy wires. Polymer 50:5533–5538CrossRef
26.
Li G, Zhang P (2013) A self-healing particulate composite reinforced with strain hardened short shape memory polymer fibers. Polymer 54:5075–5086CrossRef
27.
Li G, Ajisafe O, Meng H (2013) Effect of strain hardening of shape memory polymer fibers on healing efficiency of thermosetting polymer composites. Polymer 54:920–928CrossRef
28.
Rodriguez ED, Luo X, Mather PT (2011) Linear/network poly(ε-caprolactone) blends exhibiting Shape Memory Assisted Self-Healing (SMASH). ACS Appl Mater Interfaces 3:152–161CrossRef
29.
Luo X, Mather PT (2013) Shape memory assisted self-healing coating. ACS Macro Lett 2:152–156CrossRef
30.
García-Huete N, Laza J, Cuevas J, Gonzalo B, Vilas J, León L (2014) Shape memory effect for recovering surface damages on polymer substrates. J Polym Res 21:1–10CrossRef
31.
Zhang J, Niu Y, Huang C, Xiao L, Chen Z, Yang K, Wang Y (2012) Self-healable and recyclable triple-shape PPDO-PTMEG co-network constructed through thermoreversible Diels-Alder reaction. Polym Chem 3:1390–1393CrossRef
32.
Rivero G, Nguyen L-TT, Hillewaere XKD, Du Prez FE (2014) One-Pot thermo-remendable shape memory polyurethanes. Macromolecules 47:2010–2018CrossRef
33.
Lu X, Fei G, Xia H, Zhao Y (2014) Ultrasound healable shape memory dynamic polymers. J Mater Chem A 2:16051–16060CrossRef
34.
Heo Y, Sodano HA (2014) Self-healing polyurethanes with shape recovery. Adv Funct Mater 24:5261–5268CrossRef
35.
Woodruff MA, Hutmacher DW (2010) The return of a forgotten polymer—Polycaprolactone in the 21st century. Prog Polym Sci 35:1217–1256CrossRef
36.
Narita M, Teramoto T, Okawara M (1971) Syntheses and reactions of functional polymers. LIV. Syntheses and polymerizations of O-substituted-N-hydroxymaleimides. Bull Chem Soc Jpn 44:1084–1089CrossRef
37.
Nguyen L-TT, Gokmen MT, Du Prez FE (2013) Kinetic comparison of 13 homogeneous thiol-X reactions. Polym Chem 4:5527–5536CrossRef
38.
Mellouki A, Herman M, Demaison J, Lemoine B, Margulès L (1999) Rotational analysis of the ν7 band in furan (C4H4O). J Mol Spectrosc 198:348–357CrossRef
39.
Mani R, Bhattacharya M (2001) Properties of injection moulded blends of starch and modified biodegradable polyesters. Eur Polym J 37:515–526CrossRef
Metadaten
Titel
Thermally mendable material based on a furyl-telechelic semicrystalline polymer and a maleimide crosslinker
verfasst von
Le-Thu T. Nguyen
Ha Tran Nguyen
Thuy Thu Truong
Publikationsdatum
01.09.2015
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2015
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-015-0827-y

Weitere Artikel der Ausgabe 9/2015

Journal of Polymer Research 9/2015 Zur Ausgabe

Original Paper

Processing and characterization of thermoplastic starch/polycaprolactone/compatibilizer ternary blends for packaging applications

Original Paper

A novel surface modification for calcium sulfate whisker used for reinforcement of poly(vinyl chloride)

Original Paper

Synthesis, spectroscopic characterization, thermal stability and compatibility properties of energetic PVB-g-GAP copolymers

Original Paper

Controlled properties of high-impact polypropylene in-reactor alloys by tailoring chemical structure and morphology

Original Paper

Synthesis and characterization of novel highly soluble and optical transparent polyimides containing tert-butyl and morpholinyl moieties

Original Paper

Hydrodynamic behavior of quaternized chitosan at acidic and neutral pH

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise