Top

Colloid and Polymer Science

Published in:

01-10-2015 | Original Contribution

Adsorption of an anionic surfactant at air-liquid and different solid-liquid interfaces from solutions containing high counter-ion concentration

Authors: Sagheer A. Onaizi, M. S. Nasser, Nasir M. A. Al-Lagtah

Published in: Colloid and Polymer Science | Issue 10/2015

Activate our intelligent search to find suitable subject content or patents.

search-config

AI-assisted search

Off

Abstract

The self-assembly (adsorption) of the anionic surfactant, sodium dodecylbenzenesulphonate (SDBS), at air-liquid and different (octadecanethiol, β-mercaptoethanol, α-lipoic acid) solid-liquid interfaces from aqueous solutions containing high concentrations of counter-ion has been investigated. SDBS adsorption at the solid-liquid interfaces was obtained using surface plasmon resonance (SPR) while its adsorption at the air-liquid interface was extracted from surface tension measurements. The results have demonstrated that SDBS packing at the air-liquid interface is similar to its packing at the hydrophobic octadecanethiol-liquid interface. Additionally, SDBS packing at the three solid-liquid interfaces increases with increasing surface hydrophobicity, irrespective whether the surface is neutral or negatively charged. Nonetheless, SDBS adsorption is always within monolayer coverage (no evidence of bilayer or admicelle formation). The results have also revealed that SDBS affinity for the solid-liquid interfaces increases with increasing surface hydrophobicity. Furthermore, SDBS affinity for the air-liquid interface is more than 10-fold its affinity for the solid-liquid interfaces.

previous article Spontaneous evolution of self-assembled phases from anisotropic colloidal dispersions

next article Anion effect on the aggregation behavior of the long-chain spacers dicationic imidazolium-based ionic liquids

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

inform now

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

inform now

Cotoruelo LM et al. (2009) Lignin-based activated carbons for adsorption of sodium dodecylbenzene sulfonate: equilibrium and kinetic studies. J Colloid Interface Sci 332:39–45CrossRef

Phan CM, Nguyen AV, Evans GM (2005) Dynamic adsorption of sodium dodecylbenzene sulphonate and dowfroth 250 onto the air–water interface. Miner Eng 18:599–603CrossRef

Ozdemir U et al. (2011) Modeling adsorption of sodium dodecyl benzene sulfonate (SDBS) onto polyaniline (PANI) by using multi linear regression and artificial neural networks. Chem Eng J 178:183–190CrossRef

Vale HM, McKenna TF (2005) Adsorption of sodium dodecyl sulfate and sodium dodecyl benzenesulfonate on poly(vinyl chloride) latexes. Colloids Surfaces A: Physicochem Eng Asp 268(2005):68–72CrossRef

Onaizi SA, Nasser MS, Twaiq FA (2012) Micellization and interfacial behavior of a synthetic surfactant–biosurfactant mixture. Colloids Surfaces A: Physicochem Eng Asp 415:388–393CrossRef

Knoll W (1998) Interfaces and thin films as seen by bound electromagnetic waves. Annu Rev Phys Chem 49:569–638CrossRef

He L et al. (2009) Cooperative tuneable interactions between a designed peptide biosurfactant and positional isomers of SDOBS at the air-water interface. Langmuir 25:4021–2026CrossRef

He L et al. (2011) Comparison of positional surfactant isomers for displacement of rubisco protein from the air–water interface. J Colloid Interface Sci 360:617–622CrossRef

Ma J-G, Boyd BJ, Drummond CJ (2006) Positional isomers of linear sodium dodecyl benzene sulfonate: solubility, self-assembly, and air/water interfacial activity. Langmuir 22:8646–8654CrossRef

10.

Onaizi SA, Leong SSJ (2011) Tethering antimicrobial peptides: current status and potential challenges. Biotechnol Adv 29:67–74CrossRef

11.

Onaizi SA, Nasser MS, Twaiq FA (2014) Lysozyme binding to tethered bilayer lipid membranes prepared by rapid solvent exchange and vesicle fusion methods. Eur Biophys J 43:191–198CrossRef

12.

Onaizi SA, He L, Middelberg APJ (2009) Proteolytic cleaning of a surface-bound rubisco protein stain. Chem Eng Sci 64:3868–3878CrossRef

13.

Onaizi SA, He L, Middelberg APJ (2009) Rapid screening of surfactant and biosurfactant surface cleaning performance. Colloids Surf B 72:68–74CrossRef

14.

Onaizi SA, He L, Middelberg APJ (2010) The construction, fouling and enzymatic cleaning of a textile dye surface. J Colloid Interface Sci 351:203–209CrossRef

15.

Zhang XL et al. (2011) The role of electrolyte and polyelectrolyte on the adsorption of the anionic surfactant, sodium dodecylbenzenesulfonate, at the air–water interface. J Colloid Interface Sci 356:656–664CrossRef

16.

Ghosh P (2009) Colloid and interface science. PHI Learning Private Pvt Ltd., New Delhi

17.

Lin S-Y et al. (2002) Determination of adsorption of an ionic surfactant on latex from surface tension measurements. Colloids Surf A Physicochem Eng Asp 196:189–198CrossRef

18.

Delgado C et al. (2006) Effect of surfactant structure on the adsorption of carboxybetaines at the air–water interface. Colloids Surfaces A: Physicochem Eng Asp 280:17–22CrossRef

19.

Onaizi SA, Nasser MS, Twaiq FA (2014) Adsorption and thermodynamics of biosurfactant, surfactin, monolayers at the air-buffered liquid interface. Colloid Polym Sci 292:1649–1656CrossRef

20.

Giribabu K, Ghosh P (2007) Adsorption of nonionic surfactants at fluid–fluid interfaces: importance in the coalescence of bubbles and drops. Chem Eng Sci 62:3057–3067CrossRef

21.

Ertekin A et al. (2009) Adsorption properties of oligo(fluorooxetane)-b-poly(ethylene oxide)-b-oligo(fluorooxetane) triblock copolymers at the air–water interface: comparison of hydroxyl and acetate end groups. J Colloid Interface Sci 336:40–45CrossRef

22.

Kumar N, Couzis A, Maldarelli C (2003) Measurement of the kinetic rate constants for the adsorption of superspreading trisiloxanes to an air/aqueous interface and the relevance of these measurements to the mechanism of superspreading. J Colloid Interface Sci 267:272–285CrossRef

23.

Li J, Miller R, Mohwald H (1996) Characterisation of phospholipid layers at liquid interfaces. 1. Dynamics of adsorption of phospholipids at the chloroform/water interface. Colloids Surf A: Physicochem Eng Asp 114:113–121CrossRef

24.

Mucic N et al. (2011) Dynamics of interfacial layers—experimental feasibilities of adsorption kinetics and dilational rheology. Adv Colloid Interf Sci 168:167–178CrossRef

25.

Onaizi SA et al. (2007) Directed disassembly of an interfacial rubisco protein network. Langmuir 23:6336–6341CrossRef

26.

Paria S, Khilar KC (2004) A review on experimental studies of surfactant adsorption at the hydrophilic solid–water interface. Adv Colloid Interf Sci 110:75–95CrossRef

27.

Neto AOW et al. (2014) Recent advances on the use of surfactant systems as inhibitors of corrosion on metallic surfaces. In: Fanun M (ed) The role of colloidal systems in environmental protection. Elsevier, Amsterdam

28.

Georgieva D, Cagna A, Langevin D (2009) Link between surface elasticity and foam stability. Soft Matter 5:2063–2071CrossRef

29.

Eastoe J, Tabor RF (2014) Surfactants and Nanoscience. In: Berti D, Palazzo G (eds) Colloidal Foundations of Nanoscience. Elsevier, Amsterdam

30.

Rangel EC et al. (2011) Treatment of PVC using an alternative low energy ion bombardment procedure. Appl Surf Sci 258:1854–1861CrossRef

31.

Turner SF et al. (1999) Adsorption of sodium dodecyl sulfate to a polystyrene/water interface studied by neutron reflection and attenuated total reflection infrared spectroscopy. Langmuir 15:1017–1023CrossRef

32.

Zwetsloot JPH, Leyte JC (1995) The determination of the adsorption of an ionic surfactant on latex from conductivity measurements. J Colloid Interface Sci 175:1–5CrossRef

33.

Baier RE, Meyer AE (1996) Physics of solid surfaces. In: Brash JL, Wojciechowski PW (eds) Interfacial phenomena and bioproducts. Marcel Dekker, New York

34.

Klis FM et al. (2007) Extraction of cell surface-associated proteins from living yeast cells. Yeast 24:253–258CrossRef

35.

Zollars RL (1999) Ionic adsorbates on hydrophobic surfaces. In: Schwarz JA, Contescu CI (eds) Surfaces of nanoparticles and porous materials. Marcel Dekker, Inc, New York

36.

Karakashev SI, Manev ED (2002) Effect of interactions between the adsorbed species on the properties of single and mixed-surfactant monolayers at the air/water interface. J Colloid Interface Sci 248:477–486CrossRef

37.

Karakashev SI, Manev ED (2003) Correlation in the properties of aqueous single films and foam containing a nonionic surfactant and organic/inorganic electrolytes. J Colloid Interface Sci 259:171–179CrossRef

38.

Fainerman VB, Lucassen-Reynders EH, Miller R (1998) Adsorption of surfactants and proteins at fluid interfaces. Colloids Surf A Physicochem Eng Asp 143:141–165CrossRef

39.

Cheng Q, Brajter-Toth A (1996) Permselectivity, sensitivity, and amperometric pH sensing at thioctic acid monolayer microelectrodes. Anal Chem 68:4180–4185CrossRef

40.

Ahualli S et al. (2011) Adsorption of anionic and cationic surfactants on anionic colloids: supercharging and destabilization. Langmuir 27:9182–9192CrossRef

41.

Denoyel R, Rouquerol J (1991) Thermodynamic (including microcalorimetry) study of the adsorption of nonionic and anionic surfactants onto silica, kaolin, and alumina. J Colloid Interface Sci 143:555–572CrossRef

42.

Dick SG, Fuerstenau DW, Healy TW (1971) Adsorption of alkylbenzene sulfonate (A.B...S.) surfactants at the alumina-water interface. J Colloid Interface Sci 37:595–602CrossRef

43.

Healy TW, Somasundaran P, Fuerstenau DW (2003) The adsorption of alkyl and alkylbenzene sulfonates at mineral oxide–water interfaces. Int J Miner Process 72:3–10CrossRef

44.

Hu K, Bard AJ (1997) Characterization of adsorption of sodium dodecyl sulfate on charge-regulated substrates by atomic force microscopy force measurements. Langmuir 13:5418–5425CrossRef

45.

Ma K et al. (2013) Adsorption of cationic and anionic surfactants on natural and synthetic carbonate materials. J Colloid Interface Sci 408:164–172CrossRef

46.

Thibaut, A., et al., Adsorption of an aqueous mixture of surfactants on silica. Langmuir, 2000. 16: p. 9192-9198.

47.

Fragneto G et al. (1996) A neutron reflectivity study of the adsorption of aerosol-OT on self-assembled monolayers on silicon. J Colloid Interface Sci 178:531–537CrossRef

Title: Adsorption of an anionic surfactant at air-liquid and different solid-liquid interfaces from solutions containing high counter-ion concentration
Authors: Sagheer A. Onaizi
M. S. Nasser
Nasir M. A. Al-Lagtah
Publication date: 01-10-2015
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 10/2015
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-015-3694-5

Springer Professional

Abstract

Please log in to get access to your license.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Other articles of this Issue 10/2015

Interaction of two imidazolium gemini surfactants with two model proteins BSA and HEWL

Effect of carbon dioxide on self-setting apatite cement formation from tetracalcium phosphate and dicalcium phosphate dihydrate; ATR-IR and chemoinformatics analysis

Spontaneous evolution of self-assembled phases from anisotropic colloidal dispersions

Elaboration of sponge-like particles for textile functionalization and skin penetration

Fabrication of non-close-packed colloidal monolayers by convective self-assembly using cationic polyelectrolyte-grafted silica particles

Anion effect on the aggregation behavior of the long-chain spacers dicationic imidazolium-based ionic liquids

Premium Partners