Top

Cellulose

Published in:

06-01-2021 | Original Research

Thermo-responsive cotton fabric prepared by enzyme-initiated “graft from” polymerization for moisture/thermal management

Authors: Yunxian Yang, Xueming Bao, Qiang Wang, Ping Wang, Man Zhou, Yuanyuan Yu

Published in: Cellulose | Issue 3/2021

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Thermo-responsive textiles with moisture/thermal management characteristics have attracted extensive attention for the purpose of improving human comfort or special job requirements. In this study, a thermo-responsive cotton (TR-cotton) fabric for moisture/thermal management was prepared by horseradish peroxidase/acetylacetone (ACAC)/hydrogen peroxide (H₂O₂)-initiated “graft from” polymerization on the fiber surface. Enzymatic graft polymerization is a new environmentally friendly method to prepare thermo-responsive textiles. Diethylene glycol monomethyl ether methacrylate (MEO₂MA) and poly(ethylene glycol) methyl ether methacrylate (OEGMA₅₀₀) were selected as thermosensitive monomers for graft copolymerization. The lower critical solution temperature (LCST) of P(MEO₂MA-co-OEGMA₅₀₀) was 29 °C. TR-cotton was hydrophilic at ambient temperature below the LCST and hydrophobic at a temperature above the LCST. The air/moisture permeability of TR-cotton at a high temperature (> LCST) was better than that at a low temperature (< LCST). In a cold environment, the fabric exhibited a heat preservation effect (~ 1.5 °C warmer than that observed for unmodified cotton fabric). This study could provide an enzyme catalysis method for the development of “smart textiles”.

previous article A novel flame retardant based on polyhydric alcohols and P–N synergy for treatment of cotton fabrics

next article Durable flame retardant and water repellent cotton fabric based on synergistic effect of ferrocene and DOPO

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Bauri K, Pan A, Haldar U, Narayanan A, De P (2016) Exploring amino acid-tethered polymethacrylates as CO₂-sensitive macromolecules: a concealed property. J Polym Sci Pol Chem 54:2794–2803. https://doi.org/10.1002/pola.28165CrossRef

Brinchi L, Cotana F, Fortunati E, Kenny JM (2013) Production of nanocrystalline cellulose from lignocellulosic biomass: technology and applications. Carbohyd Polym 94:154–169. https://doi.org/10.1016/j.carbpol.2013.01.033CrossRef

Cheng H et al (2018) Flexible cellulose-based thermoelectric sponge towards wearable pressure sensor and energy harvesting. Chem Eng J 338:1–7. https://doi.org/10.1016/j.cej.2017.12.134CrossRef

Dalgakiran E, Tatlipinar H (2017) Atomistic insights on the LCST behavior of PMEO₂MA in water by molecular dynamics simulations. J Polym Sci 56:429–441. https://doi.org/10.1002/polb.24555CrossRef

Derango RA, Chiang L-c, Dowbenko R, Lasch JG (1992) Enzyme-mediated polymerization of acrylic monomers. Biotechnol Tech 6:523–526. https://doi.org/10.1007/BF02447825CrossRef

Durand A, Lalot T, Brigodiot M, Maréchal E (2001) Enzyme-mediated radical initiation of acrylamide polymerization: main characteristics of molecular weight control. Polymer 42:5515–5521. https://doi.org/10.1016/S0032-3861(01)00041-6CrossRef

Gu P, Fan N, Wang Y, Wang J, Buschbaum MP, Zhong Q (2019) Linear control of moisture permeability and anti-adhesion of bacteria in a broad temperature region realized by cross-linking thermoresponsive microgels onto cotton fabrics. ACS Appl Mater Int 11:30269–30277. https://doi.org/10.1021/acsami.9b09294CrossRef

Huang S, Liu X, Chang C, Wang Y (2020) Recent developments and prospective food-related applications of cellulose nanocrystals: a review. Cellulose 27:2991–3011. https://doi.org/10.1007/s10570-020-02984-3CrossRef

Islam GMN, Ali A, Collie S (2020) Textile sensors for wearable applications: a comprehensive review. Cellulose 27:6103–6131. https://doi.org/10.1007/s10570-020-03215-5CrossRef

Johnson HL, Clark RA (1948) Correction. Procedure of determination of the bromine number of olefinic hydrocarbons. Anal Chem 20:490. https://doi.org/10.1021/ac60017a601CrossRef

Kocak G, Tuncer C, Bütün V (2017) pH-responsive polymers. Polym Chem 8:144–176. https://doi.org/10.1039/C6PY01872FCrossRef

Liu G, Wang W, Yu D (2019) Robust and self-healing superhydrophobic cotton fabric via UV induced click chemistry for oil/water separation. Cellulose 26:3529–3541. https://doi.org/10.1007/s10570-019-02289-0CrossRef

Lutz J-F, Weichenhan K, Akdemir Z, Hoth A (2007) About the phase transitions in aqueous solutions of thermoresponsive copolymers and hydrogels based on 2-(2-methoxyethoxy) ethyl methacrylate and oligo(ethylene glycol) methacrylate. Macromolecules 40:2503–2508. https://doi.org/10.1021/ma062925qCrossRef

Ma L, Kang H, Liu R, Huang Y (2010) Smart assembly behaviors of hydroxypropylcellulose-graft-poly(4-vinyl pyridine) copolymers in aqueous solution by thermo and pH stimuli. Langmuir 26:18519–18525. https://doi.org/10.1021/la103854bCrossRefPubMed

Pan Y, Liu L, Zhang Y, Song L, Hu Y, Jiang S, Zhao H (2019) Effect of genipin crosslinked layer-by-layer self-assembled coating on the thermal stability, flammability and wash durability of cotton fabric. Carbohyd Polym 206:396–402. https://doi.org/10.1016/j.carbpol.2018.11.037CrossRef

Pinho E, Soares G (2018) Functionalization of cotton cellulose for improved wound healing. J Mater Chem B 6:1887–1898. https://doi.org/10.1039/C8TB00052BCrossRefPubMed

Rong L et al (2019) Durable antibacterial and hydrophobic cotton fabrics utilizing enamine bonds. Carbohyd Polym 211:173–180. https://doi.org/10.1016/j.carbpol.2019.01.103CrossRef

Santos AC, Alves S, Godinho MH, Baleizão C, Farinha JPS (2018) Temperature-responsive fibres of cellulose-based copolymers. Polym Chem 9:3615–3623. https://doi.org/10.1039/c8py00524aCrossRef

Schumers JM, Fustin CA, Gohy JF (2010) Light-responsive block copolymers. Macromol Rapid Commun 31:1588–1607. https://doi.org/10.1002/marc.201000108CrossRefPubMed

Shoda SI, Uyama H, Kadokawa JI, Kimura S, Kobayashi S (2016) Enzymes as green catalysts for precision macromolecular synthesis. Chem Rev 116:2307–2413. https://doi.org/10.1021/acs.chemrev.5b00472CrossRefPubMed

Teixeira D, Lalot T, Brigodiot M, Maréchal E (1999) β-Diketones as key compounds in free-radical polymerization by enzyme-mediated initiation. Macromolecules 32:70–72. https://doi.org/10.1021/ma980872CrossRef

Ulrich S et al (2017) Visible light-responsive DASA-polymer conjugates. ACS Macro Lett 6:738–742. https://doi.org/10.1021/acsmacrolett.7b00350CrossRef

Vancoillie G, Frank D, Hoogenboom R (2014) Thermoresponsive poly(oligo ethylene glycol acrylates). Prog Polym Sci 39:1074–1095. https://doi.org/10.1016/j.progpolymsci.2014.02.005CrossRef

Wang J, Chen Y, An J, Xu K, Chen T, Müller-Buschbaum P, Zhong Q (2017) Intelligent textiles with comfort regulation and inhibition of bacterial adhesion realized by cross-linking poly(n-isopropylacrylamide-co-ethylene glycol methacrylate) to cotton fabrics. ACS Appl Mater Inter 9:13647–13656. https://doi.org/10.1021/acsami.7b01922CrossRef

Wang W, Yu Y, Wang P, Wang Q, Li Y, Yuan J (2019a) Controlled graft polymerization on the surface of filter paper via enzyme-initiated RAFT polymerization. Carbohyd Polym 207:239–245. https://doi.org/10.1016/j.carbpol.2018.11.095CrossRef

Wang Y, Liang X, Zhu H, Xin JH, Zhang Q, Zhu S (2019b) Reversible water transportation diode: temperature-adaptive smart Janus textile for moisture/thermal management. Adv Funct Mater 30:1907851. https://doi.org/10.1002/adfm.2019b07851CrossRef

Welinder KG (1976) Covalent structure of the glycoprotein horseradish peroxidase (EC 1.11.1.7). FEBS Lett 72:19–23. https://doi.org/10.1016/0014-5793(76)80804-6CrossRefPubMed

Wu H et al (2017) Hydrophobic functionalization of jute fabrics by enzymatic-assisted grafting of vinyl copolymers. New J Chem 41:3373–3780. https://doi.org/10.1039/C7NJ00613FCrossRef

Wu S-W, Liu X, Miller II ALM, Cheng Y-S, Yeh M-L, Lu L (2018) Strengthening injectable thermo-sensitive NIPAAm-g-chitosan hydrogels using chemical cross-linking of disulfide bonds as scaffolds for tissue engineering. Carbohyd Polym 192:308–316. https://doi.org/10.1016/j.carbpol.2018.03.047CrossRef

Xiong M, Ren Z, Liu W (2019) Fabrication of UV-resistant and superhydrophobic surface on cotton fabric by functionalized polyethyleneimine/SiO₂ via layer-by-layer assembly and dip-coating. Cellulose 26:8951–8962. https://doi.org/10.1007/s10570-019-02705-5CrossRef

Yan G, Chen B, Zeng X, Sun Y, Tang X, Lin L (2020) Recent advances on sustainable cellulosic materials for pharmaceutical carrier applications. Carbohyd Polym 244:116492. https://doi.org/10.1016/j.carbpol.2020.116492CrossRef

Yu Y, Sun X, Zhang R, Yuan S, Lu Q, Wu Z (2017) Synthesis and properties of amphiphilic thermo-sensitive block copolymers. J Polym Res 24:55. https://doi.org/10.1007/s10965-017-1219-2CrossRef

Zarrintaj P et al (2019) Thermo-sensitive polymers in medicine: A review. Eur Polym J 117:402–423. https://doi.org/10.1016/j.eurpolymj.2019.05.024CrossRef

Zhang H, Niu Q, Wang N, Nie J, Ma G (2015) Thermo-sensitive drug controlled release PLA core/PNIPAM shell fibers fabricated using a combination of electrospinning and UV photo-polymerization. Eur Polym J 71:440–450. https://doi.org/10.1016/j.eurpolymj.2015.08.023CrossRef

Zhong Q et al (2019) Enhanced stain removal and comfort control achieved by cross-linking light and thermo dual-responsive copolymer onto cotton fabrics. ACS Appl Mater Inter 11:5414–5426. https://doi.org/10.1021/acsami.8b19908CrossRef

Title: Thermo-responsive cotton fabric prepared by enzyme-initiated “graft from” polymerization for moisture/thermal management
Authors: Yunxian Yang
Xueming Bao
Qiang Wang
Ping Wang
Man Zhou
Yuanyuan Yu
Publication date: 06-01-2021
Publisher: Springer Netherlands
Published in: Cellulose / Issue 3/2021
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-020-03626-4

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Other articles of this Issue 3/2021

Durable flame retardant and water repellent cotton fabric based on synergistic effect of ferrocene and DOPO

Influence of polysiloxane microspheres on hydrophobicity, structure and mechanical properties of paper materials

Reliability of cotton fiber length distributions measured by dual-beard fibrography and advanced fiber information system

Blending effects and performance of ring-, rotor-, and air-jet-spun color-blended viscose yarns

Changes in the cell wall components produced by exogenous abscisic acid treatment in strawberry fruit

Particle size distributions for cellulose nanocrystals measured by atomic force microscopy: an interlaboratory comparison