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Experimental Mechanics
Published in: Experimental Mechanics 4/2018

12-03-2018

Coupling Effect of State-of-Health and State-of-Charge on the Mechanical Integrity of Lithium-Ion Batteries

Authors: J. Xu, Y. Jia, B. Liu, H. Zhao, H. Yu, J. Li, S. Yin

Published in: Experimental Mechanics | Issue 4/2018

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Abstract

Two governing factors that influence the electrochemical behaviors of lithium-ion batteries (LIBs), namely, state of charge (SOC) and state of health (SOH), are constantly interchanged, thus hindering the understanding of the mechanical integrity of LIBs. This study investigates the electrochemical failure of LIBs with various SOHs and SOCs subjected to abusive mechanical loading. Comprehensive experiments on LiNi0.8CoO15Al0.05O2 (NCA) LIB show that SOH reduction leads to structural stiffness and that the change trend varies with SOC value. Low SOH, however, may mitigate this phenomenon. Electrochemical failure strain at short circuit has no relationship with SOC or SOH, whereas failure stress increases with the increase of SOC value. Experiments on three types of batteries, namely, NCA, LiCoO2 (LCO), and LiFePO4 (LFP) batteries, indicate that their mechanical behaviors share similar SOH-dependency properties. SOH also significantly influences failure stress, temperature increase, and stiffness, whereas its effect on failure strain is minimal. Results may provide valuable insights for the fundamental understanding of the electrochemically and mechanically coupled integrity of LIBs and establish a solid foundation for LIB crash-safety design in electric vehicles.
previous article State-of-Charge and Deformation-Rate Dependent Mechanical Behavior of Electrochemical Cells
next article Elastic and Dielectric Properties of Active Ag/BaTiO3 Composites

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Literature
1.
Armand M, Tarascon JM (2008) Building better batteries. Nature 451(7179):652–657CrossRef
2.
Scrosati B, Garche J (2010) Lithium batteries: status, prospects and future. J Power Sources 195(9):2419–2430CrossRef
3.
Chan CK, Peng H, Liu G, McIlwrath K, Zhang XF, Huggins RA, Cui Y (2008) High-performance lithium battery anodes using silicon nanowires. Nat Nanotechnol 3(1):31–35CrossRef
4.
Kang B, Ceder G (2009) Battery materials for ultrafast charging and discharging. Nature 458(7235):190–193CrossRef
5.
Sun Y-K, Myung S-T, Park B-C, Prakash J, Belharouak I, Amine K (2009) High-energy cathode material for long-life and safe lithium batteries. Nat Mater 8(4):320–324CrossRef
6.
Goodenough JB, Kim Y (2010) Challenges for rechargeable li batteries. Chem Mater 22(3):587–603CrossRef
7.
Cheng F, Liang J, Tao Z, Chen J (2011) Functional materials for rechargeable batteries. Adv Mater 23(15):1695–1715CrossRef
8.
Vikström H, Davidsson S, Höök M (2013) Lithium availability and future production outlooks. Appl Energy 110:252–266CrossRef
9.
Ovrum E, Bergh TF (2015) Modelling lithium-ion battery hybrid ship crane operation. Appl Energy 152:162–172CrossRef
10.
Chen J, Liu J, Qi Y, Sun T, Li X (2013) Unveiling the roles of binder in the mechanical integrity of electrodes for lithium-ion batteries. J Electrochem Soc 160(9):A1502–A1509CrossRef
11.
Ramdon S, Bhushan B (2014) Nanomechanical characterization and mechanical integrity of unaged and aged Li-ion battery cathodes. J Power Sources 246:219–224CrossRef
12.
Wang Q, Ping P, Zhao X, Chu G, Sun J, Chen C (2012) Thermal runaway caused fire and explosion of lithium ion battery. J Power Sources 208:210–224CrossRef
13.
Zhang X, Shyy W, Marie Sastry A (2007) Numerical simulation of intercalation-induced stress in Li-ion battery electrode particles. J Electrochem Soc 154(10):A910–A916CrossRef
14.
Golmon S, Maute K, Dunn ML (2009) Numerical modeling of electrochemical–mechanical interactions in lithium polymer batteries. Comput Struct 87(23–24):1567–1579CrossRef
15.
Cai L, White RE (2011) Mathematical modeling of a lithium ion battery with thermal effects in COMSOL Inc. Multiphysics (MP) software. J Power Sources 196(14):5985–5989CrossRef
16.
Greve L, Fehrenbach C (2012) Mechanical testing and macro-mechanical finite element simulation of the deformation, fracture, and short circuit initiation of cylindrical Lithium ion battery cells. J Power Sources 214:377–385CrossRef
17.
Sahraei E, Meier J, Wierzbicki T (2014) Characterizing and modeling mechanical properties and onset of short circuit for three types of lithium-ion pouch cells. J Power Sources 247:503–516CrossRef
18.
Sahraei E, Campbell J, Wierzbicki T (2012) Modeling and short circuit detection of 18650 Li-ion cells under mechanical abuse conditions. J Power Sources 220:360–372CrossRef
19.
Sahraei E, Hill R, Wierzbicki T (2012) Calibration and finite element simulation of pouch lithium-ion batteries for mechanical integrity. J Power Sources 201:307–321CrossRef
20.
Ali MY, Lai WJ, Pan J (2013) Computational models for simulations of lithium-ion battery cells under constrained compression tests. J Power Sources 242:325–340CrossRef
21.
Wierzbicki T, Sahraei E (2013) Homogenized mechanical properties for the jellyroll of cylindrical Lithium-ion cells. J Power Sources 241:467–476CrossRef
22.
Lai W-J, Ali MY, Pan J (2014) Mechanical behavior of representative volume elements of lithium-ion battery cells under compressive loading conditions. J Power Sources 245:609–623CrossRef
23.
Ali MY, Lai WJ, Pan J (2015) Computational models for simulation of a lithium-ion battery module specimen under punch indentation. J Power Sources 273:448–459CrossRef
24.
Cannarella J, Arnold CB (2014) State of health and charge measurements in lithium-ion batteries using mechanical stress. J Power Sources 269:7–14CrossRef
25.
Cannarella J, Leng CZ, Arnold CB (2014) On the coupling between stress and voltage in lithium-ion pouch cells. Proc of SPIE 9115:91150K
26.
Obrovac MN, Christensen L (2004) Structural changes in silicon anodes during lithium insertion/extraction. Electrochem Solid-State Lett 7(5):A93–A96CrossRef
27.
Zhao K, Pharr M, Cai S, Vlassak JJ, Suo Z (2011) Large plastic deformation in high-capacity lithium-ion batteries caused by charge and discharge. J Am Ceram Soc 94:s226–s235CrossRef
28.
Liu XH, Wang JW, Huang S, Fan F, Huang X, Liu Y, Krylyuk S, Yoo J, Dayeh SA, Davydov AV, Mao SX, Picraux ST, Zhang S, Li J, Zhu T, Huang JY (2012) In situ atomic-scale imaging of electrochemical lithiation in silicon. Nat Nanotechnol 7(11):749–756CrossRef
29.
Pharr M, Zhao K, Wang X, Suo Z, Vlassak JJ (2012) Kinetics of initial lithiation of crystalline silicon electrodes of lithium-ion batteries. Nano Lett 12(9):5039–5047CrossRef
30.
Huang S, Fan F, Li J, Zhang S, Zhu T (2013) Stress generation during lithiation of high-capacity electrode particles in lithium ion batteries. Acta Mater 61(12):4354–4364CrossRef
31.
Ryu I, Lee SW, Gao H, Cui Y, Nix WD (2014) Microscopic model for fracture of crystalline Si nanopillars during lithiation. J Power Sources 255:274–282CrossRef
32.
Berla LA, Lee SW, Cui Y, Nix WD (2015) Mechanical behavior of electrochemically lithiated silicon. J Power Sources 273:41–51CrossRef
33.
Sethuraman VA, Chon MJ, Shimshak M, Van Winkle N, Guduru PR (2010) In situ measurement of biaxial modulus of Si anode for Li-ion batteries. Electrochem Commun 12(11):1614–1617CrossRef
34.
Amanieu H-Y, Aramfard M, Rosato D, Batista L, Rabe U, Lupascu DC (2015) Mechanical properties of commercial Mn2O4 cathode under different states of charge. Acta Mater 89:153–162CrossRef
35.
Tao X, Du J, Sun Y, Zhou S, Xia Y, Huang H, Gan Y, Zhang W, Li X (2013) Exploring the energy storage mechanism of high performance MnO2 electrochemical capacitor electrodes: an in situ atomic force microscopy study in aqueous electrolyte. Adv Funct Mater 23(37):4745–4751
36.
Wang X, Sakiyama Y, Takahashi Y, Yamada C, Naito H, Segami G, Hironaka T, Hayashi E, Kibe K (2007) Electrode structure analysis and surface characterization for lithium-ion cells simulated low-earth-orbit satellite operation: I Electrochemical behavior and structure analysis. J Power Sources 167(1):162–170CrossRef
37.
Wang Y, Yan X, Bie X, Fu Q, Du F, Chen G, Wang C, Wei Y (2014) Effects of aging in electrolyte on the structural and electrochemical properties of the Li[Li0.18Ni0.15Co0.15Mn0.52]O2 cathode material. Electrochim Acta 116:250–257CrossRef
38.
Wang X, Hironaka T, Hayashi E, Yamada C, Naito H, Segami G, Sakiyama Y, Takahashi Y, Kibe K (2007) Electrode structure analysis and surface characterization for lithium-ion cells simulated low-earth-orbit satellite operation: II: Electrode surface characterization. J Power Sources 168(2):484–492CrossRef
39.
Liu P, Wang J, Hicks-Garner J, Sherman E, Soukiazian S, Verbrugge M, Tataria H, Musser J, Finamore P (2010) Aging mechanisms of LiFePO4 batteries deduced by electrochemical and structural analyses. J Electrochem Soc 157(4):A499–A507CrossRef
40.
Braithwaite JW, Gonzales A, Nagasubramanian G, Lucero SJ, Peebles DE, Ohlhausen JA, Cieslak WR (1999) Corrosion of lithium-ion battery current collectors. J Electrochem Soc 146(2):448–456CrossRef
41.
Xu J, Liu BH, Hu DY (2016) State of charge dependent mechanical integrity behavior of 18650 Lithium-ion batteries. Sci Rep 6:11CrossRef
42.
Xu J, Liu BH, Wang LB, Shang S (2015) Dynamic mechanical integrity of cylindrical lithium-ion battery cell upon crushing. Eng Fail Anal 53:97–110CrossRef
43.
Xu J, Liu BH, Wang XY, Hu DY (2016) Computational model of 18650 lithium-ion battery with coupled strain rate and SOC dependencies. Appl Energy 172:180–189CrossRef
44.
45.
Liu YJ, Li XH, Guo HJ, Wang ZX, Hu QY, Peng WJ, Yang Y (2009) Electrochemical performance and capacity fading reason of LiMn2O4/graphite batteries stored at room temperature. J Power Sources 189(1):721–725CrossRef
46.
Petit M, Prada E, Sauvant-Moynot V (2016) Development of an empirical aging model for Li-ion batteries and application to assess the impact of vehicle-to-grid strategies on battery lifetime. Appl Energy 172:398–407CrossRef
47.
Jeong WT, Lee KS (2002) Electrochemical cycling behavior of LiCoO2 cathode prepared by mechanical alloying of hydroxides. J Power Sources 104(2):195–200CrossRef
48.
Osaka T, Nakade S, Rajamaki M, Momma T (2003) Influence of capacity fading on commercial lithium-ion battery impedance. J Power Sources 119:929–933CrossRef
49.
Yang L, Cheng X, Gao Y, Ma Y, Zuo P, Du C, Cui Y, Guan T, Lou S, Wang F, Fei W, Yin G (2014) Lithium deposition on graphite anode during long-term cycles and the effect on capacity loss. RSC Adv 4(50):26335–26341CrossRef
50.
Dahéron L, Dedryvère R, Martinez H, Ménétrier M, Denage C, Delmas C, Gonbeau D (2008) Electron transfer mechanisms upon lithium Deintercalation from LiCoO2 to CoO2 investigated by XPS. Chem Mater 20(2):583–590CrossRef
51.
Kim JH, Woo SC, Park MS, Kim KJ, Yim T, Kim JS, Kim YJ (2013) Capacity fading mechanism of LiFePO4-based lithium secondary batteries for stationary energy storage. J Power Sources 229:190–197CrossRef
52.
Fu R, Xiao M, Choe S-Y (2013) Modeling, validation and analysis of mechanical stress generation and dimension changes of a pouch type high power Li-ion battery. J Power Sources 224:211–224CrossRef
Metadata
Title
Coupling Effect of State-of-Health and State-of-Charge on the Mechanical Integrity of Lithium-Ion Batteries
Authors
J. Xu
Y. Jia
B. Liu
H. Zhao
H. Yu
J. Li
S. Yin
Publication date
12-03-2018
Publisher
Springer US
Published in
Experimental Mechanics / Issue 4/2018
Print ISSN: 0014-4851
Electronic ISSN: 1741-2765
DOI
https://doi.org/10.1007/s11340-018-0380-9

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