Skip to main content
Disciplines
Automotive Business IT + Informatics Construction + Real Estate Electrical Engineering + Electronics Energy + Sustainability Insurance + Risk Finance + Banking Management + Leadership Marketing + Sales Mechanical Engineering + Materials
Events
DE
EN
Books
Journals
Topic Page
Marketing
Start single access now
Access for companies
EXTENDED SEARCH
Log in
Top
Polymer Bulletin
Published in: Polymer Bulletin 2/2012

01-01-2012 | Original Paper

UV-curable water-borne polyurethane primers for aluminum and polycarbonate interfaces

Authors: S. H. Yoon, B. K. Kim

Published in: Polymer Bulletin | Issue 2/2012

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

Water-borne polyurethane (WPU) primers were synthesized from three types of polyol, viz., poly(propylene glycol), poly(tetramethylene glycol), and polycaprolactone diol (PCL) at two prepolymer molecular weights, and were tested for the adhesion between vinyltrimethoxysilane modified aluminum panel and polycarbonate. It was found that chemical hybridizations of Al panel with WPU via sol–gel reaction were crucial to enhance the adhesion. Among three types of polyol, PCL gave the highest adhesion strength, glassy and rubbery moduli, tensile strength, and glass transition temperature. On the other hand, smaller prepolymer molecular weight gave improved adhesion and improved mechanical properties due to the increased crosslink density and cohesive strength.
previous article Modeling of kinetics of pertechnetate removal by amino-functionalized glycidyl methacrylate copolymer
next article Evaluation of polypropylene grafted with maleic anhydride and styrene as a compatibilizer for polypropylene/clay nanocomposites

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

inform now
Literature
1.
Madbouly SA, Otaigbe JU (2006) Kinetic analysis of fractal gel formation in waterborne polyurethane dispersions undergoing high deformation flows. Macromolecules 39:4144–4151CrossRef
2.
Nanda AK, Wicks DA (2006) The influence of the ionic concentration, concentration of the polymer, degree of neutralization and chain extension on aqueous polyurethane dispersions prepared by the acetone process. Polymer 47:1805–1811CrossRef
3.
Yen MS, Tsai PY, Hong PD (2006) The solution properties and membrane properties of polydimethylsiloxane waterborne polyurethane blended with the waterborne polyurethanes of various kinds of soft segments. Colloid Surf A 279:1–9CrossRef
4.
Furukawa M, Hamada Y, Kojio K (2003) Aggregation structure and mechanical properties of functionally graded polyurethane elastomers. J Polym Sci B 41:2355–2363CrossRef
5.
6.
Iyer NP, Gnanarajan TP, Radhakrishanan G (2002) Mechanical and thermal properties of networks prepared from reactive poly(urethane-imide)s and blocked olyurethane prepolymer. Macromol Chem Phys 203:712–717CrossRef
7.
Kim BK, Lee JC (1996) Waterborne polyurethanes and their properties. J Polym Sci A 34:1095–1104CrossRef
8.
9.
Jeong HY, Lee MH, Kim BK (2006) Surface modification of waterborne polyurethane. Colloid Surf A 290:178–185CrossRef
10.
Jeon HT, Jang MK, Kim BK, Kim KH (2007) Synthesis and characterizations of waterborne polyurethane–silica hybrids using sol–gel process. Colloid Surf A 302:559–567CrossRef
11.
Yang CH, Liu FJ, Liu YP, Liao WT (2006) Hybrids of colloidal silica and waterborne polyurethane. J Colloid Interface Sci 302:123–132CrossRef
12.
Adler HJ, Jahny K, Bettina VB (2001) Polyurethane macromers-new building blocks for acrylic hybrid emulsions with outstanding performance. Prog Org Coat 43:251–257CrossRef
13.
Kim BK, Seo JW, Jeong HM (2003) Morphology and properties of waterborne polyurethane/clay nanocomposites. Eur Polym J 39:85–91CrossRef
14.
Noh SH, Choi HS, Noh ST (2000) Synthesis and application of water-based urethane acrylate crosslinking agent containing unsaturated group. J Appl Polym Sci 78:1216–1223CrossRef
15.
Schwalm R, Häußling l, Reich W, Beak E, Enenkel P, Mensel K (1997) Tuning the mechanical properties of UV coatings towards hard and flexible systems. Prog Org Coat 32:191–196CrossRef
16.
Plueddemann EP (1991) Silane coupling agents. Plenum Press, New York
17.
Ooij WJ, Child T (1998) Protecting metals with silane coupling agents. Chem Techn 28:26–35
18.
Digby RP, Shaw SJ (1998) The international collaborative programme on organosilane coupling agents: an introduction. Int J Adhes Adhes 18:261–264CrossRef
19.
Kim J, Wong PC, Wong KC, Sodhi RNS, Mitchell KAR (2007) Adsorption of BTSE and γ-GPS organosilanes on different microstructural regions of 7075-T6 aluminum alloy. Appl Surf Sci 253:3133–3143CrossRef
20.
Matienzo LJ, Shaffer DK, Moshier WC, Davis GD (1986) Environmental and adhesive durability of aluminium-polymer systems protected with organic corrosion inhibitors. J Mater Sci 21:1601–1608CrossRef
21.
Kollek H (1985) Some aspects of chemistry in adhesion on anodized aluminium. Int J Adhes Adhes 5:75–80CrossRef
Metadata
Title
UV-curable water-borne polyurethane primers for aluminum and polycarbonate interfaces
Authors
S. H. Yoon
B. K. Kim
Publication date
01-01-2012
Publisher
Springer-Verlag
Published in
Polymer Bulletin / Issue 2/2012
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-011-0637-2

Other articles of this Issue 2/2012

Polymer Bulletin 2/2012 Go to the issue

Original Paper

Competitive mechanism of poly(ethylene glycol) with poly(vinyl methyl ether) in complexing water molecules revealed with elastic light scattering spectroscopy

Original Paper

Synthesis and properties of novel donor–acceptor copolymers based on thiophene and squaraine moieties

Original Paper

Effects of silica sol content on the properties of poly(acrylamide)/silica composite hydrogel

Original Paper

Evaluation of polypropylene grafted with maleic anhydride and styrene as a compatibilizer for polypropylene/clay nanocomposites

Original Paper

Electromagnetic interference shielding effects of polyaniline-coated multi-wall carbon nanotubes/maghemite nanocomposites

Original Paper

Supercapacitive properties of polyaniline/hydrous RuO2 composite electrode

Premium Partners

    Image Credits