Top

Polymer Bulletin

Published in:

18-12-2019 | Original Paper

Adsorption of Ag(I) ions from wastewaters using poly(2-aminothiazole): kinetic and isotherm studies

Authors: Mutluhan Bıyıkoğlu, Hakan Çiftçi

Published in: Polymer Bulletin | Issue 12/2020

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

In this study, 2-aminothiazole, (2AT), was polymerized with benzoyl peroxide in 1,4-dioxane solution, and adsorption efficiencies of poly(2-aminothiazole), P-2AT, for the Ag(I) ions to remove from the aqueous solutions were investigated. Adsorption experiments were studied at different pH, contact time and initial Ag(I) ion concentration in a batch system. The optimal pH for Ag(I) adsorption onto P-2AT was found to be 5.0, and the maximum adsorption capacity was determined to be 336.98 mg/g for 1200 mg/L Ag(I) solution at 90 min. P-2AT adsorbents were followed up by recycling in multiple adsorption cycles. The results showed that adsorbent can be used several times. Ag(I) ion adsorption performance of the P-2AT was investigated in conjunction with Cu(II) and Zn(II) ions. The selectivity series of ions were found as Ag(I) > Cu(II) > Zn(II). According to the experimental data, the adsorption reaction fitted the pseudo-second-degree kinetic model and the Langmuir isotherm equation.

previous article Enhancement of adsorption of Congo red dye onto novel antimicrobial trimellitic anhydride isothiocyanate-cross-linked chitosan hydrogels

next article TEMPO-oxidized cellulose nanofibrils–graphene oxide composite films with improved dye adsorption properties

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Lin W, Ronge X, Song L, Huahua Y, Yukun Q, Kecheng L, Jinhua F, Rongfeng L, Pengcheng L (2010) Recovery of silver(I) using a thiourea-modified chitosan resin. J Hazard Mater 180:577–582

Mohan D, Chander S (2000) Single component and multi-component adsorption of metal ions by activated carbons. Colloids Surf A Physicochem Eng Asp 177:183–196

Jeon C, Park KH (2005) Adsorption and desorption characteristics of mercury(II) ions using aminated chitosan bead. Water Res 39:3938–3944PubMed

Lin SH, Lai SL, Leu HG (2000) Removal of heavy metals from aqueous solution by chelating resin in a multistage adsorption process. J Hazard Mater B76:139–153

Mathialagan T, Viraraghavan T (2002) Adsorption of cadmium from aqueous solutions by perlite. J Hazard Mater B94:291–303

Chen JP, Lim LL (2002) Key factors in chemical reduction by hydrazine for recovery of precious metals. Chemosphere 49:363–370PubMed

Ghassabzadeh H, Mohadespour A, Torab-Mostaedi M, Zaheri P, Maragheh MG, Taheri H (2010) Adsorption of Ag, Cu and Hg from aqueous solutions using expanded perlite. J Hazard Mater 177:950–955PubMed

Akgül M, Karabakan A, Acar O, Yürüm Y (2006) Removal of silver(I) from aqueous solutions with clinoptilolite. Micropor Mesopor Mater 94:99–104

Hongyan H, Haijia S, Tianwei T (2009) Adsorption of Ag⁺ by a surface molecular-imprinted biosorbent. Chem Eng J 150:139–144

10.

Mack C, Wilhelmi BJ, Duncan R, Burgess JE (2007) Research review paper: biosorption of precious metals. Biotechnol Adv 25:264–271PubMed

11.

Jeon C (2017) Adsorption and recovery of immobilized coffee ground beads for silver ions from industrial wastewater. J Ind Eng Chem 53:261–267

12.

Gill GA, Santschi PH, Liang-Saw W, Degui T (2002) Silver concentration in Colorado, USA, Watersheds using improved methodology. Environ Toxicol Chem 21:2040–2051PubMed

13.

Soylak M, Erdogan ND (2006) Copper(II)-rubeanic acid coprecipitation system for separation-preconcentration of trace metal ions in environmental samples for their flame atomic absorption spectrometric determinations. J Hazard Mater 137:1035–1041PubMed

14.

Uluözlu OD, Tüzen M, Mendil D, Soylak M (2010) Coprecipitation of trace elements with Ni²⁺/2-nitroso-1-naphthol-4-sulfonic acid and their determination by flame atomic absorption spectrometry. J Hazard Mater 176:1032–1037PubMed

15.

Pillai KC, Chung SJ, Moon II-S (2008) Studies on electrochemical recovery of silver from simulated waste water from Ag(II)/Ag(I) based mediated electrochemical oxidation process. Chemosphere 73:1505–1511

16.

Borowiak-Resterna A, Cierpiszewski R, Prochaska K (2010) Kinetic and equilibrium studies of the removal of cadmium ions from acidic chloride solutions by hydrophobic pyridinecarboxamide extractants. J Hazard Mater 179:828–833PubMed

17.

Sonune A, Grate R (2004) Developments in wastewater treatment methods. Desalination 167:55–63

18.

Chaudhari LB, Murthy ZVP (2010) Separation of Cd and Ni from multicomponent aqueous solutions by nanofiltration and characterization of membrane using IT model. J Hazard Mater 180:309–315PubMed

19.

Caprarescu S, Corobea MC, Purcar V, Spataru CI, Ianchis R, Vasilievici G, Vuluga Z (2015) San copolymer membranes with ion exchangers for Cu(II) removal from synthetic wastewater by electrodialysis. J Environ Sci 35:27–37

20.

Caprarescu S, Ianchis R, Radu AL, Sarbu A, Somoghi R, Trica B, Alexandrescu E, Spataru CI, Fierascu RC, Ebrasu DI, Preda S, Atanase LI, Dan D (2017) Synthesis, characterization and efficiency of new organically modified montmorillonite polyethersulfone membranes for removal of zinc ions from wastewasters. Appl Clay Sci 137:135–142

21.

Caprarescu S, Radu AL, Purcar V, Ianchis R, Sarbu A, Ghiurea M, Nicolae C, Modrogan C, Vaireanu DI, Périchaud A, Ebrasu DI (2015) Adsorbents/ion exchangers-PVA blend membranes: Preparation, characterization and performance for the removal of Zn²⁺ by electrodialysis. Appl Surf Sci 329:65–75

22.

Güvenç A, Karabacakoğlu B (2005) Use of electrodialysis to remove silver ions from model solutions and wastewater. Desalination 172:7–17

23.

Kentaro M, Junichii I, Tatsushi M, Hideo Y (2010) Straight-chained thermoresponsive polymer with high chelating group content for heavy metal ion recovery. Sep Purif Technol 75:69–75

24.

Tokalioglu S, Yilmaz V, Kartal S, Delibas A, Soykan C (2009) Synthesis of a novel chelating resin and its use for selective separation and preconcentration of some trace metals in water samples. J Hazard Mater 169:593–598PubMed

25.

Qun H, Zheng H, Yin J, Xijun C, Zhifeng T, Lina Z (2010) Preconcentration of Cu(II), Fe(III) and Pb(II) with 2-((2-aminoethylamino)methyl)phenol-functionalized activated carbon followed by ICP-OES determination. J Hazard Mater 175:710–714

26.

Zhifeng T, Qun H, Xijun C, Zheng H, Ru G, Lina Z, Zhenhua L (2009) 1-(2-Formamidoethyl)-3-phenylurea functionalized activated carbon for selective solid-phase extraction and preconcentration of metal ions. Anal Chim Acta 649:252–257

27.

Silva EL, Martins AO, Valentini A, Favere VT, Carasek E (2004) Application of silica gel organofunctionalized with 3(1-imidazolyl)propyl in an on-line preconcentration system for the determination of copper by FAAS. Talanta 64:181–189PubMed

28.

Xiaojun Z, Yuemei C, Xijun C, Xiangbing Z, Zheng H, Dong Y (2009) Silica gel surface modified with sulfanilamide for selective solid-phase extraction of Cu(II), Zn(II) and Ni(II). Int J Environ Anal Chem 89:1043–1055

29.

Kensuke F, Attinti R, Teruya M, Hiroshi H, Kazumasa U (2007) Adsorption of platinum(IV), palladium(II) and gold(III) from aqueous solutions onto l-lysine modified crosslinked chitosan resin. J Hazard Mater 146:39–50

30.

Ding Z, Frost RL (2004) Study of copper adsorption on montmorillonites using thermal analysis methods. J Colloid Interf Sci 269:296–302

31.

Gupta VK, Jain CK, Sharma M (2003) Removal of cadmium and nickel from wastewater using bagasse fly ash—a sugar industry waste. Water Res 37:4038–4044PubMed

32.

Junsheng L, Yue M, Tongwen X, Guoquan S (2010) Preparation of zwitterionic hybrid polymer and its application for the removal of heavy metal ions from water. J Hazard Mater 178:1021–1029

33.

Buyi L, Fabing S, He-Kuan L, Liyun L, Bien T (2011) Hypercrosslinked microporous polymer networks for effective removal of toxic metal ions from water. Micropor Mesopor Mater 138:207–214

34.

Jie D, Han Y, Hu Y, Rongshi C (2010) Simple method for preparation of chitosan/poly(acrylic acid) blending hydrogel beads and adsorption of copper(II) from aqueous solutions. Chem Eng J 165:240–249

35.

Jinnan W, Aimin L, Li X, Yang Z (2009) Adsorption of tannic and gallic acids on a new polymeric adsorbent and the effect of Cu(II) on their removal. J Hazard Mater 69:794–800

36.

Filho NLD, do Carmo DR, Rosa AH (2006) An electroanalytical application of 2-aminothiazole-modified silica gel after adsorption and separation of Hg(II) from heavy metals in aqueous solution. Electrochim Acta 52:965–972

37.

Qiang-Feng Y, Ben-Zhi J, Shu-Fen Z, Xin-Bo W, Jin-Zong Y (2008) Preparation and characteristics of novel dialdehyde aminothiazole starch and its adsorption properties for Cu(II) ions from aqueous solution. Carbohydr Polym 72:326–333

38.

Tsyurupa MP, Davankov VA (2006) Porous structure of hyper-cross-linked polystyrene: state-of-the-art mini-review. React Funct Polym 66:768–779

39.

William D, Birkinshaw C, Francis T (2008) Heavy metal adsorbents prepared from the modification of cellulose: a review. Bioresour Technol 99:6709–6724

40.

Bingjun P, Bingcai P, Weiming Z, Lu L, Quanxing Z, Shourong Z (2009) Development of polymeric and polymer-based hybrid adsorbents for pollutants removal from waters. Chem Eng J 151:19–29

41.

Jianhan H, Kelong H, Suqin L (2009) Tertiary amino groups modified macroporous crosslinked poly(styrene-co-divinylbenzene) and its oxidized adsorbent: synthesis, characterization, and adsorption behavior. J Hazard Mater 162:771–776

42.

Filho NLD (1999) Adsorption and structure of copper(II) complexes on a silica gel surface chemically modified with 2-aminothiazole. Polyhedron 18:2241–2247

43.

Roldan PS, Alcantara IL, Castro GR, Rocha JC (2003) Determination of Cu, Ni, and Zn in fuel ethanol by FAAS after enrichment in column packed with 2-aminothiazole-modified silica gel. Anal Biochem 375:574–577

44.

Çiftçi H, Testereci HN, Öktem Z (2013) Preconcentration and electroanalysis of silver at Pt electrode modified with poly(2-aminothiazole). Russ J Electrochem 49(12):1160–1164

45.

Bıyıkoğlu M, Çiftçi H (2013) Chemical synthesis and characterization of soluble conducting poly(2-aminothiazole). Polym Bull 70(10):2843–2856

46.

Sarı A, Tüzen M, Çıtak D, Soylak M (2007) Adsorption characteristics of Cu(II) and Pb(II) onto expanded perlite from aqueous solution. J Hazard Mater 148:387–394PubMed

47.

Alkan M, Karadas M, Doğan M, Demirbas Ö (2005) Adsorption of CTAB onto perlite samples from aqueous solutions. J Colloid Interface Sci 291:309–318PubMed

48.

Üçer A, Uyanik A, Aygün ŞF (2006) Adsorption of Cu(II), Cd(II), Zn(II), Mn(II) and Fe(III) ions by tannic acid immobilised activated carbon. Sep Purif Technol 47:113–118

49.

Sengil IA, Ozacar M (2009) Competitive biosorption of Pb²⁺, C^u2+ and Zⁿ²+ ions from aqueous solutions onto valonia tannin resin. J Hazard Mater 166:1488–1494PubMed

50.

Çoruh S, Şenel G, Ergun OS (2010) A comparison of the properties of natural clinoptilolites and their ion-exchange capacities for silver removal. J Hazard Mater 180:486–492PubMed

51.

Ye-Shih H, McKay G (2000) The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Res 34:735–742

52.

Godiyaa CB, Chenga X, Denga G, Lib D, Lua X (2019) Silk fibroin/polyethylenimine functional hydrogel for metal ion adsorption and upcycling utilization. J Env Chem Eng 7:102806–102817

53.

Yanga T, Zhanga L, Zhonga L, Hana X, Donga S, Li Y (2018) Selective adsorption of Ag(I) ions with poly(vinyl alcohol) modified with thiourea (TU–PVA). Hydrometallurgy 175:179–186

54.

Jianhan H, Kelong H, Suqin L, Leong S, Su J, Kean W, Rong X (2011) Surface activated carbon nanospheres for fast adsorption of silver ions from aqueous solutions. J Hazard Mater 194:162–168

55.

Salem MA, Elsharkawy RG, Hablas MF (2016) Adsorption of brilliant green dye by polyaniline/silver nanocomposite: Kinetic, equilibrium, and thermodynamic studies. Eur Polym J 75:577–590

56.

Alkan M, Dogan M (2001) Adsorption of copper(II) onto perlite. J Colloid Interface Sci 243:280–291

57.

Atia A, Donia A, Yousif A (2005) Comparative study of the recovery of silver(I) from aqueous solutions with different chelating resins derived from glycidyl methacrylate. J Appl Poly Sci 97:806–812

58.

Yi Y, Wang YT, Liu H (2003) Preparation of new crosslinked chitosan with crownether and their adsorption for silver ion for antibacterial activities. Carbohdr Poly 53:425–430

59.

Ma J, Shen J, Wang C, Wei Y (2018) Preparation of dual-function chelating resin with high capacity and adjustable adsorption selectivity to variety of heavy metal ions. J Taiw Inst Chem Eng 91:532–538

Title: Adsorption of Ag(I) ions from wastewaters using poly(2-aminothiazole): kinetic and isotherm studies
Authors: Mutluhan Bıyıkoğlu
Hakan Çiftçi
Publication date: 18-12-2019
Publisher: Springer Berlin Heidelberg
Published in: Polymer Bulletin / Issue 12/2020
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI: https://doi.org/10.1007/s00289-019-03073-7

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 12/2020

Simple method to obtaining a prolonged-release system of urea based on wheat gluten: development and characterization

Effect of 60 keV argon ion implantation in Makrofol® DE 1-1 on the optical properties

The impact of MWCNT modification on the structural performance of polymeric composite profiles

A semi-empirical model for thermal conductivity of polymer nanocomposites containing carbon nanotubes

Strong alginate/reduced graphene oxide composite hydrogels with enhanced dye adsorption performance

Synthesis and characterization of an aromatic diamine and its polyimides containing asymmetric large side groups

Premium Partners