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Journal of Materials Science: Materials in Electronics
Published in: Journal of Materials Science: Materials in Electronics 3/2018

08-11-2017

Design and preparation of side chain electro-optic polymeric materials based on novel organic second order nonlinear optical chromophores with double carboxyl groups

Authors: Li Guo, Zupeng Guo, Xiaobing Li

Published in: Journal of Materials Science: Materials in Electronics | Issue 3/2018

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Abstract

Organic second nonlinear optical chromophore GL-COOHs with two carboxyl groups are designed and synthesized in this paper. The structure of chromophore GL-COOHs are characterized by mass spectrum and nuclear magnetic resonance spectroscopy. The first order hyperpolarizability is studied by theoretical calculation, which is similar to the famous FTC chromophore. Thanks to the double carboxyl group structure, novel side chain polyester electro optic polymers are prepared based on chromophore GL-COOHs. Their Tgs are around 110 °C, which is high enough for keeping the long term stability of their electro optic activities. Their Tds are above 239 °C, which is high enough for the devices preparing process. Else, the largest d33 values are about 29.3, 43.6 and 63.1 pm/V for polymer GL-S-1, GL-S-2 and GL-S-3 respectively. Interestingly, there is a linear relation between chromophore loading density and d33 values.
previous article Ferroelectric properties of highly a-oriented polycrystalline Bi4Ti3O12 thin films grown on glass substrates
next article Investigation of structural, electrical and dielctrical properties of Pr0.67Ba0.22Sr0.11Mn1−xFexO3 (0 ≤ x ≤ 0.2) perovskite

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Metadata
Title
Design and preparation of side chain electro-optic polymeric materials based on novel organic second order nonlinear optical chromophores with double carboxyl groups
Authors
Li Guo
Zupeng Guo
Xiaobing Li
Publication date
08-11-2017
Publisher
Springer US
Published in
Journal of Materials Science: Materials in Electronics / Issue 3/2018
Print ISSN: 0957-4522
Electronic ISSN: 1573-482X
DOI
https://doi.org/10.1007/s10854-017-8181-y

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