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Topics in Catalysis
Published in: Topics in Catalysis 1-4/2019

07-12-2018 | Original Paper

A New Class of MnCeOx Materials for the Catalytic Gas Exhausts Emission Control: A Study of the CO Model Compound Oxidation

Authors: Francesco Arena, Roberto Di Chio, Claudia Espro, Barbara Fazio, Alessandra Palella, Lorenzo Spadaro

Published in: Topics in Catalysis | Issue 1-4/2019

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Abstract

The effects of cerium addition on the physical–chemical properties and CO oxidation activity of nanocomposite MnCeOx catalysts (0 ≤ χCe ≤ 1) have been assessed. The kinetics of the CO oxidation on a typical nanocomposite MnCeOx catalyst (M5C1) were probed by temperature programmed catalytic reaction tests in the range of 293–533K. A systematic study of the interaction pattern of the catalyst with reagent and product molecules shows easy reactivity of surface oxygen to CO, low mobility of lattice oxygen and weak surface affinity to CO2. Systematic evidences on mechanism and intermediates signal an extrafacial redox path, triggered by the abstraction of oxygen atoms in the neighbouring of surface-active MnIV sites, and sustained by O2 species adsorbed on the resulting O-vacancies. A Langmuir–Hinshelwood (L–H) type reaction mechanism leads to a formal kinetic model fully predicting the CO oxidation functionality of the MnCeOx catalysts.
previous article Dynamics of Two-Step CO Oxidation Light-Off on Pt/-AlO and Pd/-AlO in the Presence of CH
next article Definitive Assessment of the Level of Risk of Exhausted Catalysts: Characterization of Ni and V Contaminates at the Limit of Detection

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Literature
1.
2.
Arena F, Di Chio R, Fazio B, Espro C, Spiccia L, Palella A, Spadaro L (2017) Appl Catal B 210:14CrossRef
3.
Arena F, Di Chio R, Filiciotto L, Espro C, Palella A, Patti A, Spadaro L (2017) Appl Catal B 218:803CrossRef
4.
Arena F, Trunfio G, Fazio B, Negro J, Spadaro L (2009) J Phys Chem C 113(7):2822CrossRef
5.
Beckera E, Thormählen P, Maunula T, Suopanki A, Skoglundh.M (2007) Top Catal 42–43:421CrossRef
6.
Brooks C, Cypes S, Grasselli RK, Hagemeyer A, Hogan Z, Lesik A, Streukens G, Volpe AF Jr, Turner HW, Weinberg WH, Yaccato K (2006) Top Catal 38(1–3):195CrossRef
7.
Kolli T, Huuhtanen M, Kanerva T, Vippola M, Kallinen K, Kinnunen T, Lepistö T, Lahtinen J, Keiski RL (2011) Top Catal 54:1185CrossRef
8.
Kolli T, Kanerva T, Lappalainen P, Huuhtanen M, Vippola M, Kinnunen T, Kallinen K, Lepistö T, Lahtinen J Keiski RL (2009) Top Catal 52:2025CrossRef
9.
Hao X, Shan B, Hyun J, Kapur N, Fujdala K, Truex T, Cho K (2009) Top Catal 52:1946CrossRef
10.
Matsuoka M, Iino K, Chen H, Yamasaki Y, Marta G, Coluccia S, Anpo M (2005) Catal Lett 102(3–4):149CrossRef
11.
12.
13.
14.
Vershinin NN, Efimov ON, Kabachkov EN, Kurkin EN (2018) Kinet Catal 59(2):174CrossRef
15.
16.
17.
Wang S-P, Zheng X-C, Wang X-Y, Wang S-R, Zhang S-M, Yu L-H, Huang W-P, Wu S-H (2005) Catal Lett 105(3–4):163CrossRef
18.
19.
Lin J, Guo Y, Li C, Lu S, Chen X, Li C, Lu S, Liew KM (2018) Catal Lett 148:181CrossRef
20.
Arena F, Di Chio R, Gumina B, Spadaro L, Trunfio G (2015) Inorg Chim Acta 431:101CrossRef
21.
Arena F, Spadaro L, International Application No.: PCT/IT2012/000172; US No.: 14/125,308
22.
Arena F, Gumina B, Lombardo AF, Espro C, Patti A, Spadaro L, Spiccia L (2015) Appl Catal B 162:260CrossRef
23.
24.
Li D, Yang J, Tang W, Wu X, Wei L, Chen Y (2014) RCS Adv 4:26796
25.
Selvakumar K, Kumar SMS, Thangamuthu R, Ganesan K, Murugan P, Rajput P, Jha SN, Bhattacharyya D (2015) J Phys Chem C 119:6604CrossRef
26.
27.
Fazio B, Spadaro L, Trunfio G, Negro J, Arena F (2011) J Raman Spectr 42:1583CrossRef
28.
29.
30.
31.
Zhang X, Wei J, Liu X, Liu W, Zhang C, Yang Y (2013) Eur J Inorg Chem 25:4443CrossRef
32.
Zhang P, Lu H, Zhou Y, Zhang L, Wu Z, Yang S, Shi H, Zhu Q, Chen Y, Dai S (2015) Nat Commun 6:1
33.
Arena F, Famulari P, Interdonato N, Bonura G, Frusteri F, Spadaro L (2006) Catal Today 116:384CrossRef
34.
35.
36.
Arena F, Di Chio R, Espro C, Palella A, Spadaro L (2018) React Chem Eng 3:293CrossRef
37.
Li C, Sakata Y, Arai T, Domen K, Maruya K, Onishi T (1989) J Chem Soc Faraday Trans I 85:929CrossRef
38.
Craciun R, Nentwick B, Hadjiivanov K, Knözinger H (2003) Appl Catal A 243:67–79CrossRef
39.
Zhang X-m, Deng Y-Q, Tian P, Shang H-h, Xu J, Han Y-F (2016) Appl Catal B 191:179CrossRef
40.
41.
Metadata
Title
A New Class of MnCeOx Materials for the Catalytic Gas Exhausts Emission Control: A Study of the CO Model Compound Oxidation
Authors
Francesco Arena
Roberto Di Chio
Claudia Espro
Barbara Fazio
Alessandra Palella
Lorenzo Spadaro
Publication date
07-12-2018
Publisher
Springer US
Published in
Topics in Catalysis / Issue 1-4/2019
Print ISSN: 1022-5528
Electronic ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-018-1113-0

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