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Erschienen in: Journal of Polymer Research 9/2015

01.09.2015 | Original Paper

A novel surface modification for calcium sulfate whisker used for reinforcement of poly(vinyl chloride)

verfasst von: Wenjin Yuan, Jiayang Cui, Yangben Cai, Shiai Xu

Erschienen in: Journal of Polymer Research | Ausgabe 9/2015

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Abstract

A novel technique is developed in this study to modify the surface of calcium sulfate whisker (CSW) for the preparation of high-performance CSW/poly(vinyl chloride) (PVC) composites. The CSW coated with poly(vinyl alcohol) (PVA) and then cross-linked by glutaraldehyde is used to strengthen PVC, and the surface morphology and mechanical properties of CSW/PVC composites are investigated. It shows that the mechanical properties of the cross-linked PVA modified CSW/PVC (cPVA@CSW/PVC) composites are significantly improved, their yield strength, breaking strength, tensile modulus and elongation at break are 65.7 MPa, 53.5 MPa, 1772 MPa and 225 %, with an increase of 7.2, 13.1, 7.6 and 8.2 % as compared with that of the unmodified CSW/PVC composites, respectively. The improvement in the mechanical properties can be attributed to the strong interfacial adhesion between cPVA@CSW and PVC matrix, because the modified CSW has abundant hydroxyl groups that can produce a strong interaction with PVC. This method is simple and inexpensive, and can be applied in large scale.

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Metadaten
Titel
A novel surface modification for calcium sulfate whisker used for reinforcement of poly(vinyl chloride)
verfasst von
Wenjin Yuan
Jiayang Cui
Yangben Cai
Shiai Xu
Publikationsdatum
01.09.2015
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2015
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-015-0813-4

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