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Colloid and Polymer Science
Erschienen in: Colloid and Polymer Science 7/2015

01.07.2015 | Original Contribution

Adsorption characteristics of anionic azo dye onto large α-alumina beads

verfasst von: Tien Duc Pham, Motoyoshi Kobayashi, Yasuhisa Adachi

Erschienen in: Colloid and Polymer Science | Ausgabe 7/2015

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Abstract

Adsorption of anionic azo dye, new coccine (NC), onto large α-alumina beads in aqueous media was systematically investigated as functions of pH and NaCl concentration. Adsorption amounts of NC decrease with increasing pH of solutions due to less positive charges of α-Al2O3 surface at high pH. At a fixed pH, the NC adsorption increases with decreasing NaCl concentration, indicating that NC molecules mainly adsorb onto α-Al2O3 by electrostatic attraction. Experimental results of NC adsorption isotherms onto α-Al2O3 at different pH, and ionic strength can be represented well by two-step adsorption model. The effects of NC on surface charge and surface modification of α-Al2O3 at the plateau adsorption are evaluated by streaming potential and Fourier transform infrared spectroscopy with attenuated total reflection technique (FTIR-ATR), respectively. On the basis of adsorption isotherms, surface charge effect, and surface modification, we suggested that the formation of a bridged bidentate complex between aluminum ions of α-Al2O3 and two oxygen atoms of a sulfonic group induced the adsorption of NC onto α-Al2O3.
Vorheriger Artikel Two-cationic 2-methylbenzothiazole derivatives as green light absorbed sensitizers in initiation of free radical polymerization
Nächster Artikel Antioxidant micelles for bortezomib delivery

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Metadaten
Titel
Adsorption characteristics of anionic azo dye onto large α-alumina beads
verfasst von
Tien Duc Pham
Motoyoshi Kobayashi
Yasuhisa Adachi
Publikationsdatum
01.07.2015
Verlag
Springer Berlin Heidelberg
Erschienen in
Colloid and Polymer Science / Ausgabe 7/2015
Print ISSN: 0303-402X
Elektronische ISSN: 1435-1536
DOI
https://doi.org/10.1007/s00396-015-3576-x

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