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Journal of Coatings Technology and Research

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08-07-2020

Antiwetting and low-surface-energy behavior of cardanol-based polybenzoxazine-coated cotton fabrics for oil–water separation

Authors: P. Prabunathan, P. Elumalai, G. Dinesh Kumar, M. Manoj, A. Hariharan, G. Rathika, M. Alagar

Published in: Journal of Coatings Technology and Research | Issue 6/2020

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Abstract

In the present work, the surface behavior of cotton fabrics coated with a series of bio-based polybenzoxazines is explored. Herein, we report the design and synthesis of bio-based benzoxazine monomers (C-x) using cardanol (C) and seven different amines (x = ba, ha, dda, oda, ddm, jef, and fa). The molecular structures of the benzoxazine monomers have been confirmed using FTIR and NMR analyses. The microstructure of the polybenzoxazine-coated cotton fabrics observed from FE-SEM reveals that formation of rough nanostructure is influenced by molecular structure of monomers. Further, surface analysis shows that poly(C-dda)-coated cotton fabric offers superior water contact angle (WCA = 155° ± 3) with low sliding angle (6°). Also, poly(C-dda)-coated cotton fabric delivers the lowest surface energy (14.1 mN/m) and high resistance against acidic and alkaline media. Subsequently, oil–water separation investigation shows that the poly(C-dda)-coated cotton fabric yields 99% of separation efficiency with flux value of 7200 L/m²h. Thus, the cardanol-based polybenzoxazine-coated cotton fabrics prepared in the present work can find application in the field of oil–water separation due to their superior water-repellent nature.

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Title: Antiwetting and low-surface-energy behavior of cardanol-based polybenzoxazine-coated cotton fabrics for oil–water separation
Authors: P. Prabunathan
P. Elumalai
G. Dinesh Kumar
M. Manoj
A. Hariharan
G. Rathika
M. Alagar
Publication date: 08-07-2020
Publisher: Springer US
Published in: Journal of Coatings Technology and Research / Issue 6/2020
Print ISSN: 1547-0091
Electronic ISSN: 1935-3804
DOI: https://doi.org/10.1007/s11998-020-00365-w

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