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2014 | OriginalPaper | Chapter

3. Column-Based Chromatographic Techniques

Authors : Harald Pasch, Muhammad Imran Malik

Published in: Advanced Separation Techniques for Polyolefins

Publisher: Springer International Publishing

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Abstract

Crystallization-based fractionation techniques are powerful methods for the chemical composition fractionation of semi-crystalline polyolefins. The non-crystallizing part cannot be fractionated and is obtained as a bulk fraction. As alternative methods, column-based separation techniques can be used. These techniques fractionate polyolefins regardless of crystallinity based on molecular size, chemical composition and/or branching. In this chapter, experimental approaches for the molar mass analysis by size exclusion chromatography and the chemical composition analysis by different means of interaction chromatography will be presented. The dual molar mass/chemical composition fractionation by two-dimensional liquid chromatography will be highlighted and examples for comprehensive analysis will be given.

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previous chapter Crystallization-Based Fractionation Techniques
next chapter Field-Flow Fractionation
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Metadata
Title
Column-Based Chromatographic Techniques
Authors
Harald Pasch
Muhammad Imran Malik
Copyright Year
2014
Book
Advanced Separation Techniques for Polyolefins

Print ISBN: 978-3-319-08631-6

Electronic ISBN: 978-3-319-08632-3

Copyright Year: 2014

DOI
https://doi.org/10.1007/978-3-319-08632-3_3

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