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Diffusion of Water in Adhesives Read chapter Read first chapter

2013 | OriginalPaper | Chapter

Water and Ions at Polymer/Metal Interfaces

Authors : Ralf Posner, Ozlem Ozcan, Guido Grundmeier

Published in: Design of Adhesive Joints Under Humid Conditions

Publisher: Springer Berlin Heidelberg

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Abstract

The adsorption and transport of water and ions at polymer/metal interfaces has a strong impact on the adhesion of the polymer as well as on the kinetics of corrosive degradation. Although not directly correlated both wet-de-adhesion and corrosive de-adhesion are accelerated by water enrichment at the interface which promotes the ingress of ions. The discussion of these phenomena starts with the consideration of the adsorption of water on oxide surfaces, as all engineering metals are covered with an ultra-thin atmospheric oxide film, and ends with the cathodic and anodic corrosive de-adhesion mechanisms of polymers from oxide covered metals. The bridge between the water adsorption and corrosive de-adhesion reactions is built based on the separation of water and ion transport in polymeric interphases and the discussion of diffusion and migration as the principal processes.

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Metadata
Title
Water and Ions at Polymer/Metal Interfaces
Authors
Ralf Posner
Ozlem Ozcan
Guido Grundmeier
Copyright Year
2013
Publisher
Springer Berlin Heidelberg
Book
Design of Adhesive Joints Under Humid Conditions

Print ISBN: 978-3-642-37613-9

Electronic ISBN: 978-3-642-37614-6

Copyright Year: 2013

DOI
https://doi.org/10.1007/978-3-642-37614-6_2

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