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Polymer Bulletin

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11-11-2016 | Original Paper

Unsymmetrical pyrazole-based new semiconductor oligomer: synthesis and optical properties

Published in: Polymer Bulletin | Issue 7/2017

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Abstract

Poly(p-phenylene-1-(2,5-dimethylphenyl)-5-phenyl-1H-pyrazole-3,4-dicarboxy amide) (poly(PDPPD)) was synthesized from reactions of p-phenylene-diamine and 1-(2,5-dimethylphenyl)-5-phenyl-1H-pyrazole-3,4-dicarbonyl dichloride (monomer) by heating under solvent. This newly synthesized poly(PDPPD) was characterized by ¹H, ¹³C-NMR, FT-IR, gel permeation chromatography (GPC). In addition, we investigated optical properties of the poly(PDPPD) containing the substituted pyrazole ring at different molarities. The average transmittance (T _avg) values of the poly(PDPPD) in the visible (V) region were higher than the T _avg values in the near-ultraviolet (NU) region. The T _avg values of the poly(PDPPD) in the NU and visible (V) region decreased with increasing molarity. The absorption band edge (Abs_be) value of the poly(PDPPD) decreased with increasing molarity. It was observed that the optical band gap (E _g) of the poly(PDPPD) value decreased more with increasing molarity. The refractive index of the poly(PDPPD) decreased with increasing wavelength and decreasing molarity. The structure of the poly(PDPPD) in the lowest energy was optimized by DFT calculation and its HOMO–LUMO orbitals were plotted.

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Title: Unsymmetrical pyrazole-based new semiconductor oligomer: synthesis and optical properties
Publication date: 11-11-2016
Published in: Polymer Bulletin / Issue 7/2017
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-016-1846-5

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