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Colloid and Polymer Science
Published in: Colloid and Polymer Science 2/2016

01-02-2016 | Original Contribution

Tunable double-stranded inclusion complexes of γ-cyclodextrin threaded onto non-modified poly(ethylene glycol)

Authors: Kai Huang, Li Li, Jie Wang, Zhiming Zhou, Xuhong Guo

Published in: Colloid and Polymer Science | Issue 2/2016

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Abstract

The formation of double-stranded inclusion complexes (ICs) between γ-cyclodextrin (γ-CD) and non-modified poly(ethylene glycol) (PEG) was reported to be of trace yield, while in the present work, tunable inclusion complexes between γ-CD and non-modified PEG were successfully prepared by choosing suitable γ-CD concentrations and PEG molecular weights. The obtained γ-CD/PEG ICs showed double-stranded structure whose yield, appearance, and forming rate were significantly affected by PEG molecular weight and temperature as revealed by means of optical microscopy, XRD, DSC, 1H NMR, and ITC. This improved understanding on how to control the formation of double-stranded inclusion complexes should be very helpful for preparation of more sophisticated molecular machines.
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Metadata
Title
Tunable double-stranded inclusion complexes of γ-cyclodextrin threaded onto non-modified poly(ethylene glycol)
Authors
Kai Huang
Li Li
Jie Wang
Zhiming Zhou
Xuhong Guo
Publication date
01-02-2016
Publisher
Springer Berlin Heidelberg
Published in
Colloid and Polymer Science / Issue 2/2016
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3788-0

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