Top

Rare Metals

Published in:

27-08-2023 | Letter

A flexible electrochemical sensor for paracetamol based on porous honeycomb-like NiCo-MOF nanosheets

Authors: Xiu-Li Liu, Jia-Wei Guo, Ya-Wen Wang, Ai-Zhu Wang, Xin Yu, Long-Hua Ding

Published in: Rare Metals | Issue 10/2023

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

The overdose of 4-aminophenol (AP) threatens human health, and the determination of AP is crucial. Here, we report a flexible electrochemical sensor for highly sensitive and precise determination of AP. The ultrathin honeycomb-like NiCo-MOF nanosheets were in situ grown on free-standing flexible carbon cloth (CC) electrode. The porous structure among nanosheets and rich porosity of NiCo-MOF shorten the transport path of electrolyte ions and reactants, ensuring fast electron transport. The large specific surface area (62.14 m²·g⁻¹) provides much active site, and NiCo-MOF exhibits high catalytic activity toward AP. The proposed NiCo-MOF/CC-based sensor showed a wide linear range from 5.0 to 400 μmol·L⁻¹ with a detection limit of 1.0 μmol·L⁻¹. The selectivity, reproducibility and stability were also verified to be satisfactory. In addition, it can detect AP in real pills. The developed flexible sensor endows its promising potential in fabrication of wearable devices.

Graphical abstract

previous article Tunable structural coloration of ultrathin zirconia nanotubes film

next article Flexible silver nanorods/carbon fiber felt metacomposites with epsilon-near-zero property adjusted by compressive deformation

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Available only for authorised users

[1]

Chou R, Deyo R, Friedly J, Skelly A, Weimer M, Fu R, Dana T, Kraegel P, Griffin J, Grusing S. Systemic pharmacologic therapies for low back pain: a systematic review for an American college of physicians clinical practice guideline. Ann Intern Med. 2017;166(7):480. https://doi.org/10.7326/m16-2458.CrossRef

[2]

Du K, Ramachandran A, Jaeschke H. Oxidative stress during acetaminophen hepatotoxicity: sources, pathophysiological role and therapeutic potential. Redox Biol. 2016;10:148. https://doi.org/10.1016/j.redox.2016.10.001.CrossRef

[3]

Mossanen JC, Krenkel O, Ergen C, Govaere O, Liepelt A, Puengel T, Heymann F, Kalthoff S, Lefebvre E, Eulberg D, Luedde T, Marx G, Strassburg CP, Roskams T, Trautwein C, Tacke F. Chemokine (C-C motif) receptor 2-positive monocytes aggravate the early phase of acetaminophen-induced acute liver injury. Hepatology. 2016;64(5):1667. https://doi.org/10.1002/hep.28682.CrossRef

[4]

Jian NG, Li RX, Li J, Liang SH, Xu Q, Wang CM. Simple, efficient, and eco-friendly sample preparation for simultaneous determination of paracetamol and chloramphenicol in meat. J Sep Sci. 2019;42(16):2696. https://doi.org/10.1002/jssc.201900224.CrossRef

[5]

Vanova J, Malinak D, Andrys R, Kubat M, Mikysek T, Rousarova E, Musilek K, Rousar T, Cesla P. Optimization of gradient reversed phase high performance liquid chromatography analysis of acetaminophen oxidation metabolites using linear and non-linear retention model. J Chromatogr A. 2022;1669:462956. https://doi.org/10.1016/j.chroma.2022.462956.CrossRef

[6]

Li M, Ding CP, Jia PD, Guo LH, Wang S, Guo ZY, Su FM, Huang YJ. Semi-quantitative detection of p-Aminophenol in real samples with colorfully naked-eye assay. Sens Actuators B Chem. 2021;334:129604. https://doi.org/10.1016/j.snb.2021.129604.CrossRef

[7]

Emdadi S, Sorouraddin MH, Denanny L. Enhanced chemiluminescence determination of paracetamol. Analyst. 2021;146(4):1326. https://doi.org/10.1039/D0AN01557A.CrossRef

[8]

Liu XT, Na WD, Liu H, Su XG. Fluorescence turn-off-on probe based on polypyrrole/graphene quantum composites for selective and sensitive detection of paracetamol and ascorbic acid. Biosens Bioelectron. 2017;98:222. https://doi.org/10.1016/j.bios.2017.06.044.CrossRef

[9]

Montaseri H, Forbes PBC. Analytical techniques for the determination of acetaminophen: a review. Trends Anal Chem. 2018;108:122. https://doi.org/10.1016/j.trac.2018.08.023.CrossRef

[10]

Sripirom J, Sim WC, Khunkaewla P, Suginta W, Schulte A. Simple and economical analytical voltammetry in 15 μL volumes: paracetamol voltammetry in blood serum as a working example. Anal Chem. 2018;90(17):10105. https://doi.org/10.1021/acs.analchem.8b01135.CrossRef

[11]

Sanger K, Durucan O, Wu K, Thilsted AH, Heiskanen A, Rindzevicius T, Schmidt MS, Zór K, Boisen A. Large-scale, lithography-free production of transparent nanostructured surface for dual-functional electrochemical and SERS sensing. ACS Sens. 2017;2(12):1869. https://doi.org/10.1021/acssensors.7b00783.CrossRef

[12]

Qian LT, Elmahdy R, Raj Thiruppathi A, Chen A. An ultrasensitive electrochemical sensor for the detection of acetaminophen via a three-dimensional hierarchical nanoporous gold wire electrode. Analyst. 2021;146(14):4525. https://doi.org/10.1039/D1AN00755F.CrossRef

[13]

Kumar KK, Devendiran M, Kumar PS, Babu RS, Narayanan SS. Green synthesis of curcumin-silver nanoparticle and its modified electrode assisted amperometric sensor for the determination of paracetamol. Chemosphere. 2022;303:134994. https://doi.org/10.1016/j.chemosphere.2022.134994.CrossRef

[14]

Veera Manohara Reddy Y, Bathinapatla S, Łuczak T, Osińska M, Maseed H, Ragavendra P, Subramanyam Sarma L, Srikanth VVSS, Madhavi G. An ultra-sensitive electrochemical sensor for the detection of acetaminophen in the presence of etilefrine using bimetallic Pd–Ag/reduced graphene oxide nanocomposites. New J Chem. 2018;42(4):3137. https://doi.org/10.1039/C7NJ04775D.CrossRef

[15]

Kader Mohiuddin A, Shamsuddin Ahmed M, Jeon S. Palladium doped α-MnO₂ nanorods on graphene as an electrochemical sensor for simultaneous determination of dopamine and paracetamol. Appl Surf Sci. 2022;578:152090. https://doi.org/10.1016/j.apsusc.2021.152090.CrossRef

[16]

Yang H, Cao GX, Huang YJ, Lin Y, Zheng FY, Lin LX, Liu FJ, Li SX. Nitrogen-doped carbon@TiO₂ double-shelled hollow spheres as an electrochemical sensor for simultaneous determination of dopamine and paracetamol in human serum and saliva. J Pharm Anal. 2022;12(3):436. https://doi.org/10.1016/j.jpha.2021.08.005.CrossRef

[17]

Sadeghi M, Shabani-Nooshabadi M. Use of a nano-porous gold film electrode modified with chitosan/polypyrrole for electrochemical determination of metronidazole in the Presence of Acetaminophen. Chemosphere. 2022;307:135722. https://doi.org/10.1016/j.chemosphere.2022.135722.CrossRef

[18]

Xu S, Zhao W, Lin GY, Wu B, Xu MY, Huang XW, Luo J, Zhu Y, Liu XY. Long conducting and water-compatible polymer/carbon nanotubes nanocomposite with “beads-on-a-string” structure as a highly effective electrochemical sensing material. ACS Sustain Chem Eng. 2019;7(3):3556. https://doi.org/10.1021/acssuschemeng.8b05891.CrossRef

[19]

Zhao P, Ni MJ, Chen C, Zhou ZD, Li XP, Li CY, Xie YX, Fei JJ. Stimuli-enabled switch-like paracetamol electrochemical sensor based on thermosensitive polymer and MWCNTs-GQDs composite nanomaterial. Nanoscale. 2019;11(15):7394. https://doi.org/10.1039/C8NR09434A.CrossRef

[20]

Tan K, Ma Q, Luo J, Xu S, Zhu Y, Wei W, Liu XY, Gu Y. Water-dispersible molecularly imprinted nanohybrids via co-assembly of carbon nanotubes with amphiphilic copolymer and photocrosslinking for highly sensitive and selective paracetamol detection. Biosens Bioelectron. 2018;117:713. https://doi.org/10.1016/j.bios.2018.07.009.CrossRef

[21]

Xiang SY, Mao SD, Chen F, Zhao SC, Su WT, Fu L, Zare N, Karimi F. A bibliometric analysis of graphene in acetaminophen detection: current status, development, and future directions. Chemosphere. 2022;306:135517. https://doi.org/10.1016/j.chemosphere.2022.135517.CrossRef

[22]

Kang XH, Wang J, Wu H, Liu J, Aksay IA, Lin YH. A graphene-based electrochemical sensor for sensitive detection of paracetamol. Talanta. 2010;81(3):754. https://doi.org/10.1016/j.talanta.2010.01.009.CrossRef

[23]

Tseng TW, Chen TW, Chen SM, Kokulnathan T, Ahmed F, Hasan PMZ, Bilgrami AL, Kumar S. Construction of strontium phosphate/graphitic-carbon nitride: a flexible and disposable strip for acetaminophen detection. J Hazard Mater. 2021;410:124542. https://doi.org/10.1016/j.jhazmat.2020.124542.CrossRef

[24]

Tang J, Hui ZZ, Hu T, Cheng X, Guo JH, Li ZR, Yu H. A sensitive acetaminophen sensor based on Co metal–organic framework (ZIF-67) and macroporous carbon composite. Rare Met. 2022;41(1):189. https://doi.org/10.1007/s12598-021-01709-0.CrossRef

[25]

Wang LY, Yang YX, Liang HH, Wu N, Peng X, Wang L, Song YH. A novel N, S-rich COF and its derived hollow N, S-doped carbon@Pd nanorods for electrochemical detection of Hg²⁺ and paracetamol. J Hazard Mater. 2021;409:124528. https://doi.org/10.1016/j.jhazmat.2020.124528.CrossRef

[26]

Murugan E, Kumar K. Fabrication of SnS/TiO₂@GO composite coated glassy carbon electrode for concomitant determination of paracetamol, tryptophan, and caffeine in pharmaceutical formulations. Anal Chem. 2019;91(9):5667. https://doi.org/10.1021/acs.analchem.8b05531.CrossRef

[27]

Bayram E, Akyilmaz E. Development of a new microbial biosensor based on conductive polymer/multiwalled carbon nanotube and its application to paracetamol determination. Sens Actuators B Chem. 2016;233:409. https://doi.org/10.1016/j.snb.2016.04.029.CrossRef

[28]

Ma YY, Wei ZY, Wang Y, Ding YH, Jiang LP, Fu X, Zhang Y, Sun J, Zhu WX, Wang JL. Surface oxygen functionalization of carbon cloth toward enhanced electrochemical dopamine sensing. ACS Sustain Chem Eng. 2021;9(48):16063. https://doi.org/10.1021/acssuschemeng.1c03430.CrossRef

[29]

Chen ZJ, Kirlikovali KO, Li P, Farha OK. Reticular chemistry for highly porous metal–organic frameworks: the chemistry and applications. Acc Chem Res. 2022;55(4):579. https://doi.org/10.1021/acs.accounts.1c00707.CrossRef

[30]

Chen TD, Hao ZT, Wang HY, Li J, Zhao P, Huang WH. Preparation and performance research of Ag@Co-based metal organic polymer composites and their non-enzymatic glucose sensors. Chin J Rare Met. 2022;46(01):36. https://doi.org/10.13373/j.cnki.cjrm.XY21100014

[31]

Guo JW, Yang ZW, Liu XL, Zhang LW, Guo WB, Zhang J, Ding LH. 2D Co metal–organic framework nanosheet as an oxidase-like nanozyme for sensitive biomolecule monitoring. Rare Met. 2023;42(3):797–805. https://doi.org/10.1007/s12598-022-02179-8.CrossRef

[32]

Lin RB, Zhang Z, Chen BL. Achieving high performance metal–organic framework materials through pore engineering. Acc Chem Res. 2021;54(17):3362. https://doi.org/10.1021/acs.accounts.1c00328.CrossRef

[33]

Zheng LX, Song JL, Ye XY, Wang YZ, Shi XW, Zheng HJ. Construction of self-supported hierarchical NiCo-S nanosheet arrays for supercapacitors with ultrahigh specific capacitance. Nanoscale. 2020;12(25):13811. https://doi.org/10.1039/d0nr02976a.CrossRef

[34]

Wang T, Zhang SL, Yan XB, Lyu MQ, Wang LZ, Bell J, Wang HX. 2-Methylimidazole-derived Ni–Co layered double hydroxide nanosheets as high rate capability and high energy density storage material in hybrid supercapacitors. ACS Appl Mater Interfaces. 2017;9(18):15510. https://doi.org/10.1021/acsami.7b02987.CrossRef

[35]

Li JL, Jiao L, Xu WQ, Yan HY, Chen GJ, Wu Y, Hu LY, Gu WL. Cobalt oxyhydroxide nanosheets integrating with metal indicator enable sensitive detection of glutathione. Sens Actuators B Chem. 2021;329:129247. https://doi.org/10.1016/j.snb.2020.129247.CrossRef

[36]

Guo JW, Liu XL, Wang AZ, Yu X, Ding LH. Antifouling electrochemical sensor-based on mesoporous silica film for imidacloprid detection in Traditional Chinese medicine. Microchem J. 2022;183:10796. https://doi.org/10.1016/j.microc.2022.107964.CrossRef

[37]

Chen Y, Zheng G, Shi QF, Zhao RF, Chen M. Preparation of thiolated calix[8]arene/AuNPs/MWCNTs modified glassy carbon electrode and its electrocatalytic oxidation toward paracetamol. Sens Actuators B Chem. 2018;277:289. https://doi.org/10.1016/j.snb.2018.09.012.CrossRef

Title: A flexible electrochemical sensor for paracetamol based on porous honeycomb-like NiCo-MOF nanosheets
Authors: Xiu-Li Liu
Jia-Wei Guo
Ya-Wen Wang
Ai-Zhu Wang
Xin Yu
Long-Hua Ding
Publication date: 27-08-2023
Publisher: Nonferrous Metals Society of China
Published in: Rare Metals / Issue 10/2023
Print ISSN: 1001-0521
Electronic ISSN: 1867-7185
DOI: https://doi.org/10.1007/s12598-023-02349-2

Springer Professional

Graphical abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 10/2023

Microstructure and properties of as-cast Zr-2.5Nb-1X (X = Ru, Mo, Ta and Si) alloys for biomedical application

Flexible silver nanorods/carbon fiber felt metacomposites with epsilon-near-zero property adjusted by compressive deformation

Arranging cation mixing and charge compensation of TiNb2O7 with W6+ doping for high lithium storage performance

Superfunctional high-entropy alloys and ceramics by severe plastic deformation

Engineering in amino acid-functionalized double-layer heteropolymolybdates: from structural control to catalytic activity

Synthesis methods and applications of high entropy nanoparticles

Premium Partners