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09-05-2018 | Original Paper

Cellulose paper grafted with polyamines as powerful adsorbent for heavy metals

Authors: Medy C. Nongbe, Guillaume Bretel, Tchirioua Ekou, Lynda Ekou, Benjamin K. Yao, Erwan Le Grognec, François-Xavier Felpin

Published in: Cellulose | Issue 7/2018

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Abstract

The preparation of new adsorbents for heavy metals consisting of cellulose paper grafted with polyamine moieties is described. The tosylation of pristine cellulose paper allowed the subsequent displacement of the tosylated leaving groups with either ethylenediamine or spermine provided the corresponding cellulose-based polyaminated adsorbents Cell-Ed and Cell-Sperm, respectively. Optimizations related to the influence of experimental conditions (time and pH) on the adsorption processes associated to detailed studies devoted to the understanding of the mechanism of adsorption through kinetic experiments and isotherm modeling provided a rational understanding for the removal Cu(II) and Pb(II). Interestingly, Cell-Sperm also displayed outstanding adsorption properties for other metal cations such as Cd(II), Zn(II) and Fe(II).

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Title: Cellulose paper grafted with polyamines as powerful adsorbent for heavy metals
Authors: Medy C. Nongbe
Guillaume Bretel
Tchirioua Ekou
Lynda Ekou
Benjamin K. Yao
Erwan Le Grognec
François-Xavier Felpin
Publication date: 09-05-2018
Publisher: Springer Netherlands
Published in: Cellulose / Issue 7/2018
Print ISSN: 0969-0239
Electronic ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1833-0

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