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Published in: Metallurgical and Materials Transactions A 11/2018

03-09-2018

Carbon Clustering in Low-Temperature Bainite

Authors: Rosalia Rementeria, Carlos Capdevila, Ricardo Domínguez-Reyes, Jonathan D. Poplawsky, Wei Guo, Esteban Urones-Garrote, Carlos Garcia-Mateo, Francisca G. Caballero

Published in: Metallurgical and Materials Transactions A | Issue 11/2018

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Abstract

The bainitic ferrite phase formed at temperatures below 573 K (300 °C) in high-carbon high-silicon steels holds an amount of carbon well above that expected from the thermodynamic paraequilibrium with austenite. Diffraction experiments have shown that the ferrite lattice is sufficiently Zener-ordered to possess a tetragonal symmetry, which allows the structures to be supersaturated in carbon. It could be expected that carbon undergoes ordering beyond that indicated by the Zener-ordering temperature as in the early stages of tempering of Fe-based martensites. This study examines the formation of cluster arrangements of carbon within bainitic ferrite and their relationship to the tetragonal distortion.

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Appendix
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Footnotes
1
Bainite transformation at temperatures below 553 K (280 °C) does not reach a true stasis even after prolonged heat treatment. The criterion used here to determine the end of the transformation is based on the maximum transformation rate measured, by defining the end of the transformation as the first moment at which the transformation rate is less than 1 pct of the maximum rate.[28]
 
2
The theory of spinodal decomposition requires the parent and product phases to be a continuous phase with the same crystallographic property. However, when carbon is inserted in a carbon-depleted bcc lattice, the alignment of carbon atoms distorts the lattice in a specific direction adopting a bct symmetry. Given the discontinuity in the crystal symmetry between carbon-rich (bct) and carbon-poor (bcc) regions in the Fe-C system, the process of separation would be considered to be a pseudospinodal decomposition.[55,69]
 
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Metadata
Title
Carbon Clustering in Low-Temperature Bainite
Authors
Rosalia Rementeria
Carlos Capdevila
Ricardo Domínguez-Reyes
Jonathan D. Poplawsky
Wei Guo
Esteban Urones-Garrote
Carlos Garcia-Mateo
Francisca G. Caballero
Publication date
03-09-2018
Publisher
Springer US
Published in
Metallurgical and Materials Transactions A / Issue 11/2018
Print ISSN: 1073-5623
Electronic ISSN: 1543-1940
DOI
https://doi.org/10.1007/s11661-018-4899-2

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