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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2013

01.10.2013 | Original Paper

Hybrid copolymer latex of MMA-BA-zonyl TM-PDMS by mini-emulsion polymerization

verfasst von: Nilutpal Phukon, Chandrashekara R. Haramagatti, Parimal Jha, Vaibhav Dave

Erschienen in: Journal of Polymer Research | Ausgabe 10/2013

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Abstract

Stable, coagulum free fluoro-silicone-acrylic latex (FSAL) of methyl methacrylate (MMA)-co-butyl acrylate (BA)-co-Zonyl TM-hyb-Polydimethylsiloxane (PDMS) is prepared through mini-emulsion polymerization. Apart from this, three more latexes/emulsions acrylic latex (AL) of methyl methacrylate (MMA)-co-butyl acrylate (BA), silicone-acrylic latex (SAL) of methyl methacrylate (MMA)-co-butyl acrylate (BA)-hyb- PDMS, and fluoro acrylic latex (FAL) of methyl methacrylate (MMA)-co-butyl acrylate (BA)-co-Zonyl TM are prepared for systematic understanding of the preparation and properties of the emulsions. The emulsions are prepared with almost uniform size of monomer droplets (mini-emulsions). The prepared latexes were characterized by IR, C13 NMR and 1H NMR. A systematic understanding of the effect of initial droplet size on final latex particle, the properties of the latex particles such as swelling ratio, MFFT, contact angle, distribution of particle size, rheological behavior, DSC/DMA thermograms, SEM images of the films and film topography are reported. The fluoro-silicone-acrylic latex (FSAL) exhibit, stable, low MFFT, narrow particle size distribution, and high contact angle for water, and hence it can be a great candidate as a hydrophobic binder in coating products.
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Metadaten
Titel
Hybrid copolymer latex of MMA-BA-zonyl TM-PDMS by mini-emulsion polymerization
verfasst von
Nilutpal Phukon
Chandrashekara R. Haramagatti
Parimal Jha
Vaibhav Dave
Publikationsdatum
01.10.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2013
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-013-0268-4

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