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Published in: Metallurgical and Materials Transactions B 6/2010

01-12-2010

Application of the Law of Additive Reaction Times to Fluid–Solid Reactions in Porous Pellets with Changing Effective Diffusivity

Authors: Hong Yong Sohn, Silvia E. Perez-Fontes

Published in: Metallurgical and Materials Transactions B | Issue 6/2010

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Abstract

An approximate closed-form solution, which is based on the Law of Additive Reaction Times for a fluid–solid reaction formulated previously, is presented for the reaction of a fluid with a porous solid in which there is a change of porosity and, thus, effective diffusivity during the reaction. The proposed solution was compared with exact solutions reported in the literature in terms of the effects of various parameters on the fractional conversion. The closed-form expression was found to give satisfactory results and, thus, makes it unnecessary to use a numerical solution. This study represents another of many examples in which Sohn’s Law has provided useful closed-form solutions.

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Literature
1.
go back to reference J. Szekely, J. W. Evans, and H. Y. Sohn, Gas-Solid Reactions, Academic Press, New York, NY, 1976. J. Szekely, J. W. Evans, and H. Y. Sohn, Gas-Solid Reactions, Academic Press, New York, NY, 1976.
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Metadata
Title
Application of the Law of Additive Reaction Times to Fluid–Solid Reactions in Porous Pellets with Changing Effective Diffusivity
Authors
Hong Yong Sohn
Silvia E. Perez-Fontes
Publication date
01-12-2010
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 6/2010
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-010-9414-0

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