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17-11-2018 | Original Contribution

Adsorption of poly(styrenesulfonate) onto different-sized alumina particles: characteristics and mechanisms

Authors: Tien Duc Pham, Thi Uyen Do, Thu Thao Pham, Thi Anh Huong Nguyen, Thi Kim Thuong Nguyen, Ngoc Duy Vu, Thanh Son Le, Cuong Manh Vu, Motoyoshi Kobayashi

Published in: Colloid and Polymer Science | Issue 1/2019

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Abstract

We report the adsorption characteristics and mechanisms of a strong polyanion, poly(styrenesulfonate), PSS, onto α-Al₂O₃ with large size (L-Al₂O₃) and small size (S-Al₂O₃) in this paper. Some effective conditions to the adsorption of PSS onto L-Al₂O₃ and S-Al₂O₃ such as adsorption time, pH, mass ratio of PSS to α-Al₂O₃, and ionic strength were systematically studied. Maximum adsorption capacities of PSS onto both L-Al₂O₃ and S-Al₂O₃ were achieved with adsorption time 120 min, mass ratio of PSS to α-Al₂O₃ 20 mg/g, and ionic strength 50 mM NaCl. The PSS adsorption onto S-Al₂O₃ significantly decreased with increasing pH from 4 to 9 while PSS adsorption onto L-Al₂O₃ decreased insignificantly in the pH range 4–9. Adsorption of PSS onto both L-Al₂O₃ and S-Al₂O₃ increased with increasing salt from 0 to 50 mM NaCl, indicating that electrostatic and none-lectrostatic interactions controlled adsorption at low ionic strength. However, adsorption of PSS was independent on the ionic strength at salt concentration higher than 50 mM. The changes in surface charge after PSS adsorption onto L-Al₂O₃ and S-Al₂O₃ were determined by zeta potential while the differences of surface functional groups before and after PSS adsorption were characterized by Fourier-transform infrared spectroscopy (FT-IR). The zeta potential as a function of the mass ratio of PSS to L-Al₂O₃ and S-Al₂O₃ agreed well with the adsorption capacity against the mass ratio. Adsorption mechanisms of PSS onto L-Al₂O₃ and S-Al₂O₃ were also discussed based on the changes in zeta potential, the differences of surface functional groups, and adsorbed amount as a function of the mass ratio of PSS to α-Al₂O₃.

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Title: Adsorption of poly(styrenesulfonate) onto different-sized alumina particles: characteristics and mechanisms
Authors: Tien Duc Pham
Thi Uyen Do
Thu Thao Pham
Thi Anh Huong Nguyen
Thi Kim Thuong Nguyen
Ngoc Duy Vu
Thanh Son Le
Cuong Manh Vu
Motoyoshi Kobayashi
Publication date: 17-11-2018
Publisher: Springer Berlin Heidelberg
Published in: Colloid and Polymer Science / Issue 1/2019
Print ISSN: 0303-402X
Electronic ISSN: 1435-1536
DOI: https://doi.org/10.1007/s00396-018-4433-5

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