Skip to main content
Erschienen in: Journal of Sol-Gel Science and Technology 1/2018

01.06.2018 | Original Paper: Sol-gel and hybrid materials with surface modification for applications

Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous silica modified with phosphonic acid groups

verfasst von: Yulia S. Fetisova, Oksana A. Dudarko, Maja Bauman, Aleksandra Lobnik, Valeriia V. Sliesarenko

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 1/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The mesoporous silica samples with different concentrations of phosphonic acid groups on the surface were obtained by direct template synthesis. The block-copolymer Pluronic P123 was used as a template, and sodium meta-silicate with diethylphosphatoethyltriethoxysilane as precursors. According to the SAXS diffractograms, mesoporous silica samples have a p6mm hexagonal symmetry. In addition, we used sol–gel method to synthesize xerogel with the same groups for comparison. All samples possess high values of specific surface area 615–730 m2/g and sorption pore volume. FTIR and potentiometric titration methods were used to investigate the surface layer of these samples. Sorption properties of the samples with phosphonic acid groups were studied in respect to a row of metal cations, among which we focused on lead(II), cadmium(II), and dysprosium(III) cations.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Jaganathan H, Godina B (2012) Biocompatibility assessment of Si-based nano- and micro-particles. Adv Drug Deliv Rev 64(15):1800–1819CrossRef Jaganathan H, Godina B (2012) Biocompatibility assessment of Si-based nano- and micro-particles. Adv Drug Deliv Rev 64(15):1800–1819CrossRef
2.
Zurück zum Zitat Bharti C, Nagaich U, Kumar Pal A, Gulati N (2015) Mesoporous silica nanoparticles in target drug delivery system: a review. Int J Pharm Investig 5(3):124–133CrossRef Bharti C, Nagaich U, Kumar Pal A, Gulati N (2015) Mesoporous silica nanoparticles in target drug delivery system: a review. Int J Pharm Investig 5(3):124–133CrossRef
3.
Zurück zum Zitat Buckley AM, Greenblatt M (1994) The sol-gel preparation of silica gels. J Chem Educ 71(7):599CrossRef Buckley AM, Greenblatt M (1994) The sol-gel preparation of silica gels. J Chem Educ 71(7):599CrossRef
4.
Zurück zum Zitat Singh LP, Bhattacharyya SK, Ahalawat S, Kumar R, Mishra G, Sharma U, Singh G (2014) Sol-Gel processing of silica nanoparticles and their applications. Adv Colloid Interface Sci 214:17–37CrossRef Singh LP, Bhattacharyya SK, Ahalawat S, Kumar R, Mishra G, Sharma U, Singh G (2014) Sol-Gel processing of silica nanoparticles and their applications. Adv Colloid Interface Sci 214:17–37CrossRef
5.
Zurück zum Zitat Hoffmann F, Cornelius M, Morell J, Froba M (2006) Silica-based mesoporous organic-inorganic hybrid materials. Angew Chem Int Ed. 45:3216–3251CrossRef Hoffmann F, Cornelius M, Morell J, Froba M (2006) Silica-based mesoporous organic-inorganic hybrid materials. Angew Chem Int Ed. 45:3216–3251CrossRef
6.
Zurück zum Zitat Colilla M, Vallet-Regi M (2011) Ordered mesoporous silica materials. Elsevier: Comprehensive Biomaterails. 1st edn.: 497–514CrossRef Colilla M, Vallet-Regi M (2011) Ordered mesoporous silica materials. Elsevier: Comprehensive Biomaterails. 1st edn.: 497–514CrossRef
7.
Zurück zum Zitat Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science 279:548–552CrossRef Zhao D, Feng J, Huo Q, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD (1998) Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science 279:548–552CrossRef
8.
Zurück zum Zitat Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036CrossRef Zhao D, Huo Q, Feng J, Chmelka BF, Stucky GD (1998) Nonionic triblock and star diblock copolymer and oligomeric surfactant syntheses of highly ordered, hydrothermally stable, mesoporous silica structures. J Am Chem Soc 120:6024–6036CrossRef
10.
Zurück zum Zitat Aliev Ab, Li Ou D, Ormsby B, Sullivan AC (2000) Porous silica and polysilsesquioxane with covalently linked phosphonates and phosphonic acids. J Mater Chem 10:2758–2764CrossRef Aliev Ab, Li Ou D, Ormsby B, Sullivan AC (2000) Porous silica and polysilsesquioxane with covalently linked phosphonates and phosphonic acids. J Mater Chem 10:2758–2764CrossRef
11.
Zurück zum Zitat Dudarko O, Mel’nyk I, Zub Y, Chuiko AA, Dabrowski A (2006) Template-directed synthesis of mesoporous silicas containing phosphonic acid derivatives in the surface layer Inorg Mater 42(4):360–367CrossRef Dudarko O, Mel’nyk I, Zub Y, Chuiko AA, Dabrowski A (2006) Template-directed synthesis of mesoporous silicas containing phosphonic acid derivatives in the surface layer Inorg Mater 42(4):360–367CrossRef
12.
Zurück zum Zitat Dudarko O, Gunathilake C, Sliesarenko V, Zub YL, Jaroniec M (2014) Microwave-assisted and conventional hydrothermal synthesis of ordered mesoporous silicas with P-containing functionalities. Colloids Surf A: Physicochem Eng Asp 459:4–10CrossRef Dudarko O, Gunathilake C, Sliesarenko V, Zub YL, Jaroniec M (2014) Microwave-assisted and conventional hydrothermal synthesis of ordered mesoporous silicas with P-containing functionalities. Colloids Surf A: Physicochem Eng Asp 459:4–10CrossRef
13.
Zurück zum Zitat Elbhiri Z, Chevalier Y, Chovelon JM, Jaffrezic-Renault N (2000) Grafting of phosphonate groups on the silica surface for the elaboration of ion-sensitive field-effect transistors. Talanta 52:495–507CrossRef Elbhiri Z, Chevalier Y, Chovelon JM, Jaffrezic-Renault N (2000) Grafting of phosphonate groups on the silica surface for the elaboration of ion-sensitive field-effect transistors. Talanta 52:495–507CrossRef
14.
Zurück zum Zitat Lebed PJ, de Souza K, Bilodeau F, Lariviere D, Kleitz F (2011) Phosphonate-functionalized large pore 3-D cubic mesoporous (KIT-6) hybrid as highly efficient actinide extracting agent. Chem Commun 47:11525–11527CrossRef Lebed PJ, de Souza K, Bilodeau F, Lariviere D, Kleitz F (2011) Phosphonate-functionalized large pore 3-D cubic mesoporous (KIT-6) hybrid as highly efficient actinide extracting agent. Chem Commun 47:11525–11527CrossRef
15.
Zurück zum Zitat Lebed PJ, Savoie JD, Florek J, Bilodeau F, Larivière D, Kleitz F (2012) Large pore mesostructured organosilica-phosphonate hybrids as highly efficient and regenerable sorbents for uranium sequestration. Chem Mater 24:4166–4176CrossRef Lebed PJ, Savoie JD, Florek J, Bilodeau F, Larivière D, Kleitz F (2012) Large pore mesostructured organosilica-phosphonate hybrids as highly efficient and regenerable sorbents for uranium sequestration. Chem Mater 24:4166–4176CrossRef
16.
Zurück zum Zitat Le Y, Yang X, Dai WL, Gao R, Fan K (2008) Unexpected mononuclear W(VI) complexes containing phosphonate ligands anchored on mesoporous silica. Catal Commun 9:1838–1841CrossRef Le Y, Yang X, Dai WL, Gao R, Fan K (2008) Unexpected mononuclear W(VI) complexes containing phosphonate ligands anchored on mesoporous silica. Catal Commun 9:1838–1841CrossRef
17.
Zurück zum Zitat Saldadze KM (1960) Ion-exchange high-molecular compounds. Goskhimizdat, Moscow (in Russian) Saldadze KM (1960) Ion-exchange high-molecular compounds. Goskhimizdat, Moscow (in Russian)
18.
Zurück zum Zitat Saldadze K M (1980) Complexing ionites (complexites). Chemistry, Moscow (in Russian) Saldadze K M (1980) Complexing ionites (complexites). Chemistry, Moscow (in Russian)
19.
Zurück zum Zitat Kholin YV, Zaitsev VN, Zaitseva GN, Mernyi SA (1995) Complexation in adsorption layers of silica with grafted groups of aminophosphonic and aminodiphosphonic acids J Inorg Chem 40(2):275–283in Russian Kholin YV, Zaitsev VN, Zaitseva GN, Mernyi SA (1995) Complexation in adsorption layers of silica with grafted groups of aminophosphonic and aminodiphosphonic acids J Inorg Chem 40(2):275–283in Russian
20.
Zurück zum Zitat Ryabchikov DI, Ryabukhin VA (1966) Analytical chemistry of rare-earth elements and yttrium. Nauka, Moscow, (in Russian) Ryabchikov DI, Ryabukhin VA (1966) Analytical chemistry of rare-earth elements and yttrium. Nauka, Moscow, (in Russian)
21.
Zurück zum Zitat Zaitsev VM, Savransky LI (2005) Functional characteristics of porous materials for analitic chemistry. VPN KNU T. Shevchenko, Kyiv, (in Ukr.) Zaitsev VM, Savransky LI (2005) Functional characteristics of porous materials for analitic chemistry. VPN KNU T. Shevchenko, Kyiv, (in Ukr.)
22.
Zurück zum Zitat Milyutin VV, Gelis VM, Nekrasova NA, Melnyk IV, Dudarko OA, Sliesarenko VV, Zub YL (2014) Sorption of actinide ions onto mesoporous phosphorus-containing silicas. Radiochemistry 56(3):262–266CrossRef Milyutin VV, Gelis VM, Nekrasova NA, Melnyk IV, Dudarko OA, Sliesarenko VV, Zub YL (2014) Sorption of actinide ions onto mesoporous phosphorus-containing silicas. Radiochemistry 56(3):262–266CrossRef
23.
Zurück zum Zitat Cheraghali R, Tavakoli H, Sepehrian H (2013) Preparation, characterization and lead sorption performance of alginate-SBA-15 composite as a novel adsorbent. Sci Iran 20(3):1028–1034 Cheraghali R, Tavakoli H, Sepehrian H (2013) Preparation, characterization and lead sorption performance of alginate-SBA-15 composite as a novel adsorbent. Sci Iran 20(3):1028–1034
24.
Zurück zum Zitat Dudarko OA, Goncharik VP, Semenii VY, Zub YL (2008) Sorption of Hg2+, Nd3+, Dy3+, and UO2 2+ Ions at polysiloxane xerogels functionalized with phosphonic acid derivatives. Prot Met 44(2):193–197CrossRef Dudarko OA, Goncharik VP, Semenii VY, Zub YL (2008) Sorption of Hg2+, Nd3+, Dy3+, and UO2 2+ Ions at polysiloxane xerogels functionalized with phosphonic acid derivatives. Prot Met 44(2):193–197CrossRef
25.
Zurück zum Zitat Melnyk I, Goncharyk V, Stolyarchuk N, Kozhara LI, Lunochkina AS, Alonso B, Zub YL (2012) Dy(III) sorption from water solutions by mesoporous silicas functionalized with phosphonic acid groups. J Porous Mater 19:579–585CrossRef Melnyk I, Goncharyk V, Stolyarchuk N, Kozhara LI, Lunochkina AS, Alonso B, Zub YL (2012) Dy(III) sorption from water solutions by mesoporous silicas functionalized with phosphonic acid groups. J Porous Mater 19:579–585CrossRef
26.
Zurück zum Zitat Melnyk I, Goncharyk V, Kozhara L, Yurchenko GR, Matkovsky AK, Zub YL, Alonso B (2012) Sorption properties of porous spray-dried microspheres functionalized by phosphonic acid groups. Microporous Mesoporous Mater 153:171–177CrossRef Melnyk I, Goncharyk V, Kozhara L, Yurchenko GR, Matkovsky AK, Zub YL, Alonso B (2012) Sorption properties of porous spray-dried microspheres functionalized by phosphonic acid groups. Microporous Mesoporous Mater 153:171–177CrossRef
27.
Zurück zum Zitat Budnyak T, Strizhak A, Gładysz-Płaska A, Sternik D, Komarov IV, Kołodynska D, Majdan M, Tertykh VA (2016) Silica with immobilized phosphonic acid-derivative for uranium extraction. J Hazard Mater 314:326–340CrossRef Budnyak T, Strizhak A, Gładysz-Płaska A, Sternik D, Komarov IV, Kołodynska D, Majdan M, Tertykh VA (2016) Silica with immobilized phosphonic acid-derivative for uranium extraction. J Hazard Mater 314:326–340CrossRef
28.
Zurück zum Zitat Dudarko OA, Gunathilake C, Wickramaratne NP, Sliesarenko VV, Zub YL, Gorka J, Dai S, Jaroniec M (2015) Synthesis of mesoporous silica-tethered phosphonic acid sorbents for uranium species from aqueous solutions. Colloids Surf A: Physicochem Eng Asp 482:4–10CrossRef Dudarko OA, Gunathilake C, Wickramaratne NP, Sliesarenko VV, Zub YL, Gorka J, Dai S, Jaroniec M (2015) Synthesis of mesoporous silica-tethered phosphonic acid sorbents for uranium species from aqueous solutions. Colloids Surf A: Physicochem Eng Asp 482:4–10CrossRef
29.
Zurück zum Zitat Pearson RG, Songstad J (1967) Application of the principle of hard and soft acids and bases to organic chemistry. J Am Chem Soc 89(8):1827–1836CrossRef Pearson RG, Songstad J (1967) Application of the principle of hard and soft acids and bases to organic chemistry. J Am Chem Soc 89(8):1827–1836CrossRef
30.
Zurück zum Zitat Pu H, Pan H, Qin Y, Wan D, Yuan J (2010) Phosphonic acid-functionalized hollow silica spheres by nitroxide mediated polymerization. Mater Lett 64:1510–1512CrossRef Pu H, Pan H, Qin Y, Wan D, Yuan J (2010) Phosphonic acid-functionalized hollow silica spheres by nitroxide mediated polymerization. Mater Lett 64:1510–1512CrossRef
31.
Zurück zum Zitat Martinez-Carmona M, Colilla M, Ruiz-Gonzalez ML, Gonzalez-Calbet JM, Vallet-Regi M (2016) High resolution transmission electron microscopy: A key tool to understand drug release from mesoporous matrices. Microporous Mesoporous Mater 225:399–410CrossRef Martinez-Carmona M, Colilla M, Ruiz-Gonzalez ML, Gonzalez-Calbet JM, Vallet-Regi M (2016) High resolution transmission electron microscopy: A key tool to understand drug release from mesoporous matrices. Microporous Mesoporous Mater 225:399–410CrossRef
32.
Zurück zum Zitat Dudarko OA, Mel’nik IV, Zub YL (2005) Synthesis of polysiloxane xerogels using tetraethoxysilane/(diethylphosphatoethyl)triethoxysilane system. Colloid J 67(6):683–687CrossRef Dudarko OA, Mel’nik IV, Zub YL (2005) Synthesis of polysiloxane xerogels using tetraethoxysilane/(diethylphosphatoethyl)triethoxysilane system. Colloid J 67(6):683–687CrossRef
33.
Zurück zum Zitat Dabrowski A, Barczak M, Dudarko OA, Zub YL (2007) Preparation and characterization of polysiloxane xerogels having covalently attached phosphonic groups. Pol J Chem 81(4):475–483 Dabrowski A, Barczak M, Dudarko OA, Zub YL (2007) Preparation and characterization of polysiloxane xerogels having covalently attached phosphonic groups. Pol J Chem 81(4):475–483
34.
Zurück zum Zitat Melnyk IV, Fatnassi M, Cacciaguerra T, Zub YL, Alonso B (2012) Spray-dried porous silica microspheres functionalised by phosphonic acid groups. Microporous Mesoporous Mater 152:172–177CrossRef Melnyk IV, Fatnassi M, Cacciaguerra T, Zub YL, Alonso B (2012) Spray-dried porous silica microspheres functionalised by phosphonic acid groups. Microporous Mesoporous Mater 152:172–177CrossRef
35.
Zurück zum Zitat Sing KSW, Everett DH, Haul RAW (1985) Reporting physisorption data for gas/solid system with special reference to the determination of surface area and porosity. Pure Appl Chem 57(4):603–619CrossRef Sing KSW, Everett DH, Haul RAW (1985) Reporting physisorption data for gas/solid system with special reference to the determination of surface area and porosity. Pure Appl Chem 57(4):603–619CrossRef
36.
Zurück zum Zitat Brunauer S, Emmet PH, Teller E (1938) Adsorption of Gases in Multimolecular Layers. J Am Chem Soc 60:309–319CrossRef Brunauer S, Emmet PH, Teller E (1938) Adsorption of Gases in Multimolecular Layers. J Am Chem Soc 60:309–319CrossRef
37.
Zurück zum Zitat Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73:373–380CrossRef Barrett EP, Joyner LG, Halenda PP (1951) The determination of pore volume and area distributions in porous substances. I. Computations from nitrogen isotherms. J Am Chem Soc 73:373–380CrossRef
38.
Zurück zum Zitat Albert A, Serjeant EP (1962) Ionization constants of acids & bases. John Wiley & Sons, New York Albert A, Serjeant EP (1962) Ionization constants of acids & bases. John Wiley & Sons, New York
39.
Zurück zum Zitat Schwarzenbach G, Flaschka G (1970) Complexation titration. Chemistry, Moscow (in Russian) Schwarzenbach G, Flaschka G (1970) Complexation titration. Chemistry, Moscow (in Russian)
40.
Zurück zum Zitat Schneider P, Hudec P, Solcova O (2008) Pore-volume and surface area in microporous–mesoporous solids. Microporous Mesoporous Mater 115:491–496CrossRef Schneider P, Hudec P, Solcova O (2008) Pore-volume and surface area in microporous–mesoporous solids. Microporous Mesoporous Mater 115:491–496CrossRef
41.
Zurück zum Zitat Lin-Vien D, Colthup NB, Fateley WG, Grasselli JG (1991) The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules. Academic Pess, UK Lin-Vien D, Colthup NB, Fateley WG, Grasselli JG (1991) The Handbook of Infrared and Raman Characteristic Frequencies of Organic Molecules. Academic Pess, UK
43.
Zurück zum Zitat Draper NR, Smith H (1998) Applied Regression Analysis. Wiley-Interscience, New York Draper NR, Smith H (1998) Applied Regression Analysis. Wiley-Interscience, New York
Metadaten
Titel
Adsorption of lead(II), cadmium(II) and dysprosium(III) from aqueous solutions using mesoporous silica modified with phosphonic acid groups
verfasst von
Yulia S. Fetisova
Oksana A. Dudarko
Maja Bauman
Aleksandra Lobnik
Valeriia V. Sliesarenko
Publikationsdatum
01.06.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 1/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4692-0

Weitere Artikel der Ausgabe 1/2018

Journal of Sol-Gel Science and Technology 1/2018 Zur Ausgabe

Original Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Sol–gel preparation of hierarchically porous magnesium aluminate (MgAl2O4) spinel monoliths for dye adsorption

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Facile synthesis of core-shell ZnO/Cu2O heterojunction with enhanced visible light-driven photocatalytic performance

Original Paper: Sol-gel and hybrid materials for energy, environment and building applications

Optimized mercapto-modified resorcinol formaldehyde xerogel for adsorption of lead and copper ions from aqueous solutions

Review Paper: Sol–gel and hybrid materials for catalytic, photoelectrochemical, and sensor applications

One-pot synthesis of Nb-modified Al2O3 support for NiMo hydrodesulfurization catalysts

Original Paper: Sol-gel and hybrid materials for catalytic, photoelectrochemical and sensor applications

Role of cetyltrimethyl ammonium bromide on sol–gel preparation of porous cerium titanate photocatalyst

Original Paper: Characterization methods of sol-gel and hybrid materials

Synthesis, characterization, and application of sol gel derived Mg2SiO4 powder

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.