Skip to main content
Top
Published in: Metallurgical and Materials Transactions B 4/2018

14-05-2018

Dephosphorization of Levitated Silicon-Iron Droplets for Production of Solar-Grade Silicon

Authors: Katherine Le, Yindong Yang, Mansoor Barati, Alexander McLean

Published in: Metallurgical and Materials Transactions B | Issue 4/2018

Log in

Activate our intelligent search to find suitable subject content or patents.

search-config
loading …

Abstract

The treatment of relatively inexpensive silicon-iron alloys is a potential refining route in order to generate solar-grade silicon. Phosphorus is one of the more difficult impurity elements to remove by conventional processing. In this study, electromagnetic levitation was used to investigate phosphorus behavior in silicon-iron alloy droplets exposed to H2-Ar gas mixtures under various experimental conditions including, refining time, temperature (1723 K to 1993 K), gas flow rate, iron content, and initial phosphorus concentration in the alloy. Thermodynamic modeling of the dephosphorization reaction permitted prediction of the various gaseous products and indicated that diatomic phosphorus is the dominant species formed.

Dont have a licence yet? Then find out more about our products and how to get one now:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literature
1.
go back to reference G. Bye, B. Ceccaroli: Sol. Energy Mater. Sol. Cells, 2014, vol. 130, pp. 634-646.CrossRef G. Bye, B. Ceccaroli: Sol. Energy Mater. Sol. Cells, 2014, vol. 130, pp. 634-646.CrossRef
4.
go back to reference M. D. Johnston, L.T. Khajavi, M. Li, S. Sokhanvaran, M. Barati: JOM, 2012, vol. 64, pp. 935-945.CrossRef M. D. Johnston, L.T. Khajavi, M. Li, S. Sokhanvaran, M. Barati: JOM, 2012, vol. 64, pp. 935-945.CrossRef
5.
go back to reference S.S. Zheng, W.H. Chen, J. Cai, J.T. Li, C. Chen, X.T. Luo: Metall. Mater. Trans. B, 2010, vol. 41, pp. 1268-1273.CrossRef S.S. Zheng, W.H. Chen, J. Cai, J.T. Li, C. Chen, X.T. Luo: Metall. Mater. Trans. B, 2010, vol. 41, pp. 1268-1273.CrossRef
6.
go back to reference T. Kemmotsu, T. Nagai, M. Maeda : High Temp. Mater. Proc., 2011, vol. 30, pp. 17-22.CrossRef T. Kemmotsu, T. Nagai, M. Maeda : High Temp. Mater. Proc., 2011, vol. 30, pp. 17-22.CrossRef
7.
go back to reference J. Safarian and M. Tangstad: High Temp. Mater. Proc., 2012, vol. 31, pp.73-81.CrossRef J. Safarian and M. Tangstad: High Temp. Mater. Proc., 2012, vol. 31, pp.73-81.CrossRef
8.
go back to reference Y. Tan, X. Guo, S. Shi, W. Dong, D. Jiang: Vacuum, 2013, vol. 93, pp. 65–70.CrossRef Y. Tan, X. Guo, S. Shi, W. Dong, D. Jiang: Vacuum, 2013, vol. 93, pp. 65–70.CrossRef
9.
go back to reference L.T. Khajavi, M. Barati: Metall. Mater. Trans. B, 2017, vol. 48, pp.268-275.CrossRef L.T. Khajavi, M. Barati: Metall. Mater. Trans. B, 2017, vol. 48, pp.268-275.CrossRef
10.
go back to reference M. Popa: Nonconv. Technol. Rev., 2010, vol. 1, pp. 34-38. M. Popa: Nonconv. Technol. Rev., 2010, vol. 1, pp. 34-38.
11.
go back to reference Z. Royer: Optimizing electromagnetic levitation design to enhance thermodynamic measurement, Ph.D. Thesis, Iowa State University, Ames, IA, 2012, pp. 5–6. Z. Royer: Optimizing electromagnetic levitation design to enhance thermodynamic measurement, Ph.D. Thesis, Iowa State University, Ames, IA, 2012, pp. 5–6.
12.
13.
go back to reference S. Ueda, K. Morita, N. Sano: Metall. Mater. Trans. B, 1997, vol. 28, pp. 1151-1155.CrossRef S. Ueda, K. Morita, N. Sano: Metall. Mater. Trans. B, 1997, vol. 28, pp. 1151-1155.CrossRef
14.
go back to reference O. Kubaschewski and C.B. Alcock, Metallurgical Thermochemistry, 5th ed., Oxford, Pergamon Press, 1979. O. Kubaschewski and C.B. Alcock, Metallurgical Thermochemistry, 5th ed., Oxford, Pergamon Press, 1979.
15.
go back to reference B.V. Patil, A.H. Chan, R.J. Choulet: The Making, Shaping and Treating of Steel: Chapter 12 Refining of Stainless Steels, 11th ed., The AISE Steel Foundation, Pittsburgh, PA, 1998, pp. 721-726. B.V. Patil, A.H. Chan, R.J. Choulet: The Making, Shaping and Treating of Steel: Chapter 12 Refining of Stainless Steels, 11th ed., The AISE Steel Foundation, Pittsburgh, PA, 1998, pp. 721-726.
16.
go back to reference Mitsutaka Hino, Kimihisa Ito: Thermodynamic Data for Steelmaking, Tohoku University Press, Sendai, 2010, p.260. Mitsutaka Hino, Kimihisa Ito: Thermodynamic Data for Steelmaking, Tohoku University Press, Sendai, 2010, p.260.
17.
go back to reference P.R. Gaines: ICP Operations Guide, Inorganic Ventures™, Christiansburg, 2011. P.R. Gaines: ICP Operations Guide, Inorganic Ventures™, Christiansburg, 2011.
18.
go back to reference M. Duffy, R. Thomas: At. Spectrosc., 1996, vol. 17, pp.128-132. M. Duffy, R. Thomas: At. Spectrosc., 1996, vol. 17, pp.128-132.
19.
go back to reference W. Yan, Y. Yang, W. Chen, M. Barati, A. McLean: Vacuum, 2017, vol. 135, pp. 101-108.CrossRef W. Yan, Y. Yang, W. Chen, M. Barati, A. McLean: Vacuum, 2017, vol. 135, pp. 101-108.CrossRef
20.
go back to reference L.T. Khajavi, M. Barati: High Temp. Mater. Proc., 2012, vol. 31, pp. 627-631.CrossRef L.T. Khajavi, M. Barati: High Temp. Mater. Proc., 2012, vol. 31, pp. 627-631.CrossRef
21.
go back to reference C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, A.E. Gheribi, K. Hack, I.H. Jung, Y.B. Kang, J. Melançon, A.D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer, M.A. Van Ende: Calphad, 2016, vol. 54, pp. 35-53.CrossRef C.W. Bale, E. Bélisle, P. Chartrand, S.A. Decterov, G. Eriksson, A.E. Gheribi, K. Hack, I.H. Jung, Y.B. Kang, J. Melançon, A.D. Pelton, S. Petersen, C. Robelin, J. Sangster, P. Spencer, M.A. Van Ende: Calphad, 2016, vol. 54, pp. 35-53.CrossRef
Metadata
Title
Dephosphorization of Levitated Silicon-Iron Droplets for Production of Solar-Grade Silicon
Authors
Katherine Le
Yindong Yang
Mansoor Barati
Alexander McLean
Publication date
14-05-2018
Publisher
Springer US
Published in
Metallurgical and Materials Transactions B / Issue 4/2018
Print ISSN: 1073-5615
Electronic ISSN: 1543-1916
DOI
https://doi.org/10.1007/s11663-018-1282-z

Other articles of this Issue 4/2018

Metallurgical and Materials Transactions B 4/2018 Go to the issue

Premium Partners