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Published in: Glass and Ceramics 1-2/2021

28-05-2021

Transparent Glass-Ceramic Materials Based on Lead Fluoroborate Glasses Co-Activated by Eu/Gd

Authors: D. A. Velichkina, K. I. Runina, M. P. Zykova, O. B. Petrova

Published in: Glass and Ceramics | Issue 1-2/2021

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Abstract

Transparent glass-ceramic materials co-activated by Eu3+/Gd3+ were obtained by heat treatment of the initial lead fluoroborate glasses. It was found that the rare-earth ions in the obtained transparent samples are located in nanoparticles of lead fluoride cubic crystals, distributed in the bulk of the glass. It was shown that Eu3+ ions are situated in a highly symmetric local environment and that the introduction of a second activator increases the nanocrystalline phase fraction.

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Literature
1.
go back to reference P. P. Fedorov, A. A. Luginina, and A. I. Popov, “Transparent oxyfluoride glass ceramics,” J. Fluorine Chem., 172, 22 – 50 (2015).CrossRef P. P. Fedorov, A. A. Luginina, and A. I. Popov, “Transparent oxyfluoride glass ceramics,” J. Fluorine Chem., 172, 22 – 50 (2015).CrossRef
2.
go back to reference P. A. Loiko, G. E. Rachkovskaya, N. A. Skoptsov, et al., “Mechanisms of upconversion luminescence in glass-ceramics containing Er:PbF2 nanocrystals,” Zh. Prikl. Spektrosk., 84(1), 172 – 180 (2017). P. A. Loiko, G. E. Rachkovskaya, N. A. Skoptsov, et al., “Mechanisms of upconversion luminescence in glass-ceramics containing Er:PbF2 nanocrystals,” Zh. Prikl. Spektrosk., 84(1), 172 – 180 (2017).
3.
go back to reference F. Zeng, G. Ren, X. Qiu, et al., “The effect of PbF2 content on the microstructure and upconversion luminescence of Er3+-doped SiO2–PbF2 –PbO glass ceramics,” J. Non-Cryst. Solids, 354, 3428 – 3432 (2008).CrossRef F. Zeng, G. Ren, X. Qiu, et al., “The effect of PbF2 content on the microstructure and upconversion luminescence of Er3+-doped SiO2–PbF2 –PbO glass ceramics,” J. Non-Cryst. Solids, 354, 3428 – 3432 (2008).CrossRef
4.
go back to reference Yu. V. Orlovskii, T. T. Basiev, K. K. Pukhov, et al., “Multiphonon relaxation of mid IR transitions of rare-earth ions in fluorite type crystals,” in: Proceedings Volume of the Advanced Solid-State Photonics 2004, Gregory Quarles, Optical Society of America, Washington (2004), Vol. 94, pp. 440 – 445. Yu. V. Orlovskii, T. T. Basiev, K. K. Pukhov, et al., “Multiphonon relaxation of mid IR transitions of rare-earth ions in fluorite type crystals,” in: Proceedings Volume of the Advanced Solid-State Photonics 2004, Gregory Quarles, Optical Society of America, Washington (2004), Vol. 94, pp. 440 – 445.
5.
go back to reference I. Richman, “Longitudinal optical phonons in CaF2, SrF2 and BaF2 ,” J. Chem. Phys., 41(9), 2836 – 2837 (1964).CrossRef I. Richman, “Longitudinal optical phonons in CaF2, SrF2 and BaF2 ,” J. Chem. Phys., 41(9), 2836 – 2837 (1964).CrossRef
6.
go back to reference V. A. Aseev, E. V. Kolobkova, K. S. Moskaleva, et al., “Luminescent properties of ytterbium-erbium nanostructured lead fluoride silicate glass-ceramics at low temperatures,” Opt. Spectroscopy, 114(5), 751 – 755 (2013) [Opt. Spektrosk., 114(5), 818 – 823 (2013)]. V. A. Aseev, E. V. Kolobkova, K. S. Moskaleva, et al., “Luminescent properties of ytterbium-erbium nanostructured lead fluoride silicate glass-ceramics at low temperatures,” Opt. Spectroscopy, 114(5), 751 – 755 (2013) [Opt. Spektrosk., 114(5), 818 – 823 (2013)].
7.
go back to reference O. B. Petrova and A. V. Khomyakov, “Lead fluorosilicate glass ceramics doped with Nd3+, Er3+, and Yb3+,” Opt. Spectroscopy, 114(6), 876 – 879 (2013) [Opt. Spektrosk., 114(6), 962 – 966 (2013)]. O. B. Petrova and A. V. Khomyakov, “Lead fluorosilicate glass ceramics doped with Nd3+, Er3+, and Yb3+,” Opt. Spectroscopy, 114(6), 876 – 879 (2013) [Opt. Spektrosk., 114(6), 962 – 966 (2013)].
8.
go back to reference O. B. Petrova, A. V. Popov, V. E. Shukshin, et al., “Lead borate oxyfluoride glasses doped with Nd3+ ions and transparent glass-crystal materials based on them,” J. Opt. Technol., 78(10), 659 – 663 (2011) [Opt. Spektrosk., 78(10), 30 – 35 (2011)]. O. B. Petrova, A. V. Popov, V. E. Shukshin, et al., “Lead borate oxyfluoride glasses doped with Nd3+ ions and transparent glass-crystal materials based on them,” J. Opt. Technol., 78(10), 659 – 663 (2011) [Opt. Spektrosk., 78(10), 30 – 35 (2011)].
9.
go back to reference J. Pisarska, W. Ryba-Romanowski, and G Dominiak-Dzik, “Nd-doped oxyfluoroborate glasses and glass-ceramics for NIR laser applications,” J. Alloys Compounds, 451, 223 – 225 (2008).CrossRef J. Pisarska, W. Ryba-Romanowski, and G Dominiak-Dzik, “Nd-doped oxyfluoroborate glasses and glass-ceramics for NIR laser applications,” J. Alloys Compounds, 451, 223 – 225 (2008).CrossRef
10.
go back to reference O. Petrova, T. Sevostjanova, A. Khomyakov, et al., “Luminescent glass-ceramics based on nanoparticles of BaxRE1–xF2+x and PbxRE1–xF2+x solid solutions into fluoroborate,” Phys. Status Solidi A, 1700446 (2018). O. Petrova, T. Sevostjanova, A. Khomyakov, et al., “Luminescent glass-ceramics based on nanoparticles of BaxRE1–xF2+x and PbxRE1–xF2+x solid solutions into fluoroborate,” Phys. Status Solidi A, 1700446 (2018).
11.
go back to reference T. S. Sevostjanova, A. V. Khomyakov, O. B. Petrova, et al., “Luminescent properties of solid solutions in the PbF2–EuF3 system and lead fluoroborate glass ceramics doped with Eu3+ ions,” Opt. Spectroscopy, 123(5), 733 – 742 (2017) [Opt. Spektrosk., 123(5), 734 – 744 (2017)]. T. S. Sevostjanova, A. V. Khomyakov, O. B. Petrova, et al., “Luminescent properties of solid solutions in the PbF2–EuF3 system and lead fluoroborate glass ceramics doped with Eu3+ ions,” Opt. Spectroscopy, 123(5), 733 – 742 (2017) [Opt. Spektrosk., 123(5), 734 – 744 (2017)].
12.
go back to reference O. B. Petrova, D. A. Velichkina, M. P. Zykova, et al., “Nd/La, Nd/Lu-co-doped transparent lead fluoroborate glass-ceramics,” J. Non-Cryst. Solids, 531, 119,858 – 119,864 (2020).CrossRef O. B. Petrova, D. A. Velichkina, M. P. Zykova, et al., “Nd/La, Nd/Lu-co-doped transparent lead fluoroborate glass-ceramics,” J. Non-Cryst. Solids, 531, 119,858 – 119,864 (2020).CrossRef
13.
go back to reference A. K. Tyagi, S. J. Patwe, and S. N. Achary, “Phase relation studies in Pb1–x MxF2+x systems (0.0 ≤ x ≤ 1.0; M = Nd3+, Eu3+ and Er3+,” J. Solid State Chem., 177, 1746 – 1757 (2004). A. K. Tyagi, S. J. Patwe, and S. N. Achary, “Phase relation studies in Pb1–x MxF2+x systems (0.0 ≤ x ≤ 1.0; M = Nd3+, Eu3+ and Er3+,” J. Solid State Chem., 177, 1746 – 1757 (2004).
14.
go back to reference B. P. Sobolev, The Rare Earth Trifluorides, Institute of Crystallography, Moscow, Russia; Institut d’Estudis Catalans, Barcelona, Spain (2000). B. P. Sobolev, The Rare Earth Trifluorides, Institute of Crystallography, Moscow, Russia; Institut d’Estudis Catalans, Barcelona, Spain (2000).
15.
go back to reference I. E. Kolesnikov, D. V. Tolstikova, A. V. Kurochkin, et al., “Concentration effect on photoluminescence of Eu3+-doped nanocrystalline YVO4 ,” J. Lumin., 158, 469 – 474 (2015).CrossRef I. E. Kolesnikov, D. V. Tolstikova, A. V. Kurochkin, et al., “Concentration effect on photoluminescence of Eu3+-doped nanocrystalline YVO4 ,” J. Lumin., 158, 469 – 474 (2015).CrossRef
16.
go back to reference D. R. Foster, F. S. Richardson, L. M. Vallarino, et al., “Magnetic circularly polarized luminescence spectra of Eu (beta.-diketonate) 3X2 complexes in nonaqueous solution,” Inorg. Chem. ACS Publ., 22(26), 4002 – 4009 (1983).CrossRef D. R. Foster, F. S. Richardson, L. M. Vallarino, et al., “Magnetic circularly polarized luminescence spectra of Eu (beta.-diketonate) 3X2 complexes in nonaqueous solution,” Inorg. Chem. ACS Publ., 22(26), 4002 – 4009 (1983).CrossRef
Metadata
Title
Transparent Glass-Ceramic Materials Based on Lead Fluoroborate Glasses Co-Activated by Eu/Gd
Authors
D. A. Velichkina
K. I. Runina
M. P. Zykova
O. B. Petrova
Publication date
28-05-2021
Publisher
Springer US
Published in
Glass and Ceramics / Issue 1-2/2021
Print ISSN: 0361-7610
Electronic ISSN: 1573-8515
DOI
https://doi.org/10.1007/s10717-021-00340-w

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