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Journal of Materials Engineering and Performance

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07-11-2017

Corrosion Protection of Phenolic-Epoxy/Tetraglycidyl Metaxylediamine Composite Coatings in a Temperature-Controlled Borax Environment

Authors: Wenhua Xu, Zhenyu Wang, En-Hou Han, Chunbo Liu

Published in: Journal of Materials Engineering and Performance | Issue 12/2017

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Abstract

The failure behavior for two kinds of phenolic-epoxy/tetraglycidyl metaxylediamine composite coatings in 60 °C borax aqueous solution was evaluated using electrochemical methods (EIS) combined with scanning electron microscopy, confocal laser scanning microscope, water immersion test, and Raman spectrum. The main focus was on the effect of curing agent on the corrosion protection of coatings. Results revealed that the coating cured by phenolic modified aromatic amine possessed more compact cross-linked structure, better wet adhesion, lower water absorption (0.064 mg h⁻¹ cm⁻²) and its impedance values was closed to 10⁸ Ω cm² after immersion for 576 h, while the coating cured by modified aromatic ring aliphatic amine was lower than 10⁵ Ω cm². The corrosion mechanism of the two coatings is discussed.

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Title: Corrosion Protection of Phenolic-Epoxy/Tetraglycidyl Metaxylediamine Composite Coatings in a Temperature-Controlled Borax Environment
Authors: Wenhua Xu
Zhenyu Wang
En-Hou Han
Chunbo Liu
Publication date: 07-11-2017
Publisher: Springer US
Published in: Journal of Materials Engineering and Performance / Issue 12/2017
Print ISSN: 1059-9495
Electronic ISSN: 1544-1024
DOI: https://doi.org/10.1007/s11665-017-2980-4

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