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20-10-2022 | Original Research

Cellulose nanofiber membrane modified with functionalized MIL-101 for enhanced hydrogen separation

Authors: Yichen Zhou, Zhirong Hu, Mengjiao Yu, Lu Zhang, Jianfeng Yao

Published in: Cellulose | Issue 1/2023

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Abstract

Mixed matrix membranes (MMMs) are expected to be strong competitors in gas separation membranes. Nevertheless, the poor interaction between fillers and matrix is a major restriction to prepare MMMs with a higher separation performance. In this work, MIL-101(Cr) was functionalized with −NH₂, −COOH, and benzenesulfonic acid (−PhSO₃H) group and these functionalized MIL-101 particles were embedded in cellulose nanofibers (CNFs) to form MMMs. The interaction effect of functionalized MIL-101 with CNFs on the separation performance was discussed. After the adjustment of MIL-101-NH₂ loading, the resulting MIL-101-NH₂/CNF membrane with 5 wt% loading exhibited enhanced H₂ permeance of ~ 2.56 × 10^− 7 mol m⁻² s^− 1 Pa^− 1 with H₂/CO₂ ideal selectivity of ~ 21.9.

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Title: Cellulose nanofiber membrane modified with functionalized MIL-101 for enhanced hydrogen separation
Authors: Yichen Zhou
Zhirong Hu
Mengjiao Yu
Lu Zhang
Jianfeng Yao
Publication date: 20-10-2022
Publisher: Springer Netherlands
Published in: Cellulose / Issue 1/2023
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-022-04877-z

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