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Published in: Microsystem Technologies 4/2012

01-04-2012 | Technical Paper

A planar micro-concentrator/injector for low power consumption microchromatographic analysis of benzene and 1,3 butadiene

Authors: H. Lahlou, J.-B. Sanchez, Y. Mohsen, X. Vilanova, F. Berger, E. Llobet, X. Correig, V. Fierro, A. Celzard, I. Gràcia, C. Cané

Published in: Microsystem Technologies | Issue 4/2012

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Abstract

In the present study, we present the first steps of the development of a low power consumption GC microsystem for the analysis of benzene in the presence of butadiene, involved in petrochemical industrial applications. This system is made by coupling a low power consumption planar microhotplate based on a preconcentrator with good preconcentration capability and a spiral microchromatographic column that presents a separation capability of both compounds at room temperature, when tested in front of a gas sensor. The first characterization results of the device showed a successful injection of benzene and butadiene when placed in front of the micro-separation module.

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Literature
go back to reference Casalnuovo SA, Frye-Mason GC, Kottenstette RJ, Heller EJ, Matzke CM, Lewis PR, Mangineli RP et al (1999) Gas phase chemical detection with an integrated chemical analysis system. In: European frequency time forum, IEEE international frequency control symposium, Proceedings of the joint meeting, Besançon, France, pp 991–996 Casalnuovo SA, Frye-Mason GC, Kottenstette RJ, Heller EJ, Matzke CM, Lewis PR, Mangineli RP et al (1999) Gas phase chemical detection with an integrated chemical analysis system. In: European frequency time forum, IEEE international frequency control symposium, Proceedings of the joint meeting, Besançon, France, pp 991–996
go back to reference Da Silva MLP, Gameiro JG (2006) Pre-concentrators: trends and future needs. Revista Brasileira de Aplicações de Vácuo 25(3):123–130 Da Silva MLP, Gameiro JG (2006) Pre-concentrators: trends and future needs. Revista Brasileira de Aplicações de Vácuo 25(3):123–130
go back to reference EPA (1998) Carcinogenic effects of benzene: update EPA/60/p-97/001 U.S. Environmental Protection Agency. U.S. Government Printing Office, Washington EPA (1998) Carcinogenic effects of benzene: update EPA/60/p-97/001 U.S. Environmental Protection Agency. U.S. Government Printing Office, Washington
go back to reference Fierro V, Torné-Fernández V, Celzard A (2007) Methodical study of the chemical activation of Kraft lignin with KOH and NaOH. Microporous Mesoporous Mater 101:419–431CrossRef Fierro V, Torné-Fernández V, Celzard A (2007) Methodical study of the chemical activation of Kraft lignin with KOH and NaOH. Microporous Mesoporous Mater 101:419–431CrossRef
go back to reference Golay MJE et al (1958) Theory of chromatography in open and coated tubular columns with round and rectangular cross-sections. Gas Chromatogr 2:36–55 Golay MJE et al (1958) Theory of chromatography in open and coated tubular columns with round and rectangular cross-sections. Gas Chromatogr 2:36–55
go back to reference Hughes K (2001) 1,3-Butadiene: human health aspects. Concise International Chemical Assessment Document 30. World Health Organization, Geneva Hughes K (2001) 1,3-Butadiene: human health aspects. Concise International Chemical Assessment Document 30. World Health Organization, Geneva
go back to reference Ivanov P, Blanco F, Gràcia I, Sabaté N, Ruiz A, Vilanova X, Fonseca L, Figueras E, Santander J, Cané C (2007) Improvement of the gas sensor response via silicon μ-preconcentrator. Sens Actuators B 127(1):288–294CrossRef Ivanov P, Blanco F, Gràcia I, Sabaté N, Ruiz A, Vilanova X, Fonseca L, Figueras E, Santander J, Cané C (2007) Improvement of the gas sensor response via silicon μ-preconcentrator. Sens Actuators B 127(1):288–294CrossRef
go back to reference Jin C, Zellers ET (2009) Chemometric analysis of gas chromatographic peaks measured with a microsensor array: methodology and performance assessment. Sens Actuators B 139:548–556CrossRef Jin C, Zellers ET (2009) Chemometric analysis of gas chromatographic peaks measured with a microsensor array: methodology and performance assessment. Sens Actuators B 139:548–556CrossRef
go back to reference Kim M, Mitra S (2003) A microfabricated microconcentrator for sensors and gas chromatography. J Chromatogr A 996:1–11CrossRef Kim M, Mitra S (2003) A microfabricated microconcentrator for sensors and gas chromatography. J Chromatogr A 996:1–11CrossRef
go back to reference Kim SK, Chang H, Zellers ET (2009) Prototype micro gas chromatograph for breath biomarkers of respiratory disease. In: Proceedings of the Transducers’09, Denver, Colorado, USA Kim SK, Chang H, Zellers ET (2009) Prototype micro gas chromatograph for breath biomarkers of respiratory disease. In: Proceedings of the Transducers’09, Denver, Colorado, USA
go back to reference Lahlou H, Vilanova X, Fierro V, Celzard A, Llobet E, Correig X (2011a) Preparation and characterisation of a planar pre-concentrator for benzene based on different activated carbon materials deposited by air-brushing. Sens Actuators B 154(2):213–219CrossRef Lahlou H, Vilanova X, Fierro V, Celzard A, Llobet E, Correig X (2011a) Preparation and characterisation of a planar pre-concentrator for benzene based on different activated carbon materials deposited by air-brushing. Sens Actuators B 154(2):213–219CrossRef
go back to reference Lahlou H, Sanchez JB, Vilanova X, Berger F, Correig X, Fierro V, Celzard A (2011b) Towards a GC-based microsystem for benzene and 1,3 butadiene detection: pre-concentrator characterization. Sens Actuators B 156(2):680–688CrossRef Lahlou H, Sanchez JB, Vilanova X, Berger F, Correig X, Fierro V, Celzard A (2011b) Towards a GC-based microsystem for benzene and 1,3 butadiene detection: pre-concentrator characterization. Sens Actuators B 156(2):680–688CrossRef
go back to reference Lambertus GR, Fix CS, Reidy SM, Miller RA, Wheeler D, Nazarov E, Sacks R (2005) Silicon microfabricated column with microfabricated differential mobility spectrometer for GC analysis of volatile organic compounds. Anal Chem 77(23):7563–7571CrossRef Lambertus GR, Fix CS, Reidy SM, Miller RA, Wheeler D, Nazarov E, Sacks R (2005) Silicon microfabricated column with microfabricated differential mobility spectrometer for GC analysis of volatile organic compounds. Anal Chem 77(23):7563–7571CrossRef
go back to reference Lewis PR, Manginell P, Adkins DR, Kottenstette RJ, Wheeler DR, Sokolowski SS, Trudell DE et al (2006) Recent advancements in the gas-phase MicroChemLab. IEEE Sens J 6(3):784–795CrossRef Lewis PR, Manginell P, Adkins DR, Kottenstette RJ, Wheeler DR, Sokolowski SS, Trudell DE et al (2006) Recent advancements in the gas-phase MicroChemLab. IEEE Sens J 6(3):784–795CrossRef
go back to reference Lu CJ, Jin C, Zellers ET (2006) Chamber evaluation of a portable GC with tunable retention and microsensor-array detection for indoor air quality monitoring. J Environ Monitor 8:270–278CrossRef Lu CJ, Jin C, Zellers ET (2006) Chamber evaluation of a portable GC with tunable retention and microsensor-array detection for indoor air quality monitoring. J Environ Monitor 8:270–278CrossRef
go back to reference Matzke CM, Kottenstette RJ, Casalnuovo SA, Frye-Mason GC, Hudson ML, Sasaki DY, Manginell RP, Wong CC (1998) Microfabricated silicon gas chromatographic microchannels: fabrication and performance. In: Micromachining and microfabrication process technology IV 3511 of proceedings of SPIE, Santa Clara, Calif, pp 262–268 Matzke CM, Kottenstette RJ, Casalnuovo SA, Frye-Mason GC, Hudson ML, Sasaki DY, Manginell RP, Wong CC (1998) Microfabricated silicon gas chromatographic microchannels: fabrication and performance. In: Micromachining and microfabrication process technology IV 3511 of proceedings of SPIE, Santa Clara, Calif, pp 262–268
go back to reference Ohira SI, Toda K (2008) Micro gas analyzers for environmental and medical applications. Anal Chim Acta 619(2):143–156CrossRef Ohira SI, Toda K (2008) Micro gas analyzers for environmental and medical applications. Anal Chim Acta 619(2):143–156CrossRef
go back to reference Radadia AD, Masel RI, Shannon MA, Jerell JP, Cadwallader KR (2008) Micromachined GC columns for fast separation of organophosphonate and organosulfur compounds. Anal Chem 80(11):4087–4094CrossRef Radadia AD, Masel RI, Shannon MA, Jerell JP, Cadwallader KR (2008) Micromachined GC columns for fast separation of organophosphonate and organosulfur compounds. Anal Chem 80(11):4087–4094CrossRef
go back to reference Radadia AD, Salehi-Khojin A, Masel RI, Shannon MA (2010) The effect of microcolumn geometry on the performance of micro-gas chromatography columns for chip scale gas analyzers. Sens Actuators B 150:456–464CrossRef Radadia AD, Salehi-Khojin A, Masel RI, Shannon MA (2010) The effect of microcolumn geometry on the performance of micro-gas chromatography columns for chip scale gas analyzers. Sens Actuators B 150:456–464CrossRef
go back to reference Reston RR, Kolesar ES (1994) Silicon-micromachined gas chromatography system used to separate and detect ammonia and nitrogen dioxide. Part I: design, fabrication, and integration of the gas chromatography system. J Microelectromech Syst 3(4):134–146CrossRef Reston RR, Kolesar ES (1994) Silicon-micromachined gas chromatography system used to separate and detect ammonia and nitrogen dioxide. Part I: design, fabrication, and integration of the gas chromatography system. J Microelectromech Syst 3(4):134–146CrossRef
go back to reference Sanchez JB, Schmitt A, Berger F, Mavon C (2010) Silicon-micromachined gas chromatographic columns for the development of portable detection device. J Sens. doi:10.1155/2010/409687 Sanchez JB, Schmitt A, Berger F, Mavon C (2010) Silicon-micromachined gas chromatographic columns for the development of portable detection device. J Sens. doi:10.​1155/​2010/​409687
go back to reference Serrano G, Chang H, Zellers ET (2009) A micro gas chromatograph for highspeed determinations of explosive vapors. In: Proceedings of the transducers’09, Denver, Colorado Serrano G, Chang H, Zellers ET (2009) A micro gas chromatograph for highspeed determinations of explosive vapors. In: Proceedings of the transducers’09, Denver, Colorado
go back to reference Terry SC, Jerman JH, Angell JB (1979) A chromatographic air analyzer fabricated on a silicon wafer. IEEE Trans Electron Dev ED-26:1880–1886 Terry SC, Jerman JH, Angell JB (1979) A chromatographic air analyzer fabricated on a silicon wafer. IEEE Trans Electron Dev ED-26:1880–1886
go back to reference Voiculescu I, Zaghloul M, Narasimhan N (2008) Microfabricated chemical preconcentrators for gas phase microanalytical detection systems. Trends Anal Chem 27(4):327–343CrossRef Voiculescu I, Zaghloul M, Narasimhan N (2008) Microfabricated chemical preconcentrators for gas phase microanalytical detection systems. Trends Anal Chem 27(4):327–343CrossRef
go back to reference Wiranto G, Haskard MR, Mulcahy DE, Davey DE (1999) Microengineered open tubular columns for GC analysis. In: Electronics and structures for MEMS 3891 of proceedings of SPIE, Queensland, Australia, pp 168–177 Wiranto G, Haskard MR, Mulcahy DE, Davey DE (1999) Microengineered open tubular columns for GC analysis. In: Electronics and structures for MEMS 3891 of proceedings of SPIE, Queensland, Australia, pp 168–177
go back to reference Zampolli S, Betti P, Elmi I, Dalcanale E (2007) A supramolecular approach to sub-ppb aromatic VOC detection in air. Chem Commun 27:2790–2792CrossRef Zampolli S, Betti P, Elmi I, Dalcanale E (2007) A supramolecular approach to sub-ppb aromatic VOC detection in air. Chem Commun 27:2790–2792CrossRef
go back to reference Zampolli S, Elmi I, Mancarella F, Betti P, Dalcanale E, Cardinali GC, Severi M (2009) Realtime monitoring of sub-ppb concentrations of aromatic volatiles with a MEMS enabled miniaturized gas chromatograph. Sens Actuators B 141:322–328CrossRef Zampolli S, Elmi I, Mancarella F, Betti P, Dalcanale E, Cardinali GC, Severi M (2009) Realtime monitoring of sub-ppb concentrations of aromatic volatiles with a MEMS enabled miniaturized gas chromatograph. Sens Actuators B 141:322–328CrossRef
go back to reference Zellers ET, Reidy S, Veeneman RA, Gordenker R, Steinecker WH, Lambertus GR, Hanseup K et al (2007) An integrated microanalytical system for complex vapor mixtures. In: Proceedings of the Transducers’07, Lyon, France Zellers ET, Reidy S, Veeneman RA, Gordenker R, Steinecker WH, Lambertus GR, Hanseup K et al (2007) An integrated microanalytical system for complex vapor mixtures. In: Proceedings of the Transducers’07, Lyon, France
go back to reference Zhong Q, Steinecker WH, Zellers ET (2009) Characterization of a high-performance portable GC with a chemiresistor array detector. Analyst 134:283–293CrossRef Zhong Q, Steinecker WH, Zellers ET (2009) Characterization of a high-performance portable GC with a chemiresistor array detector. Analyst 134:283–293CrossRef
Metadata
Title
A planar micro-concentrator/injector for low power consumption microchromatographic analysis of benzene and 1,3 butadiene
Authors
H. Lahlou
J.-B. Sanchez
Y. Mohsen
X. Vilanova
F. Berger
E. Llobet
X. Correig
V. Fierro
A. Celzard
I. Gràcia
C. Cané
Publication date
01-04-2012
Publisher
Springer-Verlag
Published in
Microsystem Technologies / Issue 4/2012
Print ISSN: 0946-7076
Electronic ISSN: 1432-1858
DOI
https://doi.org/10.1007/s00542-012-1433-0

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