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Journal of Sol-Gel Science and Technology

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01-06-2018 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous silica modified with phosphonic acid groups

Authors: Yulia S. Fetisova, Oksana A. Dudarko, Maja Bauman, Aleksandra Lobnik, Valeriia V. Sliesarenko

Published in: Journal of Sol-Gel Science and Technology | Issue 1/2018

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Abstract

The mesoporous silica samples with different concentrations of phosphonic acid groups on the surface were obtained by direct template synthesis. The block-copolymer Pluronic P123 was used as a template, and sodium meta-silicate with diethylphosphatoethyltriethoxysilane as precursors. According to the SAXS diffractograms, mesoporous silica samples have a p6mm hexagonal symmetry. In addition, we used sol–gel method to synthesize xerogel with the same groups for comparison. All samples possess high values of specific surface area 615–730 m²/g and sorption pore volume. FTIR and potentiometric titration methods were used to investigate the surface layer of these samples. Sorption properties of the samples with phosphonic acid groups were studied in respect to a row of metal cations, among which we focused on lead(II), cadmium(II), and dysprosium(III) cations.

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Title: Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous silica modified with phosphonic acid groups
Authors: Yulia S. Fetisova
Oksana A. Dudarko
Maja Bauman
Aleksandra Lobnik
Valeriia V. Sliesarenko
Publication date: 01-06-2018
Publisher: Springer US
Published in: Journal of Sol-Gel Science and Technology / Issue 1/2018
Print ISSN: 0928-0707
Electronic ISSN: 1573-4846
DOI: https://doi.org/10.1007/s10971-018-4692-0

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