Skip to main content
Top
Published in: Journal of Materials Engineering and Performance 9/2012

01-09-2012

Tobacco Stem-Based Activated Carbons for High Performance Supercapacitors

Authors: Xiaohong Xia, Hongbo Liu, Lei Shi, Yuede He

Published in: Journal of Materials Engineering and Performance | Issue 9/2012

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Tobacco stem-based activated carbons (TS-ACs) were prepared by simple KOH activation and their application as electrodes in the electrical double layer capacitor (EDLC) performed successfully. The BET surface area, pore volume, and pore size distribution of the TS-ACs were evaluated based on N2 adsorption isotherms at 77 K. The surface area of the obtained activated carbons varies over a wide range (1472.8-3326.7 m2/g) and the mesoporosity was enhanced significantly as the ratio of KOH to tobacco stem (TS) increased. The electrochemical behaviors of series TS-ACs were characterized by means of galvanostatic charging/discharging, cyclic voltammetry, and impedance spectroscopy. The correlation between electrochemical properties and pore structure was investigated. A high specific capacitance value as 190 F/g at 1 mA/cm2 was obtained in 1 M LiPF6-EC/DMC/DEC electrolyte solution. Furthermore, good performance is also achieved even at high current densities. A development of new use for TS into a valuable energy storage material is explored.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference A.G. Pandolfo and A.F. Hollenkamp, Carbon Properties and Their Role In Supercapacitors, J. Power Sour., 2006, 157, p 11–27CrossRef A.G. Pandolfo and A.F. Hollenkamp, Carbon Properties and Their Role In Supercapacitors, J. Power Sour., 2006, 157, p 11–27CrossRef
2.
go back to reference T.E. Rufford, D. Hulicova-Jurcakova, E. Fiset et al., Double-Layer Capacitance of Waste Coffee Ground Activated Carbons in an Organic Electrolyte, Electrochem. Commun., 2009, 11, p 974–977CrossRef T.E. Rufford, D. Hulicova-Jurcakova, E. Fiset et al., Double-Layer Capacitance of Waste Coffee Ground Activated Carbons in an Organic Electrolyte, Electrochem. Commun., 2009, 11, p 974–977CrossRef
3.
go back to reference B.P. Bakhmatyuk, B.Y. Venhryn, I.I. Grygorchak et al., Influence of Chemical Modification of Activated Carbon Surface on Characteristics of Supercapacitors, J. Power Sour., 2008, 180, p 890–895CrossRef B.P. Bakhmatyuk, B.Y. Venhryn, I.I. Grygorchak et al., Influence of Chemical Modification of Activated Carbon Surface on Characteristics of Supercapacitors, J. Power Sour., 2008, 180, p 890–895CrossRef
4.
go back to reference E.J. Ra, E. Raymundo-Pinero, Y.H. Lee, and F. Beguin, High Power Supercapacitors Using Polyacrylonitrile-Based Carbon Nanofiber Paper, Carbon, 2009, 47, p 2984–2992CrossRef E.J. Ra, E. Raymundo-Pinero, Y.H. Lee, and F. Beguin, High Power Supercapacitors Using Polyacrylonitrile-Based Carbon Nanofiber Paper, Carbon, 2009, 47, p 2984–2992CrossRef
5.
go back to reference H. Yamada, I. Moriguchi, and T. Kudo, Electric Double Layer Capacitance on Hierarchical Porous Carbons in an Organic Electrolyte, J. Power Sour., 2008, 175, p 651–656CrossRef H. Yamada, I. Moriguchi, and T. Kudo, Electric Double Layer Capacitance on Hierarchical Porous Carbons in an Organic Electrolyte, J. Power Sour., 2008, 175, p 651–656CrossRef
6.
go back to reference J.H. Jiang, Q.M. Gao, K.Sh. Xia, and J. Hu, Enhanced Electrical Capacitance of Porous Carbons by Nitrogen Enrichment and Control of the Pore Structure, Microporous Mesoporous Mater., 2009, 118, p 28–34CrossRef J.H. Jiang, Q.M. Gao, K.Sh. Xia, and J. Hu, Enhanced Electrical Capacitance of Porous Carbons by Nitrogen Enrichment and Control of the Pore Structure, Microporous Mesoporous Mater., 2009, 118, p 28–34CrossRef
7.
go back to reference H.Q. Li, R.L. Liu, D.Y. Zhao, and Y.Y. Xia, Electrochemical Properties of an Ordered Mesoporous Carbon Prepared by Direct Tri-Constituent Co-Assembly, Carbon, 2007, 45, p 2628–2635CrossRef H.Q. Li, R.L. Liu, D.Y. Zhao, and Y.Y. Xia, Electrochemical Properties of an Ordered Mesoporous Carbon Prepared by Direct Tri-Constituent Co-Assembly, Carbon, 2007, 45, p 2628–2635CrossRef
8.
go back to reference L.X. Li, H.H. Song, and X.H. Chen, Ordered Mesoporous Carbons from the Carbonization of Sulfuric-Acid-Treated Silica/Triblock Copolymer/Sucrose Composites, Microporous Mesoporous Mater., 2006, 94, p 9–14CrossRef L.X. Li, H.H. Song, and X.H. Chen, Ordered Mesoporous Carbons from the Carbonization of Sulfuric-Acid-Treated Silica/Triblock Copolymer/Sucrose Composites, Microporous Mesoporous Mater., 2006, 94, p 9–14CrossRef
9.
go back to reference F. Zhang, H. Ma, J. Chen et al., Preparation and Gas Storage of High Surface Area Microporous Carbon Derived from Biomass Source Cornstalks, Bioresour. Technol., 2008, 99, p 4803–4808CrossRef F. Zhang, H. Ma, J. Chen et al., Preparation and Gas Storage of High Surface Area Microporous Carbon Derived from Biomass Source Cornstalks, Bioresour. Technol., 2008, 99, p 4803–4808CrossRef
10.
go back to reference D. Kalpana, S.H. Cho, S.B. Lee et al., Recycled Waste Paper—A New Source of Raw Material for Electric Double-Layer Capacitors, J. Power Sour., 2009, 190, p 587–591CrossRef D. Kalpana, S.H. Cho, S.B. Lee et al., Recycled Waste Paper—A New Source of Raw Material for Electric Double-Layer Capacitors, J. Power Sour., 2009, 190, p 587–591CrossRef
11.
go back to reference T.C. Chandra, M.M. Mirna, and J. Sunarso, Activated Carbon from Durian Shell: Preparation and Characterization, J. Taiwan Inst. Chem. Eng., 2009, 40, p 457–462CrossRef T.C. Chandra, M.M. Mirna, and J. Sunarso, Activated Carbon from Durian Shell: Preparation and Characterization, J. Taiwan Inst. Chem. Eng., 2009, 40, p 457–462CrossRef
12.
go back to reference M. Olivares-Marín, J.A. Fernández, and M.J. Lázaro, Cherry Stones as Precursor of Activated Carbons for Supercapacitors, Mater. Chem. Phys., 2009, 114, p 323–327CrossRef M. Olivares-Marín, J.A. Fernández, and M.J. Lázaro, Cherry Stones as Precursor of Activated Carbons for Supercapacitors, Mater. Chem. Phys., 2009, 114, p 323–327CrossRef
13.
go back to reference M.S. Balathanigaimani, W.G. Shim, M.J. Lee et al., Highly Porous Electrodes from Novel Corn Grains-Based Activated Carbons for Electrical Double Layer Capacitors, Electrochem. Commun., 2008, 10, p 868–871CrossRef M.S. Balathanigaimani, W.G. Shim, M.J. Lee et al., Highly Porous Electrodes from Novel Corn Grains-Based Activated Carbons for Electrical Double Layer Capacitors, Electrochem. Commun., 2008, 10, p 868–871CrossRef
14.
go back to reference W. Li, L.B. Zhang, J.H. Peng et al., Preparation of High Surface Area Activated Carbons from Tobacco Stems with K2CO3 Activation Using Microwave Radiation, Ind. Crop Prod., 2008, 27, p 341–347CrossRef W. Li, L.B. Zhang, J.H. Peng et al., Preparation of High Surface Area Activated Carbons from Tobacco Stems with K2CO3 Activation Using Microwave Radiation, Ind. Crop Prod., 2008, 27, p 341–347CrossRef
15.
go back to reference B. Cagnon, X. Py, A. Guillot et al., Contributions of Hemicellulose, Cellulose and Lignin to the Mass and the Porous Properties of Chars and Steam Activated Carbons from Various Lignocellulosic Precursors, Bioresour. Technol., 2009, 100, p 292–298CrossRef B. Cagnon, X. Py, A. Guillot et al., Contributions of Hemicellulose, Cellulose and Lignin to the Mass and the Porous Properties of Chars and Steam Activated Carbons from Various Lignocellulosic Precursors, Bioresour. Technol., 2009, 100, p 292–298CrossRef
16.
go back to reference Y.W. Zhu, S. Muraali, M.D. Stoller et al., Carbon-based Supercapacitors Produced by Activation of Graphene, Science, 2011, 332, p 1537–1541CrossRef Y.W. Zhu, S. Muraali, M.D. Stoller et al., Carbon-based Supercapacitors Produced by Activation of Graphene, Science, 2011, 332, p 1537–1541CrossRef
17.
go back to reference M.S. Balathanigaimani, W.-G. Shim, C. Kim et al., Surface Structural Characterization of Highly Porous Activated Carbon Prepared from Corn Grain, Surf Interface Anal., 2009, 41, p 484–488CrossRef M.S. Balathanigaimani, W.-G. Shim, C. Kim et al., Surface Structural Characterization of Highly Porous Activated Carbon Prepared from Corn Grain, Surf Interface Anal., 2009, 41, p 484–488CrossRef
18.
go back to reference M.R. Jisha, Y.J. Hwang, J.S. Shin et al., Electrochemical Characterization of Supercapacitors Based on Carbons Derived from Coffee Shells, Mater. Chem. Phys., 2009, 115, p 33–39CrossRef M.R. Jisha, Y.J. Hwang, J.S. Shin et al., Electrochemical Characterization of Supercapacitors Based on Carbons Derived from Coffee Shells, Mater. Chem. Phys., 2009, 115, p 33–39CrossRef
19.
go back to reference W. Xing, C.C. Huang, and S.P. Zhuo, Hierarchical Porous Carbons with High Performance for Supercapacitor Electrodes, Carbon, 2009, 47, p 1715–1722CrossRef W. Xing, C.C. Huang, and S.P. Zhuo, Hierarchical Porous Carbons with High Performance for Supercapacitor Electrodes, Carbon, 2009, 47, p 1715–1722CrossRef
20.
go back to reference C.L. Liu, W.S. Dong, G.P. Cao et al., Influence of KOH Followed by Oxidation Pretreatment on the Electrochemical Performance of Phenolic Based Activated Carbon Fibers, J. Electroanal. Chem., 2007, 611, p 225–231CrossRef C.L. Liu, W.S. Dong, G.P. Cao et al., Influence of KOH Followed by Oxidation Pretreatment on the Electrochemical Performance of Phenolic Based Activated Carbon Fibers, J. Electroanal. Chem., 2007, 611, p 225–231CrossRef
21.
go back to reference D.W. Wang, F. Li, H.-T. Fang, M. Liu, and G.Q. Lu, Effect of Pore Packing Defects in 2-D Ordered Mesoporous Carbons in Ionic Transport, J. Phys. Chem. B, 2006, 110, p 8570–8575CrossRef D.W. Wang, F. Li, H.-T. Fang, M. Liu, and G.Q. Lu, Effect of Pore Packing Defects in 2-D Ordered Mesoporous Carbons in Ionic Transport, J. Phys. Chem. B, 2006, 110, p 8570–8575CrossRef
22.
go back to reference R. Lin, P.L. Taberna, J. Chmiola, D. Guay, Y. Gogosti, and P. Simon, Microelectrode Study of Pore Size, Ion Size, and Solvent Effects on the Charge/Discharge Behavior of Microporous Carbons for Electrical Double-Layer Capacitors, J. Electrochem. Soc., 2009, 156, p A7–A12CrossRef R. Lin, P.L. Taberna, J. Chmiola, D. Guay, Y. Gogosti, and P. Simon, Microelectrode Study of Pore Size, Ion Size, and Solvent Effects on the Charge/Discharge Behavior of Microporous Carbons for Electrical Double-Layer Capacitors, J. Electrochem. Soc., 2009, 156, p A7–A12CrossRef
Metadata
Title
Tobacco Stem-Based Activated Carbons for High Performance Supercapacitors
Authors
Xiaohong Xia
Hongbo Liu
Lei Shi
Yuede He
Publication date
01-09-2012
Publisher
Springer US
Published in
Journal of Materials Engineering and Performance / Issue 9/2012
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI
https://doi.org/10.1007/s11665-011-0101-3

Other articles of this Issue 9/2012

Journal of Materials Engineering and Performance 9/2012 Go to the issue

Premium Partners