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Biomass Conversion and Biorefinery

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19-01-2022 | Original Article

Valorization of biomass to furfuryl alcohol via chemoenzymatic cascade catalysis by deep eutectic solvent-silica heterogeneous catalyst and reductase biocatalyst in the aqueous system

Authors: Junhua Di, Lizhen Qin, Yu-Cai He

Published in: Biomass Conversion and Biorefinery | Issue 17/2023

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Abstract

A new type of metal-free solid acid catalyst ChCl:OA-SG(SiO₂) was firstly synthesized by loading deep eutectic solvent ChCl:oxalic acid on silica with sol–gel process using tetraethyl orthosilicate as silicon source. The properties of the catalyst were characterized by Fourier transform infrared spectrum, X-ray diffraction, scanning electron microscope, and Brunauer-Emmet-Teller. Highest furfural (FF) yield reached 41.2% from corncob with ChCl:OA-SG(SiO₂) catalyst (2.0 wt%) in water at 170 °C for 0.5 h. The catalytic mechanism of ChCl:OA-SG(SiO₂)-catalyzed biomass into furfural was interpreted in the aqueous system. Corncob-valorized FF was wholly transformed to furfuryl alcohol with recombinant Escherichia coli CG-19 cells after bioreduction for 3 h of at 30 °C and pH 7.0. Yield of 0.416 g furfuryl alcohol/g xylan in corncob was obtained. This established hybrid catalysis could efficiently valorize biomass into value-added furfuryl alcohol.

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Title: Valorization of biomass to furfuryl alcohol via chemoenzymatic cascade catalysis by deep eutectic solvent-silica heterogeneous catalyst and reductase biocatalyst in the aqueous system
Authors: Junhua Di
Lizhen Qin
Yu-Cai He
Publication date: 19-01-2022
Publisher: Springer Berlin Heidelberg
Published in: Biomass Conversion and Biorefinery / Issue 17/2023
Print ISSN: 2190-6815
Electronic ISSN: 2190-6823
DOI: https://doi.org/10.1007/s13399-021-02171-9

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