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Journal of Polymer Research

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01-08-2014 | Original Paper

Convenient synthesis and morphology of latex particles composed of poly (methyl methacrylate)-b-poly (n-butyl acrylate) by 1, 1-diphenylethylene (DPE) seeded emulsion polymerization

Authors: Wenwen Wang, Mengjiao Liu, Junwei Gu, Qiuyu Zhang, Jimmy W. Mays

Published in: Journal of Polymer Research | Issue 8/2014

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Abstract

Methyl methacrylate-butyl acrylate structural latexes were synthesized by two-stage seeded emulsion polymerization using 1,1-diphenylethylene (DPE) as a control reagent. In the first stage, the seed latex particles with the precursor poly (methyl methacrylate-DPE) (P(MMA-DPE)) were prepared, and then the second monomer n-butyl acrylate (nBA) was swollen into the seed latex particles under stirring at room temperature. In the second stage, the polymerization of nBA was thermally initiated at 80 °C, and the latex particles composed of block copolymer were synthesized. The size and morphology of the latex particles were investigated by light scattering and TEM. The contact angles of different latex films were also measured. The block copolymer was characterized by size exclusion chromatography, nuclear magnetic resonance spectroscopy, and differential scanning calorimetry. Microphase separation of the block copolymer was examined using atomic force microscopy.

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Title: Convenient synthesis and morphology of latex particles composed of poly (methyl methacrylate)-b-poly (n-butyl acrylate) by 1, 1-diphenylethylene (DPE) seeded emulsion polymerization
Authors: Wenwen Wang
Mengjiao Liu
Junwei Gu
Qiuyu Zhang
Jimmy W. Mays
Publication date: 01-08-2014
Publisher: Springer Netherlands
Published in: Journal of Polymer Research / Issue 8/2014
Print ISSN: 1022-9760
Electronic ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-014-0502-8

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