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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 10/2015

01.10.2015 | Original Contribution

Adsorption of an anionic surfactant at air-liquid and different solid-liquid interfaces from solutions containing high counter-ion concentration

verfasst von: Sagheer A. Onaizi, M. S. Nasser, Nasir M. A. Al-Lagtah

Erschienen in: Colloid and Polymer Science | Ausgabe 10/2015

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Abstract

The self-assembly (adsorption) of the anionic surfactant, sodium dodecylbenzenesulphonate (SDBS), at air-liquid and different (octadecanethiol, β-mercaptoethanol, α-lipoic acid) solid-liquid interfaces from aqueous solutions containing high concentrations of counter-ion has been investigated. SDBS adsorption at the solid-liquid interfaces was obtained using surface plasmon resonance (SPR) while its adsorption at the air-liquid interface was extracted from surface tension measurements. The results have demonstrated that SDBS packing at the air-liquid interface is similar to its packing at the hydrophobic octadecanethiol-liquid interface. Additionally, SDBS packing at the three solid-liquid interfaces increases with increasing surface hydrophobicity, irrespective whether the surface is neutral or negatively charged. Nonetheless, SDBS adsorption is always within monolayer coverage (no evidence of bilayer or admicelle formation). The results have also revealed that SDBS affinity for the solid-liquid interfaces increases with increasing surface hydrophobicity. Furthermore, SDBS affinity for the air-liquid interface is more than 10-fold its affinity for the solid-liquid interfaces.
Vorheriger Artikel Spontaneous evolution of self-assembled phases from anisotropic colloidal dispersions
Nächster Artikel Anion effect on the aggregation behavior of the long-chain spacers dicationic imidazolium-based ionic liquids

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Metadaten
Titel
Adsorption of an anionic surfactant at air-liquid and different solid-liquid interfaces from solutions containing high counter-ion concentration
verfasst von
Sagheer A. Onaizi
M. S. Nasser
Nasir M. A. Al-Lagtah
Publikationsdatum
01.10.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 10/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3694-5

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