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Polymer Bulletin
Published in: Polymer Bulletin 11/2023

15-12-2022 | ORIGINAL PAPER

Design of acetylene-modified bio-based tri-functional benzoxazine and its copolymerization with bismaleimide for performance enhancement

Authors: Yunliang Xing, Yuan Zhang, Xianru He

Published in: Polymer Bulletin | Issue 11/2023

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Abstract

Developing of high-performance thermosets with outstanding thermal properties has attracted increasing attention. Herein, a combined strategy, acetylene modification and copolymerization with bismaleimide, has been utilized for a novel bio-based tri-functional benzoxazine monomer. The monomer (RES-pa) was successfully synthesized using biomass resources, resveratrol, as raw material. Three systems with different ratios (RES-pa: bismaleimide = 1:0, 1:1, 1:2) were designed. The thermal derived polymerization of three systems was monitored by DSC and in situ FT-IR. Thermal stability of derived thermosets was systemically investigated in detail by dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA). Specially, poly(RES-pa-co-DDM-BMI-1/1) is found to show a high Tg value of 374 °C and Td10 of 387 °C. Promisingly, the combined strategy used in the work may grant efficient way for design and preparation of high-performance thermosets.
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Metadata
Title
Design of acetylene-modified bio-based tri-functional benzoxazine and its copolymerization with bismaleimide for performance enhancement
Authors
Yunliang Xing
Yuan Zhang
Xianru He
Publication date
15-12-2022
Publisher
Springer Berlin Heidelberg
Published in
Polymer Bulletin / Issue 11/2023
Print ISSN: 0170-0839
Electronic ISSN: 1436-2449
DOI
https://doi.org/10.1007/s00289-022-04639-8

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