Top

Polymer Bulletin

Published in:

01-01-2013 | Original Paper

A facile way to synthesize polylactide grafted starch: anionic swollen polymerization

Authors: Jun Shao, Jingyi Zhao, Yaoming Zhao, Yurong Yan, Zhiming Qiu

Published in: Polymer Bulletin | Issue 1/2013

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

Polylactide grafted starch (starch-g-PLA) was successfully synthesized via anionic swollen grafting polymerization. The swelling of starch was proved effective to facilitate the grafting reaction. The product with grafting percentage up to 376 % was obtained when optimized the experimental condition. The structure of grafted product was confirmed by Fourier transform infrared spectra and nuclear magnetic resonance spectroscopy. The modified starch has favorable thermal stability below 200 °C according to derivative thermogravimetric analysis. The thermal property of the starch-g-PLA attested that the grafted products have great potential melt blending with PLA and starch.

Graphical Abstract

previous article Synthesis of a new poly(dinaphthylacetylene) and evaluation of its solution conformation

next article Charge transfer dye-based PHEMA hydrogel sensor: its fluorescence responses to pH, metal ion, and humidity

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Zavareze EDR, Guerra Dias AR (2011) Impact of heat-moisture treatment and annealing in starches: a review. Carbohydr Polym 83(2):317–328CrossRef

Liu P-L, Hu X-S, Shen Q (2010) Effect of high hydrostatic pressure on starches: a review. Starch/Starke 62(12):615–628CrossRef

Reddy G, Altaf M, Naveena BJ, Venkateshwar M, Kumar EV (2008) Amylolytic bacterial lactic acid fermentation: a review. Biotechnol Adv 26(1):22–34CrossRef

Huneault MA, Li HB (2007) Morphology and properties of compatibilized polylactide/thermoplastic starch blends. Polymer 48(1):270–280CrossRef

Jun CL (2000) Reactive blending of biodegradable polymers: PLA and starch. J Polym Environ 8(1):33–37CrossRef

Ke TY, Sun XZ (2000) Physical properties of poly(lactic acid) and starch composites with various blending ratios. Cereal Chem 77(6):761–768CrossRef

Ohkita T, Lee SH (2004) Effect of aliphatic isocyanates (HDI and LDI) as coupling agents on the properties of eco-composites from biodegradable polymers and corn starch. J Adhes Sci Technol 18(8):905–924CrossRef

Wang H, Sun XZ, Seib P (2002) Mechanical properties of poly(lactic acid) and wheat starch blends with methylenediphenyl diisocyanate. J Appl Polyme Sci 84(6):1257–1262CrossRef

Silva KMD, Tarverdi K, Withnall R, Silver J (2011) Incorporation of wheat starch and coupling agents into poly(lactic acid) to develop biodegradable composite. Plast Rubber Compos 40(1):17–24CrossRef

10.

Dubois P, Narayan R (2003) Biodegradable compositions by reactive processing of aliphatic polyester/polysaccharide blends. Macromol Symp 198:233–243CrossRef

11.

Cai Q, Wan YQ, Bei JZ, Wang SG (2003) Synthesis and characterization of biodegradable polylactide-grafted dextran and its application as compatilizer. Biomaterials 24(20):3555–3562CrossRef

12.

Chen L, Qiu XY, Deng MX, Hong ZK, Luo R, Chen XS, Jing XB (2005) The starch grafted poly(l-lactide) and the physical properties of its blending composites. Polymer 46(15):5723–5729CrossRef

13.

Xu Q, Wang QR, Liu LJ (2008) Ring-opening graft polymerization of l-lactide onto starch granules in an ionic liquid. J Appl Polym Sci 107(4):2704–2713CrossRef

14.

Gong QX, Wang LQ, Tu KH (2006) In situ polymerization of starch with lactic acid in aqueous solution and the microstructure characterization. Carbohyd Polym 64(4):501–509CrossRef

15.

Tanaka. H, Kawamatsu. T, Utsue. I, Okumura Y, Tanaka H (1998) Polyester-grafted starch-polymer alloy. Patent 5719214

16.

Tate S, Watanabe Y, Chiba A (1993) Synthesis of ultra-high-molecular-weight poly(ethylene–terephthalate) by swollen-state polymerization. Polymer 34(23):4974–4977CrossRef

17.

Tate S, Watanabe Y (1995) Swollen-state polymerization of poly(ethylene terephthalate) in fibre form. Polymer 36(26):4991–4995CrossRef

18.

Tate S, Ishimaru F (1995) Swollen-state polymerization of poly(ethylene-terephthalate) kinetic analysis of reaction rate and polymerization conditions. Polymer 36(2):353–356CrossRef

19.

Ma Y, Agarwal US (2005) Solvent assisted post-polymerization of PET. Polymer 46(15):5447–5455CrossRef

20.

Jun S, Yaoming Z (2009) Investigation and Application of In situ synthesized polylactic acid grafting starch copolymer. China Plast 23(10):10–15

21.

Ohya Y, Maruhashi S, Ouchi T (1998) Graft polymerization of l-lactide on pullulan through the trimethylsilyl protection method and degradation of the graft copolymers. Macromolecules 31(14):4662–4665CrossRef

22.

Jun S, Yaoming Z (2010) The preparation and characterization of PLA/DMSO plasticized starch composite materials. China Plast Ind 38(02):8–11

23.

Koganti N, Mitchell JR, Ibbett RN, Foster TJ (2011) Solvent effects on starch dissolution and gelatinization. Biomacromolecules 12(8):2888–2893CrossRef

24.

Bellis HE, Thayer CA (1994) Process for the synthesis of lactide or glycolide from lactic acid or glycolide acid oligomers. Patent US5374743-A

25.

Kricheldorf HR, Berl M, Scharnagl N (1988) Poly(lactones) 9. Polymerization mechanism of metal alkoxide initiated polymerizations of lactide and various lactones. Macromolecules 21(2):286–293CrossRef

26.

Rutot-Houze D, Degee P, Gouttebaron R, Hecq M, Narayan R, Dubois P (2004) In-depth characterization of granular starch-graft-polyester compositions as obtained by in situ polymerization of lactones from the starch surface. Polym Int 53(6):656–663CrossRef

27.

Heinze T, Lieber T, Koschella A (eds) (2006) Esterification of polysaccharides, 1st edn. Springer, New York, pp 15–39

Title: A facile way to synthesize polylactide grafted starch: anionic swollen polymerization
Authors: Jun Shao
Jingyi Zhao
Yaoming Zhao
Yurong Yan
Zhiming Qiu
Publication date: 01-01-2013
Publisher: Springer-Verlag
Published in: Polymer Bulletin / Issue 1/2013
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-012-0820-0

Springer Professional

Abstract

Graphical Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 1/2013

Study on the thermal effects of rubbers during loading–unloading cycles by infrared thermography

Thermodegradative study of HDPE–HA nanocomposites: IKP and E 2 function

Grazing-incidence wide-angle X-ray diffraction study on molecular aggregation state of imprinted polyimide film before and after hard baking

Silver-filled epoxy composites: effect of hybrid and silane treatment on thermal properties

Preparation and characterization of polylactide/poly(polyethylene glycol-co-citric acid) blends

Synthesis, electropolymerization, and photoelectrochemical characterization of 2,7-di(thiophen-2-yl)-N-methylcarbazole

Premium Partners