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Journal of Materials Science: Materials in Electronics

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01-12-2023

Wet chemical-processed nanostructured bismuth selenide thin films for electrochemical supercapacitors

Authors: Tushar B. Deshmukh, Raunak Tolani, Akansha Agrawal, Komal Patil, Pravin Babar, Rajulal Sahu, Babasaheb R. Sankapal

Published in: Journal of Materials Science: Materials in Electronics | Issue 36/2023

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Abstract

Bismuth selenide (Bi₂Se₃) thin films have been grown on stainless steel (SS) substrate by using successive ionic layer adsorption and reaction (SILAR) at room temperature to serve as a supercapacitive electrode. Structural, surface morphological, and wettability studies have been performed to obtain a correlation between the morphological and crystalline characteristics with the supercapacitive electrochemical performance. Synthesized thin film exhibits irregular spherical shape and crystallize in rhombohedral structure. In a three-electrode cell configuration using 0.5 M KOH as electrolyte, well-optimized Bi₂Se₃/SS exhibited areal capacitances of 114 mF cm⁻² at 10 mV/s and 20.4 mF cm⁻² at 1.1 mA cm⁻² with a cyclic stability of 122.8% after 400 CV cycles, indicating a potential candidature of formed electrode towards supercapacitor applications.

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Title: Wet chemical-processed nanostructured bismuth selenide thin films for electrochemical supercapacitors
Authors: Tushar B. Deshmukh
Raunak Tolani
Akansha Agrawal
Komal Patil
Pravin Babar
Rajulal Sahu
Babasaheb R. Sankapal
Publication date: 01-12-2023
Publisher: Springer US
Published in: Journal of Materials Science: Materials in Electronics / Issue 36/2023
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI: https://doi.org/10.1007/s10854-023-11674-2

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