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Adsorption

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01-02-2015

Chromium-based metal–organic framework/mesoporous carbon composite: synthesis, characterization and CO₂ adsorption

Authors: Zhongzheng Zhang, Hui Wang, Xinqing Chen, Chenming Zhu, Wei Wei, Yuhan Sun

Published in: Adsorption | Issue 1-2/2015

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Abstract

New composites of a water-stable chromium-based metal organic framework MIL-101 and mesoporous carbon CMK-3 were in situ synthesized with different ratios of MIL-101 and CMK-3 using the hydrothermal method. The composites as well as the parent materials were characterized by X-ray diffraction, thermo gravimetric analysis, scanning electron microscope, transmission electron microscope and nitrogen/carbon dioxide adsorption isotherms. The hybrid material possesses the same crystal structure and morphology as its parent MIL-101, and exhibits an enhancement in CO₂ adsorption uptakes when compared to MIL-101 and CMK-3. The increase in CO₂ uptakes was attributed to the combined effect of the formation of additional micropores, the enhancement of micropore volume and the activation of unsaturated metal sites by CMK-3 incorporation.

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Arstad, B., Fjellvag, H., Kongshaug, K.O., Swang, O., Blom, R.: Amine functionalized metal organic frameworks (MOFs) as adsorbents for carbon dioxide. Adsorption 14, 755–762 (2008)CrossRef

Buso, D., Nairn, K.M., Gimona, M., Hill, A.J., Falcaro, P.: Fast synthesis of MOF-5 microcrystals using sol-gel SiO₂ nanoparticles. Chem. Mater. 23, 929–934 (2011)CrossRef

Chang, F., Chao, K., Cheng, H., Tan, C.: Adsorption of CO₂ onto amine-grafted mesoprous silicas. Sep. Purif. Technol. 70, 87–95 (2009)CrossRef

Férey, G., Mellot-Draznieks, C., Serre, C., Millange, F., Dutour, J., Surblé, S., Margiolaki, I.A.: A chromium terephthalate-based solid with unusually large pore volumes and surface area. Science 309, 2040–2042 (2005)CrossRef

Furukawa, H., Ko, N., Go, Y.B., Aratani, N., Choi, S.B., Choi, E., Yazaydin, A.O., Snurr, R.Q., Keeffe, M.O., Kim, J., Yaghi, O.M.: Ultra-high porosity in metal-organic frameworks. Science 329, 424–428 (2010)CrossRef

Govindasamy, C., Won, J.S., Wha, S.A.: Synthesis of mesoporous materials SBA-15 and CMK-3 from fly ash and their application for CO₂ adsorption. J. Porous Mater. 16, 545–551 (2009)CrossRef

Guo, B., Chang, L., Xiel, K.: Adsorption of carbon dioxide on activated carbon. J. Nat. Gas Chem. 15, 223–229 (2006)CrossRef

Jun, S., Joo, S.H., Ryoo, R., Kruk, M., Jaroniec, M., Liu, Z., Ohsuna, T., Terasaki, O.: Synthesis of new, nanoporous carbon with hexagonally ordered mesostructure. J. Am. Chem. Soc. 122, 10712–10713 (2000)CrossRef

Kaye, S.S., Dailly, A., Yaghi, O.M., Long, J.R.: Impact of preparation and handing on the hydrogen storage properties of Zn₄O(1,4-benzenedicarboxylate)₃ (MOF-5). J. Am. Chem. Soc. 129, 14176–14177 (2007)CrossRef

Krungleviciute, V., Lask, K., Heroux, L., Migone, D., Lee, J.Y., Skoulidas, A.: Argon adsorption on Cu₃(benzene-1,3,5-tricarboxylate)₂(H₂O)₃ metal-organic. Langmuir 23, 3106–3109 (2007)CrossRef

Kumar, R., Jayaramule, K., Maji, T.K., Rao, C.N.R.: Hybrid nanocomposites of ZIF-8 with grapheme oxide exhibiting tunable morphology, significant CO₂ uptake and other novel properties. Chem. Commun. 49, 4947–4949 (2013)CrossRef

Li, L., Wen, X., Fu, X., Wang, F., Zhao, N., Xiao, F.K., Wei, W., Sun, Y.H.: MgO/Al₂O₃ sorbent for CO₂ capture. Energy Fuels 24, 5773–5780 (2010)CrossRef

Li, Y., Sun, N.N., Li, L., Zhao, N., Xiao, F.K., Wei, W., Sun, Y.H., Huang, W.: Grafting of amines on ethanol-extracted SBA-15 for CO₂ adsorption. Materials 6, 981–999 (2013)CrossRef

Liewellyn, P.L., Bourrelly, S., Serre, C., Vimont, A., Daturi, M., Iiamon, L.: High uptakes of CO₂ and CH₄ in mesoporous metal-orfanic frameworks MIL-100 and MIL-101. Langmuir 24, 7245–7250 (2008)CrossRef

Liu, Y.Y., Zeng, J.L., Zhang, J., Xu, F., Sun, L.X.: Improved hydrogen strorage in the modified metal-organic frameworks by hydrogen spillover effect. Int. J. Hydrogen Energy 32, 4005–4010 (2007)CrossRef

Liu, J., Wang, Y., Benin, A.I., Jakubczak, P., Willis, R.R., Levan, M.D.: CO₂/H₂O adsorption equilibrium and rates on metal-organic frameworks: HKUST-1 and Ni/DOBDC. Langmuir 26, 14301–14307 (2010)CrossRef

Liu, J., Thallapally, P.K., McGrail, B.P., Brown, D.R., Liu, J.: Process in adsorption-based CO₂ capture by metal-organic frameworks. Chem. Soc. Rev. 41, 2308–2322 (2012)CrossRef

Maksimchuk, N.V., Timofeeva, M.N., Melgunov, M.S., Shmakov, A.N., Chesalov, Y.A., Dybtsev, D.N., Fedin, V.P., Kholdeeva, O.A.: Heterogeneous selective oxidation catalysts based on coordination polymer MIL-101 and transition metal-substituted polyoxometalates. J. Catal. 257, 315–323 (2008)CrossRef

Martacaltzi, C.S., Lemonidou, A.A.: Development of new CaO based sorbent materials for CO₂ removal at high temperature. Microporous Mesoporous Mater. 110, 119–127 (2008)CrossRef

Millwar, A.R., Yaghi, O.M.: Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature. J. Am. Chem. Soc. 127, 17998–17999 (2005)CrossRef

Miyamoto, M., Fujiokax, Y., Yogo, K.: Pure silica CHA type zeolite for CO₂ separation using pressure swing adsorption at high pressure. J. Mater. Chem. 22, 20186–20189 (2012)CrossRef

Pachfule, P., Balan, B.K., Kurungot, S., Banerjee, R.: One-dimensional confinement of a nanosized metal-organic framework in carbon nanofibers for improved gas adsorption. Chem. Comm. 48, 2009–2011 (2012)CrossRef

Petit, C., Bandosz, T.J.: MOF-graphite oxide nanocomposites: surface characteriazation and ecaluation as adsorbents of ammonia. J. Mater. Chem. 19, 6521–6528 (2009a)CrossRef

Petit, C., Bandosz, T.J.: MOF-graphite oxide composites: combing the uniqueness of grapheme layers and metal-organic frameworks. Adv. Mater. 21, 4753–4757 (2009b)

Petit, C., Bandosz, T.J.: Enhanced adsorption of ammonia on metal-organic framework/graphite oxide composites: analysis of surface interactions. Adv. Funct. Mater. 20, 111–118 (2010)CrossRef

Petit, C., Mendoza, B., Bandoza, T.: Reactive adsorption of ammonia on Cu-based MOF/grapheme composites. Langmuir 26, 15302–15309 (2010)CrossRef

Petit, C., Burress, J., Bandosz, T.J.: The synthesis and characterization of copper-based metal-organic framework/graphite oxide composites. Carbon 49, 563–572 (2011)CrossRef

Policicchio, A., Zhao, Y.X., Zhong, Q., Agostino, R.G., Bandosz, T.J.: Cu-BTC/aminated graphite oxide composites as high-efficiency CO₂ capture media. ACS Appl. Mater. Interfaces 6, 101–108 (2014)CrossRef

Prasanth, K.P., Rallapalli, P., Raj, M.C., Bajaj, H.C., Jasra, R.V.: Enhanced hydrogen sorption in single walled carbon nanotube incorporated MIL-101 composite metal-organic framework. Int. J. Hydrogen Energy 36, 7594–7601 (2011)CrossRef

Rallapalli, P.B.S., Raj, M.C., Patil, D.V., Prasanth, P.K., Somani, R.S., Bajaj, H.C.: Activated carbon@MIL-101(Cr): a potential metal-organic framework composite material for hydrogen strorage. Int. J. Energy Res. 37, 746–753 (2013)CrossRef

Shao, W., Zhang, L.Z., Li, L.X., Lee, R.L.: Adsorption of CO₂ and N₂ on synthesized NaY zeolite at high temperatures. Adsorption 15, 497–505 (2009)CrossRef

Suddik, A.C., Cote, A.P., Wong-Foy, A.G., O’Keeffe, M., Yaghi, O.M.: A metal-organic framework with a hierarchical system of pores and tetrahedral building blocks. Angew. Chem. Int. Ed. 45, 2528–2533 (2006)CrossRef

Sun, Y., Liu, X.W., Su, W., Zhou, Y.P., Zhou, L.: Studies on ordered mesoporous materials for potential environmnental and clean energy applications. Appl. Surf. Sci. 253, 5650–5655 (2007)CrossRef

Wong, S., Bioletti, R.: Carbon dioxide separation technologies. Carbon & Energy Management, Alberta Research Council, Edmonton, Alberta, Canada (2002)

Wu, H., Simmons, J.M., Srinivas, G., Zhou, W., Yildirim, T.: Adsorption sites and binding nature of CO2 in prototypical metal-organic frameworks: a combined neutron diffraction and first-principles study. J. Phys. Chem. Lett. 1, 1946–1951 (2010)CrossRef

Wu, C.M., Rathi, M., Ahrenkiel, S.P., Koodali, R.T., Wang, Z.Q.: Facile synthesis of MOF-5 confined in SBA-15 hybrid material with enhanced hydrostability. Chem. Comm. 49, 1223–1225 (2013)CrossRef

Yang, S.J., Choi, J.Y., Chae, H.K., Cho, J.H., Nahm, K.S., Park, C.R.: Preparation and enhanced hydrostability and hydrogen storage capacity of CNT@MOF-5 hybrid composite. Chem. Mater. 21, 1893–1897 (2009)CrossRef

Yang, H., Gong, M., Chen, Y.: Preparation of activated carbons and their adsorption properties for greenhouse gases: CH₄ and CO2. J. Nat. Gas Chem. 20, 460–464 (2011)CrossRef

Yazaydin, A.O., Snurr, R.Q., Park, T.H., Koh, K., Liu, J., Levan, M.D., Benin, A.I., Jakubazak, P., Lanuza, M., Galloway, D.B., Low, J.J., Willis, R.R.: Screening of metal-organic frameworks for carbon dioxide capture from flue gas using a combined experimental and modeling approach. J. Am. Chem. Soc. 131, 18198–18199 (2009)CrossRef

Zhang, Z.Z., Ruan, H.Z., Zhou, Y.P., Su, W., Sun, Y., Zhou, L.: A research note on the adsorption of CO₂ and N₂. Chin. J. Chem. Eng. 19, 733–737 (2011)CrossRef

Zhang, Z.Z., Tang, J.D., Sun, Y., Su, W.: Water effect on amine-modification of adsorbents for separation of CO₂/N₂. Trans. Tianjin Univ. 19, 313–318 (2013)CrossRef

Zhao, D.Y., Feng, J.L., Huo, Q.S., Melosh, N., Fredrickson, G.H., Chmelka, B.F., Stucky, G.D.: Triblock copolymer synthesis of mesoporous silica with periodic 50 to 300 Angstrom pores. Science 279, 548–552 (1998)CrossRef

Zhao, Y.X., Seredych, M., Zhong, Q., Bandosz, T.J.: Superior performance of copper based MOF and aminated graphite oxide composites as CO₂ adsorbents at room temperature. ACS Appl. Mater. Interfaces 5, 4951–4959 (2013)CrossRef

Zhao, Y.X., Seredych, M., Jagiello, J., Zhong, Q., Bandosz, T.J.: Insight into the mechanism of CO₂ adsorption on Cu-BTC and its composites with graphite oxide or aminated graphite oxide. Chem. Eng. J. 239, 399–407 (2014)CrossRef

Title: Chromium-based metal–organic framework/mesoporous carbon composite: synthesis, characterization and CO2 adsorption
Authors: Zhongzheng Zhang
Hui Wang
Xinqing Chen
Chenming Zhu
Wei Wei
Yuhan Sun
Publication date: 01-02-2015
Publisher: Springer US
Published in: Adsorption / Issue 1-2/2015
Print ISSN: 0929-5607
Electronic ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-015-9651-2

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